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Safety Data Sheet

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SECTION 1: IDENTIFICATION

TRADE NAME: UNSATURATED POLYESTER GEL COAT IN MONOMER

CAS NUMBER: MIXTURE

PRODUCT CODE: HDW-2491

PRODUCT DESCRIPTION: WHITE NAI PUTTY

HK RESEARCH CORPORATION

PO Box 1809 EMERGENCY TELEPHONE

908 Lenoir Road 828-328-1721 (M-F, 9:00am-5:00pm)

Hickory, NC 28603 CHEMTREC 800-424-9300 (365 days, 24 hours)

(828) 328-1721

Section 2: Hazard(s): Identification

Classification of the substance or mixture

GHS Classification and labeling according to JISZ 7252-2009 and

JIS Z 7253-2012 (GHS 2011)

Classification

Flammable liquids, Category 3

Acute toxicity, Category 4, Inhalation

Skin irritation, Category 2

Eye irritation, Category 2A

Germ cell mutagenicity, Category 2

Carcinogenicity, Category 2

Reproductive toxicity, Category 1B

Specific target organ systemic toxicity - single exposure,

Category 1, Central nervous system

Specific target organ systemic toxicity - single exposure,

Category 3, Respiratory tract irritation

Specific target organ systemic toxicity - repeated exposure,

Category 1, Blood system, Liver, Nervous system, respiratory

tract/organ

Aspiration hazard, Category 1

SIGNAL WORD: DANGER

Hazard Statements H226: Flammable liquid and vapor.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H319: Causes serious eye irritation.

H332: Harmful if inhaled.

H335: May cause respiratory irritation.

H341: Suspected of causing genetic defects.

H351: Suspected of causing cancer.

H360: May damage fertility or the unborn child.

H370: Causes damage to organs

(Central nervous system).

H372: Causes damage to organs (Blood system, Liver,

Nervous system, respiratory tract/organ) through

prolonged or repeated exposure.

H401: Toxic to aquatic life.

Summary of content (33 pages)

