Percent Oxygen Analyzer OPERATING INSTRUCTIONS FOR Model 3000MA Percent Oxygen Analyzer DANGER HIGHLY TOXIC AND OR FLAMMABLE LIQUIDS OR GASES MAY BE PRESENT IN THIS MONITORING SYSTEM. PERSONAL PROTECTIVE EQUIPMENT MAY BE REQUIRED WHEN SERVICING THIS SYSTEM. HAZARDOUS VOLTAGES EXIST ON CERTAIN COMPONENTS INTERNALLY WHICH MAY PERSIST FOR A TIME EVEN AFTER THE POWER IS TURNED OFF AND DISCONNECTED. ONLY AUTHORIZED PERSONNEL SHOULD CONDUCT MAINTENANCE AND/OR SERVICING.
Model 3000MA Copyright © 2000 Teledyne Analytical Instruments All Rights Reserved. No part of this manual may be reproduced, transmitted, transcribed, stored in a retrieval system, or translated into any other language or computer language in whole or in part, in any form or by any means, whether it be electronic, mechanical, magnetic, optical, manual, or otherwise, without the prior written consent of Teledyne Analytical Instruments, 16830 Chestnut Street, City of Industry, CA 91749-1580.
Percent Oxygen Analyzer Specific Model Information The instrument for which this manual was supplied may incorporate one or more options not included with the standard instrument. Commonly available options are listed below, with check boxes. Any that are incorporated in the instrument for which this manual is supplied are indicated by a check mark in the box.
Model 3000MA Table of Contents 1 Introduction 1.1 1.2 1.3 1.4 1.5 1.6 1.7 Overview ........................................................................ 1-1 Typical Applications ....................................................... 1-1 Main Features of the Analyzer ....................................... 1-1 Model Designations ....................................................... 1-2 Front Panel (Operator Interface) .....................................
Percent Oxygen Analyzer 4.4.1 Span Cal ................................................................ 4-11 4.4.1.1 Auto Mode Spanning ..................................... 4-10 4.4.1.2 Manual Mode Spanning ................................. 4-11 4.5 The Alarms Function ...................................................... 4-12 4.6 The Range Function ...................................................... 4-14 4.6.1 Setting the Analog Output Ranges......................... 4-15 4.6.2 Autoranging Analysis .
Model 3000MA DANGER COMBUSTIBLE GAS USAGE WARNING This is a general purpose instrument designed for usage in a nonhazardous area. It is the customer's responsibility to ensure safety especially when combustible gases are being analyzed since the potential of gas leaks always exist. The customer should ensure that the principles of operating of this equipment is well understood by the user.
Percent Oxygen Analyzer Introduction 1 Introduction 1.1 Overview The Teledyne Analytical Instruments Model 3000MA Percent Oxygen Analyzer is a versatile microprocessor-based instrument for detecting the percentage of oxygen in a variety of background gases. This manual covers the Model 3000MA General Purpose flush-panel and/or rack-mount units only. These units are for indoor use in a nonhazardous environment. 1.
1 Introduction Model 3000MA • Advanced Paramagnetic sensor, designed for percent oxygen analysis. Several options are available. • Versatile analysis over a wide range of applications. • Microprocessor based electronics: 8-bit CMOS microprocessor with 32 kB RAM and 128 kB ROM. • Three user definable output ranges (from 0-1% through 0-100 %) allow best match to users process and equipment. • Air-calibration range for convenient spanning at 20.9 %.
Percent Oxygen Analyzer Introduction 1 Door Latch Digital Meter Alphanumeric Display Sample System Flow Indicator Standby Switch Data Entry Buttons Function Buttons Figure 1-1: Model 3000MA Front Panel 1.5 Front Panel (Operator Interface) The standard 3000MA is housed in a rugged metal case with all controls and displays accessible from the front panel. See Figure 1-1.
1 Introduction Model 3000MA Function Keys: Six touch-sensitive membrane switches are used to change the specific function performed by the analyzer: • Analyze Perform analysis for oxygen content of a sample gas. • System Perform system-related tasks (described in detail in chapter 4, Operation.). • Span Span calibrate the analyzer. • Zero Zero calibrate the analyzer. • Alarms Set the alarm setpoints and attributes. • Range Set up the 3 user definable ranges for the instrument.
