SDS

ManualsBrandsTremco ManualsCaulkVulkem® 45 SSL Limestone Polyurethane Sealant - 30 oz.

Version: 3.1

Revision Date: 10/12/2018

000000016967

1/18

SAFETY DATA SHEET

Identification

Material name: VULKEM 45 SSL LIMESTONE QT CTG

Material: 445805A 333

Recommended use and restriction on use

Recommended use

Sealant

Restrictions on use:

Not known.

Manufacturer/Importer/Supplier/Distributor Information

Tremco U.S Sealants

3735 Green Road

Beachwood OH 44122

Contact person

EH&S Department

Telephone

216-292-5000

Emergency telephone number

1-800-424-9300 (US); 1-613-996-6666 (Canada)

Hazard(s) identification

Hazard Classification

Health Hazards

Respiratory sensitizer Category 1

Skin sensitizer Category 1

Carcinogenicity Category 1A

Unknown toxicity - Health

Acute toxicity, oral 56.46 %

Acute toxicity, dermal 63.03 %

Acute toxicity, inhalation, vapor 98.01 %

Acute toxicity, inhalation, dust

or mist

90.45 %

Environmental Hazards

Acute hazards to the aquatic

environment

Category 2

Unknown toxicity - Environment

Acute hazards to the aquatic

environment

86.58 %

Chronic hazards to the aquatic

environment

98.15 %

Label Elements

Summary of content (18 pages)

