Trade name: Valve Regulated Lead Battery Revision date: January 17, 2020 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE 1.1 Product Identifier 1.1.1 Trade name/designation: Valve Regulated Lead Battery 1.2 Relevant identified uses of the substance or mixture and uses advised against: Relevant identified uses: 1.2.1 Power sport batteries General Purpose Deep Cycle Medical Equipment Standby Applications SLI Uses advised against: 1.2.2 Any other not listed above 1.
SAFETY DATA SHEET 2.2 2.2.1 Label elements Labeling according to GHS Health Physical Acute Toxicity (Oral/Dermal/ Inhalation) Skin Corrosion/ Irritation Eye Damage Reproductive Carcinogenicity (lead compounds) Carcinogenity (arsenic) Carcinogenity (acid mist) Category 4 Catagory 1 A Catagory 1 Catagory 1A Category 1B Catagory 1A Catagory 1A Specific Target Organ Toxicity (repeated exposure) Hazard Statements - DANGER! Category 2 Normal conditions No health effects are expected.
SAFETY DATA SHEET SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Description of the mixture: EC No Case material composes 5-6% of the article.
SAFETY DATA SHEET 4.1.5 Self-protection of the first aider: If artificial respiration is required use a pocket mask equipped with a one-way valve or other proper respiratory medical device. SECTION 5: FIREFIGHTING MEASURES 5.1 5.1.1 5.1.2 5.2 5.2.1 5.3 5.4 Extinguishing media: Suitable extinguishing media: CO2, dry chemical or foam Unsuitable extinguishing media: Avoid using water Special hazards arising from the substance or mixture.
SAFETY DATA SHEET SECTION 7: HANDLING AND STORAGE 7.1 7.1.1 7.1.2 7.2 Precautions for safe handling Protective measures: Handle batteries cautiously. Do not tip to avoid spills (if filled with electrolyte). Avoid contact with internal components. Wear protective clothing when filling or handling batteries. Follow manufacturer’s instructions for installation and service. Do not allow conductive material to touch the battery terminals. Short circuit may occur and cause battery failure and fire.
SAFETY DATA SHEET Ceiling(DE) MAK(DE) Ceiling(JP) TWA(ME) TWA(NIOSH) TWA(OSHA) TWA (ACGIH) TWA(CA ON) TWA(CA QU) Lead 231-100-4 7439-92-1 0.1 mg/m3 peak 0.1 mg/m3 1 mg/m3 1 mg/m3 1 mg/m3 1 mg/m3 0.05 mg/m3 0.05 mg/m3 0.05 mg/m3 0.15 (0.09) mg/m3 0.05(0.03)mg/m3 STEL(CH) TWA(CH) 0.1 mg/m3 TWA(FI) Biological Limit Value (FI) TWA(JP) TWA(ME) TWA(NIOSH) TWA(OSHA) 1.4 umol/L 0.1 mg/m3 0.15 mg/m3 0.
SAFETY DATA SHEET Evaporation rate: Not applicable Lower explosive limit: 4.1% (Hydrogen) Upper explosive limit: 74.2% (Hydrogen) Ignition temperature No Data. Vapor pressure (hPa): 10 mmHg. Vapor density (air = 1): 1 75.8523-84.2803 lbs/ft3. Density (g/cm3)at B ul k densi ty ( kg/m3) : No Data . Water solubility(20 in g/l): 100% Solubility(ies): No Data. Partition coefficient: No Data. N-Octanol/Water (log Po/w): No Data. Viscosity, dynamic (mPa s): No Data. 9.1.3 Physical hazards: Flammable gases.
SAFETY DATA SHEET SECTION 10: STABILITY AND REACTIVITY 10.1 10.2 10.3 10.4 10.5 10.6 Reactivity: Not reactive Chemical stability: Stable under normal temperatures and pressures. Possibility of hazardous reactions: Hazardous polymerization will not occur. Conditions to avoid: Prolonged overcharge, sources of ignition. Incompatible materials: Sulfuric acid: Contact with combustible and organic materials may cause fire and explosion.
SAFETY DATA SHEET Arsenic (7440-38-2) Effect dose / Concentration 763 mg/kg 5 mg/kg 0.21 1 mg/L 605 ug/kg Acute oral toxicity Acute oral toxicity M utagen R eproducti ve 11.2 11.2.1 Species Method Rat Rat Human R at LD50 LDLo Oral T DL o Time 1 5 Y ears 35 weeks preg.
SAFETY DATA SHEET 12.2 Environmental fate: Lead is very persistent in soil and sediments. No data on environmental degradation. Mobility of metallic lead between ecological compartments is slow. Bioaccumulation of lead occurs in aquatic and terrestrial animals and plants but little bioaccumulation occurs through the food chain. Most stdfies include lead compounds and not elemental lead. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 13.1.
SAFETY DATA SHEET 14.3 Land transport (TDG): These batteries have been tested and meet the non-spillable criteria. Non-spillable batteries are excepted provided that the following criteria are met: 1.) The batteries must be protected against short circuits and securely packaged. 2.) The batteries and their outer packaging must be plainly and durably marked “NON -SPILLABLE” or “NON SPILLABLE BATTERY." UN-No: UN2800 Proper shipping name: Batteries, Wet, Non-Spillable.