Percent Oxygen Analyzer Introduction 1 Access Door: To provide access to the sensor, the front panel swings open when the latch in the upper right corner of the panel is pressed all the way in with a narrow gauge tool. Accessing the main circuit board requires unfastening the rear panel screws and sliding the unit out of the case. 1.6 Recognizing Difference Between LCD & VFD LCD has GREEN background with BLACK characters. VFD has DARK background with GREEN characters.
1 Introduction Model 3000MA • Alarm Connections 2 concentration alarms and 1 system alarm. • RS-232 Port Serial digital concentration signal output and control input. • Remote Probe Used in the 3000MA for controlling external solenoid valves only. • Remote Span/Zero Digital inputs allow external control of analyzer calibration. (See Note, below.) • Calibration Contact To notify external equipment that instrument is being calibrated and readings are not monitoring sample.
Percent Oxygen Analyzer Operational Theory 2 Operational Theory 2.1 Introduction The analyzer is composed of three subsystems: 1. Paramagnetic Sensor 2. Sample System 3. Electronic Signal Processing, Display and Control The sample system is designed to accept the sample gas and transport it through the analyzer without contaminating or altering the sample prior to analysis.
2 Operational Theory Model 3000MA bell to the zero position in the presence of zero gas (i.e. no O2 present) or of sample gas is proportional to the partial pressure of oxygen in the sample gas. The sensor enclosure is temperature controlled to 55 degrees centigrade to insure that the magnetic susceptibility of oxygen in the sample is not affected by the ambient temperature.
Percent Oxygen Analyzer Operational Theory 2 Sensor (rear view shown) Pin out: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 2.3 -15Vdc test pin (Not connected) +15Vdc test pin (Not connected) Measuring ground Not used Preamplifier output ~0- 1 Vdc Not used 24 Vdc return, power ground Collector of transistor switching heating element (Not connected) Fault signal: <0 Vdc= OK, >4.
2 Operational Theory Model 3000MA Gas Cross Sensitivity in vol. % Gas Cross Sensitivity in vol. % Acetylene C2H2 Allene C3H4 Ammonia NH3 Argon Ar Bromine Br2 1.2 Butadiene C4H6 1.3 Butadiene C4H6 n-Butane C4H10 I-Butane C4H8 cis 2-Butane C4H8 trans 2-Butane C4H8 Carbon dioxide CO2 Carbon monoxide CO Chlorine Cl2 Cyclo hexane C6H12 Ethane C2H6 Ethylene C2H4 Helium He n-Heptane C7H16 n-Hexane C6H14 Hydrogen H2 Hydrogen bromide HBr -0.24 -0.44 -0.26 -0.22 -1.30 -0.49 -0.49 -1.11 -085 -0.89 -0.92 -0.
Percent Oxygen Analyzer Operational Theory 2 (0% 02) - (Cross Interference Value) = Zero Point Value 0% -(-0.137) = +0.137%02 2.4 Sample System The sample system delivers gases to the sensor from the analyzer gas panel inlets. Depending on the mode of operation either sample or calibration gas is delivered. The Model 3000MA sample system is designed and fabricated to ensure that the oxygen concentration of the gas is not altered as it travels through the sample system.
2 Operational Theory 2.5 Model 3000MA Electronics and Signal Processing The Model 3000MAPercent Oxygen Analyzer uses an 8031 microcontroller with 32 kB of RAM and 128 kB of ROM to control all signal processing, input/output, and display functions for the analyzer. System power is supplied from a universal power supply module designed to be compatible with any international power source. Figure 2-6 shows the location of the power supply and the main electronic PC boards.
Percent Oxygen Analyzer Operational Theory 2 Sensor Amplifier Sensor A to D Converter 24V Power Supply Auto Range Power Supply System Failure Alarm MicroProcessor Displays Self Test Signal 0-1 V 0-1 V Concentration D to A Converter Range Figure 2-6: Block Diagram of the Model 3000MA Electronics Teledyne Analytical Instruments 2-7
2 Operational Theory 2-8 Teledyne Analytical Instruments Model 3000MA
Percent Oxygen Analyzer Installation 3 Installation Installation of the Model 3000MA Analyzer includes: 1. Unpacking 2. Mounting 3. Gas connections 4. Electrical connections 5. Testing the system. 3.1 Unpacking the Analyzer The analyzer is shipped with all the materials you need to install and prepare the system for operation. Carefully unpack the analyzer and inspect it for damage. Immediately report any damage to the shipping agent. 3.
