Version: 1.1 Revision Date: 01/16/2020 SAFETY DATA SHEET 1. Identification Material name: VULKEM 116 LV BRONZE 30 CTG/CS Material: 426719L 323 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US Contact person: Telephone: Emergency telephone number: EH&S Department 216-292-5000 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2.
Version: 1.1 Revision Date: 01/16/2020 Label Elements Hazard Symbol: Signal Word: Danger Hazard Statement: Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause genetic defects. May cause cancer. Toxic to aquatic life. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area.
Version: 1.1 Revision Date: 01/16/2020 Diisodecyl phthalate 26761-40-0 10 - <25% Calcium Carbonate (Limestone) 1317-65-3 10 - <20% Polyethylene 9002-88-4 1 - <5% P-chlorobenzotrifluoride 98-56-6 1 - <5% Heavy aromatic naphtha 64742-94-5 1 - <5% 4,4'-Methylene bis(phenylisocyanate) 101-68-8 0.1 - <1% 1,2,4-Trimethylbenzene 95-63-6 0 - <1% Aromatic petroleum distillates 64742-95-6 0.1 - <1% Trimethyl benzene (mixed isomers) 25551-13-7 0.1 - <1% 1,3,5-Trimethylbenzene 108-67-8 0.
Version: 1.1 Revision Date: 01/16/2020 Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical: During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: No data available.
Version: 1.1 Revision Date: 01/16/2020 Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. Contaminated work clothing should not be allowed out of the workplace. Avoid contact with skin. Storage Safe storage conditions: Store locked up. Safe packaging materials: No data available. 8.
Version: 1.1 Revision Date: 01/16/2020 ST ESL 700 µg/m3 AN ESL 125 µg/m3 TWA PEL 25 ppm TWA 25 ppm Trimethyl benzene (mixed isomers) 1,3,5-Trimethylbenzene TWA 25 ppm TWA 25 ppm Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. TWA 0.025 mg/m3 TWA 0.05 mg/m3 OSHA_AC T Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. PEL Crystalline Silica (Quartz)/ Silica Sand - Respirable. TWA 0.025 mg/m3 0.
Version: 1.1 Revision Date: 01/16/2020 Calcium Carbonate (Limestone) - Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Polyethylene - Respirable fraction. TWA 3 mg/m3 Polyethylene - Total dust. TWA 10 mg/m3 Polyethylene - Inhalable fraction. TWA 10 mg/m3 Polyethylene - Respirable fraction. TWA 3 mg/m3 Polyethylene - Total dust. TWA 10 mg/m3 Heavy aromatic naphtha Non-aerosol.
Version: 1.1 Revision Date: 01/16/2020 4,4'-Methylene bis(phenylisocyanate) TWA 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm Polymethylene polyphenyl isocyanate TWA 0.005 ppm CEILING 0.005 ppm 0.051 mg/m3 123 mg/m3 123 mg/m3 0.
Version: 1.1 Revision Date: 01/16/2020 Calcium Carbonate (Limestone) - Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Polyethylene - Respirable fraction. TWA 3 mg/m3 Polyethylene - Total dust. TWA 10 mg/m3 Polyethylene - Inhalable fraction. TWA 10 mg/m3 Polyethylene - Respirable fraction. TWA 3 mg/m3 Polyethylene - Total dust. TWA 10 mg/m3 Heavy aromatic naphtha Non-aerosol.
Version: 1.1 Revision Date: 01/16/2020 4,4'-Methylene bis(phenylisocyanate) TWA 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm Polymethylene polyphenyl isocyanate TWA 0.005 ppm CEILING 0.005 ppm 0.051 mg/m3 123 mg/m3 123 mg/m3 0.
Version: 1.1 Revision Date: 01/16/2020 Cumene TWA 50 ppm Cumene TWA 50 ppm 1,2,3-Trimethylbenzene TWA 25 ppm 1,2,3-Trimethylbenzene TWA 25 ppm 1,2,3-Trimethylbenzene TWA 25 ppm 123 mg/m3 Xylene TWA 100 ppm 434 mg/m3 STEL 150 ppm 651 mg/m3 TWA 100 ppm STEL 150 ppm TWA 100 ppm STEL 150 ppm STEL 150 ppm 651 mg/m3 TWA 100 ppm 434 mg/m3 CEILING 0.01 ppm Xylene Xylene Xylene 2,4-Toluene diisocyanate 2,4-Toluene diisocyanate 2,4-Toluene diisocyanate TWA 0.