SAFETY DATA SHEET WHMIS: Ingredient Disclosure List Substance CAS No. Calcium 7440-70-2 Sulfuric Acid 7664-93-9 L ead 7439-92-1 L ead as L ead compounds Lead as Lead, inorganic compounds Tin 7440-31 -5 Antimony 7440-36-0 Antimony as Antimony compounds Arsenic 7440-38-2 Wt % 0.002% 10-30% 63-78% 63-78% 63-78% Disclosure Limit % Not Listed 1% 0.1 % Not L i sted 1% 0.006% 0.2 % 0.2% 1% 1% 1% 0.003% 0.1% CEPA: Priority Substances List Substance CAS No.
SAFETY DATA SHEET CLP (1272/2008) Concentration Limits Substance CAS WT % Cal ci um 7440-70-2 0.002 Sulfuric Acid 7664-93-9 10-30 L ead 7439-92-1 63-78 Lead as Lead compounds 63-78 Lead as Lead, inorganic compounds Tin A nti mony Antimony as Antimony compounds A rseni c 63-78 Concentration Limit Not L i sted 15%<=C: C; R35 5%<=C<15%: Xi; R36/38 Not L i sted 2.5%<=C: Repr. Cat. 3; R62 1%<=C: Xn; R20/22 0.5%<=C: R33 Not Listed 7440-31 -5 7440-36-0 0.006 0.2 0.2 Not L i sted Not L i sted 0.
SAFETY DATA SHEET Substance Cal ci um Sul f uri c A ci d L ead Emission Limits for Inorganic Dusts CAS WT % 7440-70-2 0.002 7664-93-9 1 0-30 7439-92-1 63-78 L ead as L ead compounds 63-78 Lead as Lead, inorganic compounds Tin 7440-31 -5 63-78 0.006 A nti mony 0.2 7440-36-0 Antimony as Antimony compounds A rseni c 15.1.4 0.2 7440-38-2 0.003 Emission Limit Not L i sted Not L i sted 2.5 g/h M ass f l ow ( cl ass I I ) ; 0.5 mg/m3 mass concentration (Class II) 2.
SAFETY DATA SHEET ISHL Notifiable Substances: Substance Cal ci um Sul f uri c A ci d L ead L ead as L ead compounds Lead as Lead, inorganic compounds Tin A nti mony Antimony as Antimony compounds A rseni c CAS 7440-70-2 7664-93-9 7439-92-1 7440-31 -5 7440-36-0 7440-38-2 WT % 0.002 1 0-30 63-78 63-78 63-78 0.006 0.2 0.2 0.003 Limit Not L i sted 1 % wei ght 0.1 % wei ght Not L i sted 0.1% weight 0.1 % wei ght 0.1 % wei ght 0.1% weight 0.
SAFETY DATA SHEET 15.1.5 National regulations(Korea): The following substances are listed on the Korean KECL: Lead (7439-92-1); Sulfuric Acid (7664-93-9); Antimony (7440-36-0); Tin (7440-31-5); Arsenic (7440-38-2); Calcium (7440-70-2) 15.1.6 National regulations(Mexico): Pollutant Release and Transfer Register: Reporting Emissions: Substance CAS WT % Threshold Quantities Cal ci um 7440-70-2 0.
SAFETY DATA SHEET CAA: 1990 Hazardous Air Pollutants: Substance CAS Cal ci um 7440-70-2 Sul f uri c A ci d 7664-93-9 L ead 7439-92-1 L ead as L ead compounds WT % 0.002 1 0-30 63-78 63-78 Lead as Lead, inorganic compounds Tin 7440-31 -5 A nti mony 7440-36-0 Antimony as Antimony compounds 63-78 0.006 0.2 0.2 A rseni c 0.
SAFETY DATA SHEET Substance Cal ci um Sul f uri c A ci d L ead L ead as L ead compounds Lead as Lead, inorganic compounds Tin A nti mony Antimony as Antimony compounds A rseni c CAS 7440-70-2 7664-93-9 7439-92-1 7440-31 -5 7440-36-0 7440-38-2 WT % 0.002 1 0-30 63-78 63-78 63-78 0.006 0.2 0.2 0.
SAFETY DATA SHEET D Series Wastes: Max Concentration of Contaminants for the Toxic Characteristic: Substance CAS WT % Regulatory Level Cal ci um 7440-70-2 0.002 Not L i sted Sul f uri c A ci d 7664-93-9 1 0-30 Not L i sted L ead 7439-92-1 63-78 5.0 mg/L L ead as L ead compounds 63-78 Not L i sted Lead as Lead, inorganic compounds 63-78 Not Listed Tin 7440-31 -5 0.006 Not L i sted A nti mony 7440-36-0 0.2 Not L i sted Antimony as Antimony compounds 0.2 Not Listed A rseni c 7440-38-2 0.003 5.
SAFETY DATA SHEET Tin A nti mony Antimony as Antimony compounds A rseni c 7440-31 -5 7440-36-0 7440-38-2 Special hazardous Substances: Substance CAS Cal ci um 7440-70-2 Sul f uri c A ci d 7664-93-9 L ead 7439-92-1 L ead as L ead compounds Lead as Lead, inorganic compounds Tin 7440-31 -5 A nti mony 7440-36-0 Antimony as Antimony compounds A rseni c 7440-38-2 0.006 0.2 0.2 0.003 Not L i sted WT % 0.002 1 0-30 63-78 63-78 63-78 0.006 0.2 0.2 0.
SAFETY DATA SHEET Safety Phrases: S1/2: Keep locked up and out of the reach of children. S2: Keep out of the reach of children. S8: Keep container dry. S20/21: When using do not eat, drink, or smoke . S24/25: Avoid contact with skin and eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28: After contact with skin, wash immediately with plenty of water. S30: Never add water to this product. S43: In case of fire use CO2, dry chemical, or foam.