3 Installation Model 3000MA Latch Analyze System Span Zero Alarms Range 2.0 1.0 Hinge Enter Escape 6.7” 3000MA OXYGEN ANALYZER 10” Figure 3-1: Front Panel of the Model 3000MA All operator controls are mounted on the control panel, which is hinged on the left edge and doubles as the door that provides access to the sensor inside the instrument.
Percent Oxygen Analyzer Installation 3 Figure 3-3: Rear Panel of the Model 3000MA 3.3.1 Gas Connections It is recommended that a gas filter be located upstream of the 3000MA to prevent sensor or restrictor contamination. A 0.5 micron filter should be suitable. Before using this instrument, it should be determined if the unit will be used for pressurized service or vacuum service and low pressure applications. Inspect the restrictor kit that came with the unit.
3 Installation Model 3000MA The unit is manufactured with 1/4 inch tube fittings. Six millimeter adapters are available for metric system installations. For a safe connection: 1. Insert the tube into the tube fitting, and finger-tighten the nut until the tubing cannot be rotated freely, by hand, in the fitting. (This may require an additional 1/8 turn beyond finger-tight.) 2. Hold the fitting body steady with a backup wrench, and with another wrench rotate the nut another 1 1/4 turns.
Percent Oxygen Analyzer Installation 3 Primary Input Power: The power cord receptacle and fuse block are located in the same assembly. Insert the female plug end of the power cord into the power cord receptacle. CAUTION: Power is applied to the instrument's circuitry as long as the instrument is connected to the power source. The switch on the front panel is for switching power on or off to the displays and outputs only. The universal power supply requires a 100-240 VAC, 50/60 Hz power source.
3 Installation Model 3000MA Figure 3-4: Analog Output Connections Alarm Relays: The three alarm-circuit connectors are spring terminals for making connections to internal alarm relay contacts. Each provides a set of Form C contacts for each type of alarm. Each has both normally open and normally closed contact connections. The contact connections are indicated by diagrams on the rear panel. They are capable of switching up to 3 amperes at 250 V ac into a resistive load. See Figure 3-5.
Percent Oxygen Analyzer Installation 3 Digital Remote Cal Inputs: Accept 0 V (off) or 24 V dc (on) inputs for remote control of calibration. (See Remote Calibration Protocol below.) Zero: Floating input. A 5 to 24 V pulse input across the + and – terminals puts the analyzer into the Zero mode. Either side may be grounded at the source of the signal. A synchronous signal must open and close the external zero valve appropriately. See 3.3.3 Remote Probe Connector.
3 Installation Model 3000MA Note: The Remote Probe connector (paragraph 3.3.3) provides signals to ensure that the zero and span gas valves will be controlled synchronously. If you have the –C Internal valve option—which includes additional zero and span gas inputs— the 3000MA automatically regulates the zero, span and sample gas flow. Range ID Relays: Four dedicated Range ID relay contacts.
Percent Oxygen Analyzer st Installation 3 Toggling input. Stops/Starts any status message output from the RS-232, until st is sent again. The RS-232 protocol allows some flexibility in its implementation. Table 3-2 lists certain RS-232 values that are required by the 3000MA implementation. Table 3-2: Required RS-232 Options Parameter Baud Byte Parity Stop Bits Message Interval Setting 2400 8 bits none 1 2 seconds 3.3.
3 Installation Model 3000MA Figure 3-7: FET Series Resistance 3.4 Testing the System Before plugging the instrument into the power source: • Check the integrity and accuracy of the gas connections. Make sure there are no leaks. • Check the integrity and accuracy of the electrical connections. Make sure there are no exposed conductors. • Check that sample pressure is between 3 and 15 psig, according to the requirements of your process.
Percent Oxygen Analyzer Operation 4 Operation 4.1 Introduction Once the analyzer has been installed, it can be configured for your application. To do this you will: • • • • Set system parameters: • Establish a security password, if desired, requiring Operator to log in. • Establish and start an automatic calibration cycle, if desired. Calibrate the instrument. Define the three user selectable analysis ranges. Then choose autoranging or select a fixed range of analysis, as required.