Version: 1.1 Revision Date: 01/16/2020 Iron oxide - Total dust. TWA 10 mg/m3 Iron oxide - Dust. - as Fe TWA 5 mg/m3 Iron oxide - Fume. - as Fe STEL 10 mg/m3 Iron oxide - Respirable fraction. TWA 3 mg/m3 Iron oxide - Fume. - as Fe TWA 5 mg/m3 Iron oxide - Respirable fraction. TWA 5 mg/m3 Iron oxide - Total dust. TWA 10 mg/m3 Iron oxide - Dust and fume. as Fe TWA 5 mg/m3 Carbon Black - Inhalable TWA 3 mg/m3 Carbon Black - Inhalable fraction. TWA 3 mg/m3 Carbon Black TWA 3.
Version: 1.1 Revision Date: 01/16/2020 Dibutyl tin dilaurate - as Sn TWA 0.1 mg/m3 Dibutyl tin dilaurate - as Sn STEL 0.2 mg/m3 TWA 0.1 mg/m3 Diphenylmethane diisocyanate TWA CEILING 0.005 ppm 0.01 ppm Talc - Respirable. TWA 2 mg/m3 Talc - Respirable dust. TWA 3 mg/m3 Talc TWA 2 Fibers/cc Talc - Respirable fraction. TWA 2 mg/m3 Magnesite - Total dust.
Version: 1.1 Revision Date: 01/16/2020 Appropriate Engineering Controls Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust. Individual protection measures, such as personal protective equipment General information: Use personal protective equipment as required. Eye/face protection: Wear goggles/face shield.
Version: 1.1 Revision Date: 01/16/2020 Relative density: Solubility(ies) Solubility in water: Solubility (other): Partition coefficient (n-octanol/water): 1.16 Auto-ignition temperature: Decomposition temperature: Viscosity: No data available. No data available. No data available. Insoluble in water No data available. No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions.
Version: 1.1 Revision Date: 01/16/2020 Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: ATEmix: 10,939.3 mg/kg Dermal Product: Not classified for acute toxicity based on available data.
Version: 1.
Version: 1.1 Revision Date: 01/16/2020 IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Crystalline Silica (Quartz)/ Silica Sand Overall evaluation: Carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens: Crystalline Silica Known To Be Human Carcinogen. (Quartz)/ Silica Sand US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Crystalline Silica (Quartz)/ Silica Cancer Sand Germ Cell Mutagenicity In vitro Product: No data available.
Version: 1.1 Revision Date: 01/16/2020 Fish Product: Specified substance(s): Diisodecyl phthalate No data available. LC 50 (Fathead minnow (Pimephales promelas), 96 h): > 0.47 mg/l Mortality 1,2,4-Trimethylbenzene LC 50 (Fathead minnow (Pimephales promelas), 96 h): 7.19 - 8.28 mg/l Mortality 2,4-Toluene diisocyanate LC 50 (Fathead minnow (Pimephales promelas), 96 h): 108.8 - 240.
Version: 1.1 Revision Date: 01/16/2020 Mobility in soil: No data available. Other adverse effects: Toxic to aquatic organisms. 13. Disposal considerations Disposal methods: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Contaminated Packaging: No data available. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 15.
Version: 1.1 Revision Date: 01/16/2020 CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity 4,4'-Methylene bis(phenylisocyanate) Cumene Xylene 2,4-Toluene diisocyanate Toluene-2,6-Diisocyanate Ethylbenzene Reportable quantity 5000 lbs. 5000 lbs. 100 lbs. 100 lbs. 100 lbs. 1000 lbs.
Version: 1.1 Revision Date: 01/16/2020 US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Calcium Carbonate (Limestone) P-chlorobenzotrifluoride Heavy aromatic naphtha Crystalline Silica (Quartz)/ Silica Sand US. Massachusetts RTK - Substance List Chemical Identity Calcium Carbonate (Limestone) Heavy aromatic naphtha Crystalline Silica (Quartz)/ Silica Sand 2,4-Toluene diisocyanate Toluene-2,6-Diisocyanate US.
Version: 1.1 Revision Date: 01/16/2020 Inventory Status: Australia AICS: One or more components in this product are not listed on or exempt from the Inventory. Canada DSL Inventory List: All components in this product are listed on or exempt from the Inventory. EINECS, ELINCS or NLP: One or more components in this product are not listed on or exempt from the Inventory. Japan (ENCS) List: One or more components in this product are not listed on or exempt from the Inventory. China Inv.
Version: 1.1 Revision Date: 01/16/2020 16.Other information, including date of preparation or last revision Revision Date: 01/16/2020 Version #: 1.1 Further Information: No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.