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Safety Data Sheet _________________________________________________________________________ SECTION 1: IDENTIFICATION TRADE NAME: UNSATURATED POLYESTER GEL COAT IN MONOMER CAS NUMBER: MIXTURE PRODUCT CODE: HDW-2491 PRODUCT DESCRIPTION: WHITE NAI PUTTY HK RESEARCH CORPORATION PO Box 1809 908 Lenoir Road Hickory, NC 28603 (828) 328-1721 EMERGENCY TELEPHONE 828-328-1721 (M-F, 9:00am-5:00pm) CHEMTREC 800-424-9300 (365 days, 24 hours) Section 2: Hazard(s): Identification Classification of the substance or mixt
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Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. P260: Do not breathe dust/fume/gas/mist/vapor/spray.
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Section 3: Composition/Information on ingredients 1. CAS# MIXTURE UNSATURATED POLYESTER RESIN EXPOSURE LIMIT: ACGIH TLV/TWA: NONE ESTABLISHED OSHA PEL/TWA: 100 ppm LD50, ORAL: NOT AVAILABLE LD50, DERMAL: NOT AVAILABLE LC50, INHALATION: NOT AVAILABLE 25 - 35% 2. CAS# 000100-42-5 STYRENE MONOMER [1] 29% VAPOR PRESSURE: 4.
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5. CAS# 000080-62-6 METHYL METHACRYLATE [1] EXPOSURE LIMIT: ACGIH TLV/TWA: 50 ppm OSHA PEL/TWA: 100 ppm LD50, ORAL: 7900 mg/kg LD50, DERMAL: 5000 mg/kg LC50, INHALATION: 29.8 mg/l AVOID BREATHING DUST 6. CAS# 112945-52-5 SILICON DIOXIDE EXPOSURE LIMIT: ACGIH TLV/TWA: 10 mg/m3 OSHA PEL/TWA: 6 mg/m3 LD50, ORAL: 5000 mg/kg LD50, DERMAL: 2000 mg/kg LC50, INHALATION: N/A NOT HAZARDOUS 7.
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Section 4: First-aid measures ROUTE OF EXPOSURE INGESTION: Moderately Toxic. May cause gastrointestinal disturbances. Symptoms may include irritation, nausea, vomiting and diarrhea. Exposure may cause symptoms similar to those listed under "Inhalation" (see Inhalation section). SKIN: Moderately Irritating. Repeated or prolonged skin contact may cause reddening, inflammation or blistering. May cause allergic reactions in some individuals. Contact with heated material may cause thermal burns.
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Section 5: Fire-fighting measures FLASH POINT oC (oF): 30-35(87-95) FLAMMABILITY CLASSIFICATION: CLASS 1C AUTOIGNITION TEMPERATURE, oC (oF): 490 (914) FLAMMABILITY LIMITS IN AIR (% by volume): LOWER: 1.1 UPPER: 6.1 BASIC FIREFIGHTING PROCEDURES: Use dry chemical, all purpose or polar AFFF foam or water spray to extinguish fire. Water or foam may cause frothing, with further application leading to boilover. Foam may have limited effectiveness on three dimensional fires.
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Section 8. Exposure controls/personal protection EYE PROTECTION: Wear safety glasses or chemical goggles to prevent eye contact. Do not wear contact lenses when working with this substance. Have eye baths readily available where eye contact can occur. SKIN PROTECTION: Wear impervious gloves and protective clothing to prevent skin contact. Suggested protective materials are: Polyvinyl alcohol, Polyethylene and Viton. Provide safety showers at any location where skin contact can occur.
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11. Toxicological information INGESTION: Moderately Toxic. May cause gastrointestinal disturbances. Symptoms may Include irritation, nausea, vomiting and diarrhea. Exposure may cause symptoms similar to those listed under "Inhalation" (see Inhalation section). SKIN: Moderately Irritating. Repeated or prolonged skin contact may cause reddening, inflammation or blistering. May cause allergic reactions in some individuals. Contact with heated material may cause thermal burns.
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Section 13. Disposal considerations Waste Disposal Method: Hazardous waste. Can be incinerated, when in compliance with local regulations. Contaminated Packaging: Empty containers should be taken for local recycling, recovery or waste disposal. US EPA Waste Number: D001 (IGNITABLE): When discarded in its purchased form, this material would be regulated under 40 CFR 261.21 as EPA Hazardous Waste Number D001 based on the characteristic of ignitability. Section 14.
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SARA Title III: Section 304 - CERCLA: STYRENE MONOMER [1] (CAS# 000100-42-5), METHYL METHACRYLATE [1] (CAS# 000080-62-6) Reportable Quantity = 1,000 lb.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 SECTION 1. IDENTIFICATION Product name : NOROX MEKP-925 Manufacturer or supplier's details Company name of supplier : United Initiators GmbH Address : Dr. Gustav-Adolph-Str. 3 Pullach 09 D-82049 Emergency telephone : +49 / 89 / 74422 – 0 (24 h) E-mail address of person responsible for the SDS : contact@united-in.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 Precautionary Statements SDS Number: 600000000112 : Print Date: 07/10/2017 Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P220 Keep/Store away from clothing/ strong acids, bases, heavy metal salts and other reducing substances /combustible materials. P234 Keep only in original container. P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Hazardous ingredients Chemical name Dimethyl phthalate 2-Butanone, peroxide Trimethylpentanediol isobutyrate Butanone Hydrogen peroxide CAS-No. 131-11-3 1338-23-4 6846-50-0 78-93-3 7722-84-1 Concentration (% w/w) >= 40 - < 45 >= 30 - < 35 >= 20 - < 25 >= 1 - < 5 >= 1 - < 5 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 SECTION 5.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 Methods and materials for containment and cleaning up SDS Number: 600000000112 : Print Date: 07/10/2017 Contact with incompatible substances can cause decomposition at or below SADT. Clear spills immediately. Suppress (knock down) gases/vapors/mists with a water spray jet. To clean the floor and all objects contaminated by this material, use plenty of water. Soak up with inert absorbent material. Isolate waste and do not reuse.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 Recommended storage temperature SDS Number: 600000000112 : Print Date: 07/10/2017 < 100 °F < 38 °C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 soon as possible after exposure ceases) Engineering measures : Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter. Filter type : ABEK-filter : : : butyl-rubber >= 480 min 0.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 pH : No data available Melting point/range : No data available Boiling point/boiling range : Decomposition: Decomposes below the boiling point.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Heat, flames and sparks. Avoid confinement. Incompatible materials : Accelerators, strong acids and bases, heavy metals and heavy metal salts, reducing agents Hazardous decomposition products : Irritant, caustic, flammable, noxious/toxic gases and vapours can develop in the case of fire and decomposition SECTION 11.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 icity Acute inhalation toxicity : LCLo (Rat): > 5.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Species: Guinea pig Result: Mild skin irritation Butanone: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Hydrogen peroxide: Result: Corrosive after 3 minutes or less of exposure Serious eye damage/eye irritation Causes serious eye damage. Product: Remarks: May cause irreversible eye damage.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Ingredients: Dimethyl phthalate: Species: Mouse Method: OECD Test Guideline 429 Result: Does not cause skin sensitization. 2-Butanone, peroxide: Species: Guinea pig Method: OECD Test Guideline 406 Result: Does not cause skin sensitization. Assessment: Harmful if swallowed., Harmful if inhaled.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 2-Butanone, peroxide: Remarks: This information is not available. IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Remarks: Based on data from similar materials Effects on fetal development : Species: Rat Application Route: Inhalation General Toxicity Maternal: NOAEC: ca. 1,002 mg/kg body weight Teratogenicity: NOAEC Parent: ca. 1,002 mg/kg body weight Method: OECD Test Guideline 414 Result: negative STOT-single exposure Not classified based on available information.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Ingredients: Dimethyl phthalate: No aspiration toxicity classification Further information Product: Remarks: No data available SECTION 12.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 Toxicity to daphnia and other aquatic invertebrates SDS Number: 600000000112 : Print Date: 07/10/2017 EC50 (Daphnia magna (Water flea)): 39 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 NOEC (Daphnia magna (Water flea)): 26.7 mg/l Method: OECD Test Guideline 202 Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 5.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 2,029 mg/l Exposure time: 96 h Method: OECD Test Guideline 201 Toxicity to microorganisms : NOEC (Pseudomonas putida): 1,150 mg/l Exposure time: 16 h Method: DIN 38 412 Part 8 Hydrogen peroxide: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 16.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Bioaccumulative potential Ingredients: Dimethyl phthalate: Bioaccumulation Partition coefficient: noctanol/water 2-Butanone, peroxide: Partition coefficient: noctanol/water : Bioconcentration factor (BCF): 57 Method: OECD Test Guideline 305 : log Pow: 1.54 : log Pow: < 0.3 (25 °C) Trimethylpentanediol isobutyrate: Partition coefficient: n: log Pow: 4.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 SDS Number: 600000000112 Print Date: 07/10/2017 Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of wastes in an approved waste disposal facility. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. Dispose of in accordance with local regulations. SECTION 14.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.1 Revision Date: 07/10/2017 ERG Code Marine pollutant SDS Number: 600000000112 : : Print Date: 07/10/2017 145 no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Ingredients CAS-No.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.
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SAFETY DATA SHEET NOROX MEKP-925 Version 1.