4 Operation Model 3000MA 4.2 Using the Data Entry and Function Buttons Data Entry Buttons: The < > arrow buttons select options from the menu currently displayed on the VFD screen. The selected option blinks. When the selected option includes a modifiable item, the ∆ ∇ arrow buttons can be used to increment or decrement that modifiable item. The Enter button is used to accept any new entries on the VFD screen.
Percent Oxygen Analyzer Operation 4 Contrast Function is DISABLED (Refer to Section 1.6) Figure 4-1: Hierarchy of Functions and Subfunctions duced, at the appropriate point in the procedure, in a Monospaced type style. Pushbutton names are printed in Oblique type. 4.3 The System Function The subfuctions of the System function are described below. Specific procedures for their use follow the descriptions: • • Auto-Cal: Used to define an automatic calibration sequence and/or start an Auto-Cal.
4 Operation • • • • Model 3000MA operation, such as setting the instrument span or zero setting, adjusting the alarm setpoints, or defining analysis ranges. After a password is assigned, the operator must log out to activate it. Until then, anyone can continue to operate the instrument without entering the new password. Only one password can be defined. Before a unique password is assigned, the system assigns TBEAI by default. This allows access to anyone.
Percent Oxygen Analyzer Operation 4 4.3.2 Setting up an Auto-Cal When proper automatic valving is connected (see chapter 3, installation), the Analyzer can cycle itself through a sequence of steps that automatically zero and span the instrument. Note: If you require highly accurate Auto-Cal timing, use external Auto-Cal control where possible. The internal clock in the Model 3000MA is accurate to 2-3 %. Accordingly, internally scheduled calibrations can vary 2-3 % per day.
4 Operation Model 3000MA If you have decided not to employ password security, use the default password TBEAI. This password will be displayed automatically by the microprocessor. The operator just presses the Enter key to be allowed total access to the instrument’s features. NOTE: If you use password security, it is advisable to keep a copy of the password in a separate, safe location. 4.3.3.
Percent Oxygen Analyzer Operation 4 Change Password? =Yes =No Press Escape to move on, or proceed as in Changing the Password, below. 4.3.3.2 Installing or Changing the Password If you want to install a password, or change an existing password, proceed as above in Entering the Password.
4 Operation Model 3000MA A A A A A Retype PWD To Verify Wait a moment for the entry screen. You will be given clearance to proceed. AAAAA TO Proceed Use the arrow keys to retype your password and press Enter when finished. Your password will be stored in the microprocessor and the system will immediately switch to the Analyze screen, and you now have access to all instrument functions. If all alarms are defeated, the Analyze screen appears as: 0.
Percent Oxygen Analyzer Operation 4 4.3.5 System Self-Diagnostic Test The Model 3000MA has a built-in self-diagnostic testing routine. Preprogrammed signals are sent through the power supply, output board and sensor circuit. The return signal is analyzed, and at the end of the test the status of each function is displayed on the screen, either as OK or as a number between 1 and 3. (See System Self Diagnostic Test in chapter 5 for number code.
4 Operation 4.4 Model 3000MA The Span Functions The analyzer is calibrated using span gas. NOTE: Zero is not necessary for Percent (%) level measurements. Additional information on Zero functions is provided in the Appendix A-6 of this manual. Although the instrument can be spanned using air, a span gas with a known oxygen concentration in the range of 70–90% of full scale of the range of interest is recommended.
Percent Oxygen Analyzer Operation 4 Press Enter to move to the next screen. Span Val: 20.90 Span Mod # Use the ∆ ∇ arrow keys to enter the oxygen-concentration mode. Use the < > arrow keys to blink the digit you are going to modify. Use the ∆ ∇ arrow keys again to change the value of the selected digit. When you have finished typing in the concentration of the span gas you are using (20.90 if you are using air), press Enter to begin the Span calibration.
4 Operation Model 3000MA for the first Slope value to display. Slope indicates rate of change of the Span reading. It is a sensitive indicator of stability. #### % Span Slope=#### ppm/s When the Span value displayed on the screen is sufficiently stable, press Enter. (Generally, when the Span reading changes by 1 % or less of the full scale of the range being calibrated for a period of five minutes it is sufficiently stable.) Once Enter is pressed, the Span reading changes to the correct value.
