SDS

ManualsBrandsUnbranded ManualsOutdoors37.5 lb. Pool Chlorine Tablets

SAFETY DATA SHEET

HTH 3" CHLORINATING TABLETS

REVISION DATE : 03/20/2017 Page 1 of 11

FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL:

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®:

FOR ALL SDS QUESTIONS & REQUESTS, CALL:

1-800-654-6911 (OUTSIDE

USA: 1-423-780-2970)

1-800-424-9300 (OUTSIDE

USA: 1-703-527-3887)

1-800-511-MSDS (OUTSIDE

USA: 1-423-780-2347)

PRODUCT NAME: HTH 3" CHLORINATING TABLETS

EPA Registration Number: 1258-1278

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Arch Chemicals, Inc.

1200 Bluegrass Lakes Parkway

Alpharetta, GA 30004

REVISION DATE:

03/20/2017

SUPERCEDES:

08/03/2016

MSDS Number:

000000025303

SYNONYMS:

none

CHEMICAL FAMILY:

Chloroisocyanurates

DESCRIPTION / USE

Swimming pool water treatment

FORMULA:

NOT APPLICABLE/MIXTURE

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Acute toxicity (Oral)

Category 4

Skin irritation

Category 2

Serious eye damage

Category 1

Specific target organ toxicity -

single exposure

Category 3

GHS label elements

Hazard pictograms

Signal word

Danger

Hazard statements

H302 Harmful if swallowed.

H315 Causes skin irritation.

H318 Causes serious eye damage.

Summary of content (11 pages)

PAGE 1
SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL SDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: HTH 3" CHLORINATING TABLETS EPA Registration Number: 1258-1278 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc.
PAGE 2
SAFETY DATA SHEET H335 May cause respiratory irritation. Precautionary statements : Prevention: P260 Do not breathe vapours. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P301 + P330 + P331 IF SWALLOWED: Rinse mouth.
PAGE 3
SAFETY DATA SHEET SECTION 4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: IF INHALED: Move person to fresh air.
PAGE 4
SAFETY DATA SHEET SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Situations: Spill Mitigation Procedures Air Release: Water Release: Land Release: Additional Spill Information : Response to a large quantity spill (100 pounds or greater) or when dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air repirator or self contained breathing apparatus (SCBA), chemical resistant gloves, coveralls and boots.
PAGE 5
SAFETY DATA SHEET SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit.
PAGE 6
SAFETY DATA SHEET Evaporation Rate: Oxidizing: Volatiles, % by vol.: VOC Content Not applicable Oxidizing Not applicable This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Not applicable HAP Content SECTION 10.
PAGE 7
SAFETY DATA SHEET ANHYDROUS Component Animal Toxicology Inhalation LC50 value: ALUMINUM SULFATE, Inhalation LC50 ANHYDROUS no data available Product Animal Toxicity Oral LD50 value: LD50 Believed to be > 500 but < 5,000 mg/kg. Rat Dermal LD50 value: LD50 > 5,000 mg/kg Rabbit Inhalation LC50 no data available value: Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS. Eye Irritation: Corrosive to eyes.
PAGE 8
SAFETY DATA SHEET Lepomis macrochirus (Bluegill sunfish) Daphnia magna (Water flea) Daphnia magna (Water flea) Chlorella pyrenoidosa (aglae) Anas platyrhynchos (Mallard duck) Anas platyrhynchos (Mallard duck) Bobwhite quail Mallard duck Mallard duck - Acute toxicity 96 h LC50 0.3 mg/l - 48 h EC50 0.21 mg/l static test 48 h EC50 0.17 mg/l 3 h EC50 0.5 mg/l 3 h NOEC < 0.5 mg/l LC50 1,600.00000 mg/kg 8 d LC50 > 10,000.
PAGE 9
SAFETY DATA SHEET Labels Emergency Response Guidebook Number TDG UN number Description of the goods Class Packing group Labels IATA UN number Description of the goods Class Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG-CODE UN number Description of the goods : 9 : 171 : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
PAGE 10
SAFETY DATA SHEET Hazard statements : Harmful if swallowed. May be fatal if absorbed through skin. May be fatal if inhaled. Corrosive. Causes skin burns. Corrosive. Causes irreversible eye damage. This pesticide is toxic to fish. EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Aluminum sulfate (2:3) 10043-01-3 Component RQ (lbs) 5000 Calculated product RQ (lbs) 80645 SARA 311/312 Hazards See above: SECTION 2.
PAGE 11
SAFETY DATA SHEET The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A: Components Aluminum sulfate (2:3) CAS-No. 10043-01-3 Concentration This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know Components 1,3,5-Trichloro-1,3,5-triazinane-2,4,6-trione Aluminum sulfate (2:3) CAS-No.