Safety Data Sheet Titebond Polyurethane Glue Section 1. Identification GHS product identifier : Titebond Polyurethane Glue Other means of identification Product type : None known. CAS # : 53862-89-8 Address Contact person : Franklin International 2020 Bruck Street Columbus OH 43207 : Franklin Technical Services Telephone : (800) 877-4583 In case of emergency Reference number : Franklin Security (614) 445-1300 : 3810 Product code : 2302 Date of revision : 6/2/2015. Print date : 6/3/2015.
Titebond Polyurethane Glue Section 2. Hazards identification Hazard statements : Causes skin and eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure if inhaled. (lungs) Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
Titebond Polyurethane Glue Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4.
Titebond Polyurethane Glue Section 4. First aid measures Skin contact Ingestion : Adverse symptoms may include the following: irritation redness : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Specific treatments Protection of first-aiders : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. : No specific treatment.
Titebond Polyurethane Glue Section 6. Accidental release measures Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. : Stop leak if without risk. Move containers from spill area. Approach release from upwind.
Titebond Polyurethane Glue Section 8. Exposure controls/personal protection Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/ m³ Other ppm mg/ m³ Other ppm mg/ m³ Other 4,4'-methylenediphenyl diisocyanate US ACGIH 4/2014 AB 4/2009 BC 4/2014 ON 1/2013 QC 1/2014 AB 4/2009 0.005 0.005 0.005 0.005 0.005 0.005 0.05 0.051 0.07 - - - - 0.01 - - - BC 4/2014 ON 1/2013 BC 4/2014 0.005 0.005 0.005 0.005 - - - - - 0.01 0.02 0.01 0.
Titebond Polyurethane Glue Section 8. Exposure controls/personal protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.
Titebond Polyurethane Glue Section 11. Toxicological information Product/ingredient name Result Species Score Exposure Observation 4,4'-methylenediphenyl diisocyanate Isocyanic acid, polymethylenepolyphenylene ester Eyes - Moderate irritant Rabbit - - Eyes - Mild irritant Rabbit - 100 milligrams 100 milligrams Conclusion/Summary Skin - Eyes : May cause skin irritation. Contains isocyanates. May be harmful if absorbed through skin. : This product may irritate eyes upon contact.
Titebond Polyurethane Glue Section 11. Toxicological information Skin contact : Adverse symptoms may include the following: irritation redness : No specific data. Ingestion Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate effects : Not available. Potential delayed effects : Not available.
Titebond Polyurethane Glue Section 13. Disposal considerations and sewers. Section 14. Transport information DOT Classification TDG Classification Mexico Classification ADR/RID IMDG IATA UN number Not regulated. Not regulated. Not regulated. Not regulated. Not regulated. Not regulated. UN proper shipping name - - - - - - Transport hazard class(es) - - - - - Packing group - - - - - - Environmental hazards No. No. No. No. No. No.
Titebond Polyurethane Glue Section 15. Regulatory information Name % Fire Sudden hazard release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard 4,4’-methylenediphenyl diisocyanate Isocyanic acid, polymethylenepolyphenylene ester methylenediphenyl diisocyanate 5 - 10 5 - 10 No. No. No. No. No. No. Yes. Yes. Yes. No. 0.5 - 1 No. No. No. Yes. Yes.
Titebond Polyurethane Glue Section 15. Regulatory information International lists : Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted.
Titebond Polyurethane Glue Section 16. Other information Date of previous issue : 5/22/2015. Version : 4.