Percent Oxygen Analyzer Operation 4 In failsafe mode, the alarm relay de-energizes in an alarm condition. For non-failsafe operation, the relay is energized in an alarm condition. You can set either or both of the concentration alarms to operate in failsafe or non-failsafe mode. 3. Are either of the alarms to be latching? In latching mode, once the alarm or alarms trigger, they will remain in the alarm mode even if process conditions revert to non-alarm conditions.
4 Operation • • • • Model 3000MA To define the setpoint, use the < > arrow keys to move the blinking over to AL–1 ####. Then use the ∆∇ arrow keys to change the number. Holding down the key speeds up the incrementing or decrementing. (Remember, the setpoint units are percent-of-oxygen.) To set the other parameters use the < > arrow keys to move the blinking over to the desired parameter. Then use the ∆∇ arrow keys to change the parameter.
Percent Oxygen Analyzer Operation 4 4.6.1 Setting the Analog Output Ranges To set the ranges, enter the range function mode by pressing the Range button on the front panel. L1.00 M5.00 H10.00 ModeAUTO Use the < > arrow keys to blink the range to be set: low (L), medium (M), or high (H). Use the ∆∇ arrow keys to enter the upper value of the range (all ranges begin at 0 %). Repeat for each range you want to set. Press Enter to accept the values and return to Analyze mode. (See note below.
4 Operation Model 3000MA To switch from autoranging to fixed range analysis, enter the range function by pressing the Range button on the front panel. Use the < > arrow keys to move the blinking over AUTO. Use the ∆∇ arrow keys to switch from AUTO to FX/LO, FX/MED, or FX/HI to set the instrument on the desired fixed range (low, medium, or high). L1.00 M5.00 H10.00 ModeFX/LO or L1.00 M5.00 H10.00 ModeFX/MED or L1.00 M5.00 H10.
Percent Oxygen Analyzer Operation 4 The signal output for concentration is linear over the currently selected analysis range. For example, if the analyzer is set on range that was defined as 0–10 % O2, then the output would be: % O2 Voltage Signal Output (V dc) 0 1 2 3 4 5 6 7 8 9 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Current Signal Output (mA dc) 4.0 5.6 7.2 8.8 10.4 12.0 13.6 15.2 16.8 18.4 20.
4 Operation 4-18 Model 3000MA Teledyne Analytical Instruments
Percent Oxygen Analyzer Maintenance 5 Maintenance 5.1 Routine Maintenance Aside from normal cleaning and checking for leaks at the gas connections, routine maintenance is limited to replacing fuses, and recalibration. For recalibration, see Section 4.4 Calibration. WARNING: SEE WARNINGS ON THE TITLE PAGE OF THIS MANUAL. 5.2 Fuse Replacement 1. Place small screwdriver in notch, and pry cover off, as shown in Figure 5-1.
5 Maintenance Model 3000MA 2. To change between American and European fuses, remove the single retaining screw, flip Fuse Block over 180 degrees, and replace screw. 3. Replace fuse as shown in Figure 5-2. 4. Reassemble Housing as shown in Figure 5-1. American Fuses European Fuses Figure 5-2: Installing Fuses 5.3 System Self Diagnostic Test 1. Press the System button to enter the system mode. 2. Use the < > arrow keys to move to More, and press Enter. 3.
Percent Oxygen Analyzer Maintenance 5 2 3 5.4 Amplifier output doesn't match test input Both Failed Major Internal Components The Paramagnetic cell is accessed by unlatching and swinging open the front panel, as described earlier. Other internal components are accessed by removing the rear panel and sliding out the entire chassis. See Figure 5-4, below. The gas piping is illustrated in Figure 2-4, and the major electronic components locations are shown in Figure 2-5, in chapter 2.
5 Maintenance 5.5 Model 3000MA Cleaning If instrument is unmounted at time of cleaning, disconnect the instrument from the power source. Close and latch the front-panel access door. Clean outside surfaces with a soft cloth dampened slightly with plain clean water. Do not use any harsh solvents such as paint thinner or benzene. For panel-mounted instruments, clean the front panel as prescribed in the above paragraph. DO NOT wipe front panel while the instrument is controlling your process. 5.
