Material Safety Data Sheet Titebond PROvantage Heavy Duty Construction Adhesive 1. Product and company identification Address Contact person Telephone In case of emergency Product code Date of revision Print date Chemtrec (24 Hour) Chemtrec International Chemical family Product use : Franklin International 2020 Bruck Street Columbus OH 43207 : Franklin Technical Services : (800) 877-4583 : Franklin Security (614) 445-1300 : 5251 : 4/23/2012. : 4/23/2012. : (800) 424 - 9300 : (703) 527 - 3887 : Adhesive.
Titebond PROvantage Heavy Duty Construction Adhesive 2. Hazards identification Carcinogenicity : Contains material which may cause cancer. Risk of cancer depends on duration and level of exposure. 3. Composition/information on ingredients United States Name CAS number % methyl acetate n-hexane vinyl acetate 79-20-9 110-54-3 108-05-4 25 - 50 1-5 0.1 - 0.5 Name CAS number % methyl acetate n-hexane methanol vinyl acetate 79-20-9 110-54-3 67-56-1 108-05-4 25 - 50 1-5 0.1 - 0.5 0.1 - 0.
Titebond PROvantage Heavy Duty Construction Adhesive 5. Fire-fighting measures Flammability of the product Extinguishing media Suitable Not suitable Special exposure hazards Special protective equipment for fire-fighters : Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. : Use dry chemical, CO2, water spray (fog) or foam. : Do not use water jet.
Titebond PROvantage Heavy Duty Construction Adhesive 8. Exposure controls/personal protection United States Ingredient Exposure limits methyl acetate ACGIH TLV (United States, 1/2011). TWA: 200 ppm 8 hour(s). TWA: 606 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 757 mg/m³ 15 minute(s). OSHA PEL 1989 (United States, 3/1989). TWA: 200 ppm 8 hour(s). TWA: 610 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 760 mg/m³ 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 200 ppm 10 hour(s).
Titebond PROvantage Heavy Duty Construction Adhesive 8. Exposure controls/personal protection vinyl acetate AB 4/2009 BC 9/2011 ON 7/2010 QC 9/2011 US ACGIH 1/2011 AB 4/2009 BC 9/2011 ON 7/2010 QC 9/2011 200 200 200 200 10 10 10 10 10 262 262 262 35 35 35 35 - 250 250 250 250 15 15 15 15 15 328 328 328 53 53 53 53 - - - - [1] [1] [1] [1] [1]Absorbed through skin. Mexico Occupational exposure limits Ingredient Exposure limits methyl acetate NOM-010-STPS (Mexico, 9/2000).
Titebond PROvantage Heavy Duty Construction Adhesive 9. Physical and chemical properties Physical state Flash point Color Odor Boiling/condensation point Relative density Volatility Evaporation rate VOC (less water, less exempt solvents) : : : : : : : : : Liquid. [Paste.] Closed cup: -18°C (-0.4°F) Brown. [Light] Solvent(s) 54.44°C (130°F) 1.2469 37.28% (w/w) >1 (butyl acetate = 1) 44 g/l Solubility : Very slightly soluble in the following materials: cold water and hot water. 10.
Titebond PROvantage Heavy Duty Construction Adhesive 11. Toxicological information Conclusion/Summary Skin Eyes Respiratory : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. : This product may irritate eyes upon contact. : High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and may lead to unconsciousness. Sensitizer No known significant effects or critical hazards.
Titebond PROvantage Heavy Duty Construction Adhesive 11. Toxicological information Skin Eyes Respiratory : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. : This product may irritate eyes upon contact. : High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and may lead to unconsciousness. Sensitizer No known significant effects or critical hazards.
Titebond PROvantage Heavy Duty Construction Adhesive Classification Product/ingredient name ACGIH IARC EPA vinyl acetate A3 2B - NIOSH - NTP OSHA - - Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. 12. Ecological information Ecotoxicity United States Aquatic ecotoxicity : No known significant effects or critical hazards.
Titebond PROvantage Heavy Duty Construction Adhesive 12. Ecological information Persistence/degradability No known significant effects or critical hazards. 13. Disposal considerations Waste disposal : The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant.
Titebond PROvantage Heavy Duty Construction Adhesive 15. Regulatory information United States HCS Classification U.S. Federal regulations : Flammable liquid Irritating material Carcinogen : TSCA 8(a) PAIR: methyl acetate; mequinol; tert-butyl acetate; 2-methylpropan-2-ol TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. SARA 302/304/311/312 extremely hazardous substances: No products were found.
Titebond PROvantage Heavy Duty Construction Adhesive 15. Regulatory information methanol Canada WHMIS (Canada) No. Yes. 45000 μg/day (ingestion) 47000 μg/day (inhalation) No. : Class B-2: Flammable liquid Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). Canadian lists Canadian NPRI : The following components are listed: n-Hexane CEPA Toxic substances : None of the components are listed. Canada inventory : Not determined.
Titebond PROvantage Heavy Duty Construction Adhesive 16. Other information Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).
