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Table Of Contents

Safety Data Sheet

MSDS 2.001.005

Primary Lithium button cell

1 Identiﬁcation of the product and of the company undertaking

Product details

Trade name Lithium primary button cell

Electrochemical system: Lithium metal | organic electrolyte | manganese dioxide

Anode (negative): Lithium metal

Cathode (positive): Manganese dioxide

This MSDS applies to the following cell and battery types and batteries assembled from these types.

Type Lithium content Nominal voltage

CR1025 0.009 g 3.0 V

CR1216 0.008 g 3.0 V

CR1220 0.01 g 3.0 V

CR1225 0.015 g 3.0 V

CR1616 0.02 g 3.0 V

CR1620 0.02 g 3.0 V

CR1632 0.04 g 3.0 V

CR2016 0.03 g 3.0 V

CR2016-P 0.03 g 3.0 V

CR2025 0.05 g 3.0 V

CR2025-P 0.05 g 3.0 V

CR2032 0.07 g 3.0 V

CR2032-P 0.07 g 3.0 V

CR2320 0.043 g 3.0 V

CR2354 0.15 g 3.0 V

CR2430 0.09 g 3.0 V

CR2430-P 0.09 g 3.0 V

CR2450 0.17 g 3.0 V

CR2450-P 0.17 g 3.0 V

CR2477 0.29 g 3.0 V

CR 1/3 N 0.06 g 3.0 V

p 28 pxl 0.12 g 6.0 V

Page no.: 1 of 9

Edition: 10.01.2020

Version: 24

Electronically generated document - no signature required.

VARTA Microbattery GmbH

VARTA-Platz 1

73479 Ellwangen

Germany

Summary of content (9 pages)

PAGE 1
Safety Data Sheet MSDS 2.001.005 Primary Lithium button cell 1 Identification of the product and of the company undertaking Product details Trade name Lithium primary button cell Electrochemical system: Lithium metal | organic electrolyte | manganese dioxide Anode (negative): Lithium metal Cathode (positive): Manganese dioxide This MSDS applies to the following cell and battery types and batteries assembled from these types. Type Page no.: Lithium content Nominal voltage CR1025 0.009 g 3.
PAGE 2
Safety Data Sheet MSDS 2.001.005 Supplier details Address: VARTA Microbattery GmbH VARTA-Platz 1 73479 Ellwangen Germany Emergency Phone Number: +49 7961 921 110 (VAC) General remark This information is provided as a service to our customers. The details presented are in accordance with our present knowledge and experiences. They are no contractual assurances of product attributes. Legal remark (EU) These batteries are no “substances” or “mixtures” according to Regulation (EC) No 1907/2006 EC.
PAGE 3
Safety Data Sheet MSDS 2.001.005 Content CAS no. EC no. Material Hazard Categories Hazard Statements 13 – 40 % 1313-13-9 215-202-6 Manganese dioxide Acute Tox. 4 H302, H332 3 – 10 % confidential confidential Plastic < 10 % 108-32-7 203-572-1 Propylene carbonate Eye Irrit. 2 H319 < 10 % 110-71-4 203-794-9 1,2-Dimethoxy ethane Flam. Liq. 2, Repr. 1B, Acute Tox. 4 H225, H332, H360-FD < 5% 646-06-0 211-463-5 1,3-Dioxolane Flam. Liq.
PAGE 4
Safety Data Sheet MSDS 2.001.005 4 First-aid measures After inhalation: Fresh air. Seek for medical assistance. After skin contact: Remove solid particles immediately. Flush affected areas with plenty of water (at least 15 min). Remove contaminated cloth immediately. Seek for medical assistance. After eye contact: Flush the eye gently with plenty of water (at least 15 min). Seek for medical assistance. After ingestion of battery components: Drink plenty of water. Avoid vomiting.
PAGE 5
Safety Data Sheet MSDS 2.001.005 7 Handling and storage Guideline for safe handling: • Always follow the warning information on the batteries and in the manuals of devices. Only use the recommended battery types. • Keep batteries away from children. Keep small cells and batteries which are considered swallowable out of the reach of children. • For devices to be used by children, the battery casing should be protected against unauthorized access. • Unpacked batteries shall not lie about in bulk.
PAGE 6
Safety Data Sheet MSDS 2.001.005 8 Exposure controls/personal protection Under normal conditions (discharge) release of ingredients does not occur. Avoid prolonged deep discharge. 9 Physical and chemical properties Not applicable if closed. 10 Stability and reactivity Dangerous reactions: 11 When heated above 100 ◦C the risk of rupture occurs. Toxicological information Under normal conditions (during discharge) release of ingredients does not occur.
PAGE 7
Safety Data Sheet MSDS 2.001.005 Importers and users outside EU should consider the local law and rules. USA VARTA primary Lithium button cell are classified by the federal government as non-hazardous waste and are safe for disposal in the normal municipal waste stream. These batteries, however, do contain recyclable materials and are accepted for recycling by Call2Recycle, Inc. Please go to their website at www.call2recycle.org for additional information.
PAGE 8
Safety Data Sheet MSDS 2.001.005 International safety standards For UL recognition of the basis cells according to UL 1642 see: BBCV2.MH13654 Water hazard class The regulations of the German Federal Water Management Act (WHG) are not applicable as VARTA primary Lithium button cell are articles and not substances, thus there is no risk of water pollution, except the batteries are violated or dismantled.
PAGE 9
Safety Data Sheet MSDS 2.001.005 Full text of Hazard Statements referred to under section 3 (continued) H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Note: Date of issue of the transport regulations: ADR 2019, RID 2019, IATA DGR 2020 (61st edition), IMDG Code 2018, DOT / 49 CFR 2019. Latest covered modification of the European Battery Directive 2006/66/EC: Directive (EU) 2018/849.