Percent Oxygen Analyzer Appendix Appendix A-1 Model 3000MA Specifications Packaging: General Purpose • Flush panel mount (Standard). • Rack mount — Relay rack mounted to contain either one or two instruments in one 19" relay rack mountable plate (Optional). Sensor: Paramagnetic Sensor 90 % Response Time: 10 seconds at 25 °C (77 °F). Ranges: Three user definable ranges from 0-1 % to 0-100 %, plus air calibration range of 0-25 %. Alarms: One system-failure alarm contact to detect power failure.
Appendix Model 3000MA range, on factory default analysis ranges, once thermal equilibrium has been reached. Analog outputs: 0-1 V dc percent-of-range (Standard) 0-1 V dc range ID (Standard) 4-20 mA dc—isolated— percent-of-range (Optional) 4-20 mA dc—isolated— range ID (Optional) Dimensions: 19 cm high × 24.9 cm wide × 31 cm deep (5.96″ × 8.7″ × 12.2″).
Percent Oxygen Analyzer Appendix A-2 Recommended 2-Year Spare Parts List Qty Part Number Description 1 C62374 Back Panel Board 1 C62371-B Front Panel Board 1 C670043 Percent Preamplifier Board 1* C62365-C Main Computer Board (std) 1* C62365-A Main Computer Board (4-20 mA) 3 F9 Fuse, 1 A, 250 V, 3 AG, Slow Blow 3 F1275 Fuse, 1 A, 250 V, 5 × 20 mm, Slow Blow 1 R1460 Molex Connector for Remote Probe 1 T976 Molex Crimp Terminals for Remote Probe Connector 2 F73 Ferrule 1/4” SS
Appendix Model 3000MA A-3 Drawing List D-71698 Outline Drawing B-71699 Piping Diagram Figure A-1: Single and Dual 19" Rack Mounts A-4 Teledyne Analytical Instruments 5.75 8.72 5.75 8.
Percent Oxygen Analyzer A-5 Appendix Zero Cal The Zero button on the front panel is used to enter the zero calibration function. Zero calibration can be performed in either the automatic or manual mode. In the automatic mode, an internal algorithm compares consecutive readings from the sensor to determine when the output is within the acceptable range for zero. In the manual mode, the operator determines when the reading is within the acceptable range for zero.
Appendix Model 3000MA to toggle between AUTO and MAN zero settling. Stop when MAN appears, blinking, on the display. Zero: Settling: Man To Begin Press Enter to begin the zero calibration. After a few seconds the first of five zeroing screens appears. The number in the upper left hand corner is the first-stage zero offset. The microprocessor samples the output at a predetermined rate.
Percent Oxygen Analyzer Appendix Teledyne Analytical Instruments A-7
Appendix Model 3000MA A-5 Material Safety Data Sheet Section I – Product Identification Product Name: Micro-Fuel Cells and Super Cells, all classes except A-2C, A-3, and A-5. Electrochemical Oxygen Sensors, all classes except R-19. Mini-Micro-Fuel Cells, all classes.
Percent Oxygen Analyzer Appendix Section IV – Fire and Explosion Hazard Data Flash Point: na Flammable Limits: na LEL: na UEL: na Extinguishing Media: Use extinguishing media appropriate to surrounding fire conditions. No specific agents recommended. Special Fire Fighting Equipment: Wear NIOSH/OSHA approved self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual Fire and Explosion Hazards: Emits toxic fumes under fire conditions.
Appendix Model 3000MA Signs and Symptoms of Exposure: Contact of electrolyte with skin or eyes will cause a burning sensation and/or feel soapy or slippery to touch. Other symptoms of exposure to lead include loss of sleep, loss of appetite, metallic taste and fatigue. Carcinogenicity: Lead is classified by the IARC as a class 2B carcinogen (possibly carcinogenic to humans) OSHA: Where airborne lead exposures exceed the OSHA action level, refer to OSHA Lead Standard 1910.1025.
Percent Oxygen Analyzer Appendix Section VIII – Control Measures Eye Protection: Chemical splash goggles Hand Protection: Rubber gloves Other Protective Clothing: Apron, face shield Ventilation: na Section IX – Disposal Both lead and potassium hydroxide are considered poisonous substances and are regulated under TSCA and SARA Title III. EPA Waste Number: D008 California Waste Number: 181 DOT Information: RQ Hazardous Waste Solid N.O.S.