PAGE 1
Version: 3.1 Revision Date: 10/12/2018 SAFETY DATA SHEET 1. Identification Material name: VULKEM 45 SSL LIMESTONE QT CTG Material: 445805A 333 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US Contact person: Telephone: Emergency telephone number: EH&S Department 216-292-5000 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2.
PAGE 2
Version: 3.1 Revision Date: 10/12/2018 Hazard Symbol: Signal Word: Danger Hazard Statement: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause cancer. Toxic to aquatic life. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. [In case of inadequate ventilation] wear respiratory protection. Contaminated work clothing should not be allowed out of the workplace.
PAGE 3
Version: 3.1 Revision Date: 10/12/2018 Calcium Carbonate (Limestone) 1317-65-3 10 - <20% Polyvinyl chloride 9002-86-2 10 - <20% Petroleum distillates 64742-47-8 5 - <10% Titanium dioxide 13463-67-7 1 - <5% Calcium oxide 1305-78-8 1 - <5% Xylene 1330-20-7 1 - <5% Isophorone Diisocyanate 4098-71-9 0.1 - <1% Diisodecyl phthalate 26761-40-0 0.01 - <1% Ethylbenzene 100-41-4 0.1 - <1% Hydrotreated heavy naphthenic distillate 64742-52-5 0.1 - <1% Aluminum oxide 1344-28-1 0.
PAGE 4
Version: 3.1 Revision Date: 10/12/2018 Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical: During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: No data available. Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6.
PAGE 5
Version: 3.1 Revision Date: 10/12/2018 (Limestone) - Respirable fraction. Polyvinyl chloride Respirable fraction. Polyvinyl chloride - as vinyl chloride monomer Polyvinyl chloride Respirable fraction. Polyvinyl chloride - Total dust. Contaminants (29 CFR 1910.1000) (02 2006) TWA 1 mg/m3 TWA 1 ppm STEL 5 ppm OSHA_AC T PEL 0.5 ppm 5 mg/m3 PEL 15 mg/m3 TWA US. ACGIH Threshold Limit Values (2011) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (02 2006) US.
PAGE 6
Version: 3.1 Revision Date: 10/12/2018 Isophorone Diisocyanate Ethylbenzene Hydrotreated heavy naphthenic distillate Inhalable fraction. Hydrotreated heavy naphthenic distillate Hydrotreated heavy naphthenic distillate - Mist. Aluminum oxide - Respirable fraction. Aluminum oxide - Total dust. ST ESL 350 µg/m3 ST ESL 80 ppb AN ESL 42 ppb AN ESL 180 µg/m3 STEL 150 ppm Ceiling 300 ppm TWA PEL 100 ppm TWA 100 ppm STEL 150 ppm PEL 100 ppm 435 mg/m3 0.
PAGE 7
Version: 3.1 Revision Date: 10/12/2018 Calcium Carbonate (Limestone) - Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Polyvinyl chloride Respirable. TWA 1 mg/m3 Polyvinyl chloride Respirable fraction. Polyvinyl chloride - Total dust. TWA 1 mg/m3 TWA 10 mg/m3 Petroleum distillates - Nonaerosol. - as total hydrocarbon vapor TWA 200 mg/m3 Petroleum distillates TWA 525 mg/m3 Petroleum distillates - Nonaerosol.
PAGE 8
Version: 3.1 Revision Date: 10/12/2018 Xylene Isophorone Diisocyanate STEL 150 ppm 651 mg/m3 TWA 100 ppm 434 mg/m3 TWA 0.005 ppm CEILING Isophorone Diisocyanate 0.01 ppm TWA 0.005 ppm CEV 0.02 ppm Isophorone Diisocyanate TWA Ethylbenzene TWA 20 ppm Ethylbenzene TWA 20 ppm Ethylbenzene STEL 125 ppm 543 mg/m3 TWA 100 ppm 434 mg/m3 Hydrotreated heavy naphthenic distillate - Mist. Hydrotreated heavy naphthenic distillate Inhalable fraction.
PAGE 9
Version: 3.1 Revision Date: 10/12/2018 Appropriate Engineering Controls Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust. Individual protection measures, such as personal protective equipment General information: Use personal protective equipment as required. Eye/face protection: Wear goggles/face shield.
PAGE 10
Version: 3.1 Revision Date: 10/12/2018 Relative density: Solubility(ies) Solubility in water: Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: in the bottom of containers. 1.32 Insoluble in water No data available. No data available. No data available. No data available. No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions.
PAGE 11
Version: 3.1 Revision Date: 10/12/2018 Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: ATEmix: 138,552.24 mg/kg Dermal Product: ATEmix: 11,135.34 mg/kg Inhalation Product: Not classified for acute toxicity based on available data. Repeated dose toxicity Product: No data available. Skin Corrosion/Irritation Product: No data available. Serious Eye Damage/Eye Irritation Product: No data available.
PAGE 12
Version: 3.1 Revision Date: 10/12/2018 Germ Cell Mutagenicity In vitro Product: No data available. In vivo Product: No data available. Reproductive toxicity Product: No data available. Specific Target Organ Toxicity - Single Exposure Product: No data available. Specific Target Organ Toxicity - Repeated Exposure Product: No data available. Aspiration Hazard Product: Other effects: No data available. No data available. 12.
PAGE 13
Version: 3.1 Revision Date: 10/12/2018 BOD/COD Ratio Product: No data available. Bioaccumulative potential Bioconcentration Factor (BCF) Product: No data available. Partition Coefficient n-octanol / water (log Kow) Product: No data available. Mobility in soil: No data available. Other adverse effects: Toxic to aquatic organisms. 13.
PAGE 14
Version: 3.1 Revision Date: 10/12/2018 US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Chemical Identity Polyvinyl chloride OSHA hazard(s) Blood Liver Cancer Flammability Central nervous system CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Xylene Ethylbenzene Nonane Toluene Methanol Reportable quantity 100 lbs. 1000 lbs. 100 lbs. 1000 lbs. 5000 lbs.
PAGE 15
Version: 3.
PAGE 16
Version: 3.1 Revision Date: 10/12/2018 US. Massachusetts RTK - Substance List Chemical Identity Calcium Carbonate (Limestone) Petroleum distillates Titanium dioxide Xylene Isophorone Diisocyanate Crystalline Silica (Quartz)/ Silica Sand US. Pennsylvania RTK - Hazardous Substances Chemical Identity Calcium Carbonate (Limestone) Petroleum distillates Titanium dioxide Calcium oxide Xylene US.
PAGE 17
Version: 3.1 Revision Date: 10/12/2018 Inventory Status: Australia AICS: One or more components in this product are not listed on or exempt from the Inventory. Canada DSL Inventory List: All components in this product are listed on or exempt from the Inventory. EINECS, ELINCS or NLP: One or more components in this product are not listed on or exempt from the Inventory. Japan (ENCS) List: One or more components in this product are not listed on or exempt from the Inventory. China Inv.
PAGE 18
Version: 3.1 Revision Date: 10/12/2018 16.Other information, including date of preparation or last revision Revision Date: 10/12/2018 Version #: 3.1 Further Information: No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.