Safety data sheet


STANLEYCHALKSMSDS 


STANLEYCHALKSMSDS
PAGE4OF10
8.EXPOSURECONTROLS-PERSONALPROTECTION(Continued)
INTERNATIONALOCCUPATIONALEXPOSURELIMITS(continued): 
CARBONBLACK(continued):
ThePhilippines:TWA=3.5mg/m
3
,JAN1993
TheNetherlands:MAC-TGG=3.5mg/m
3
,2003
Russia:STEL=4mg/m
3
,JUN2003
Sweden:NGV=3mg/m
3
(dust),JAN1999
UnitedKingdom:TWA=3.5mg/m
3
;STEL=7mg/m
3
,2005
In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam,VietnamcheckACGIHTLV
CRYSTALLINESILICA:
Belgium:TWA=0.1mg/m
3
,JAN1993
Denmark:TWA=0.1mg/m
3
(respirable),OCT2002
Denmark:TWA=0.3mg/m
3
(total),OCT2002
Finland:TWA=0.2mg/m
3
,JAN1999
France:VME=10/(X+2),JAN1999
Korea:TWA=0.1mg/m
3
,2006
Mexico:TWA=0.1mg/m
3
(respirable),2004
CRYSTALLINESILICA(continued):
New Zealand: TWA = 0.2 mg/m
3
 (respirable dust),
JAN2002
TheNetherlands:MAC-TGG=0.075mg/m
3
,2003
Norway:TWA=0.1mg/m
3
(resp.dust),JAN1999
Norway:TWA=0.3mg/m
3
(totaldust),JAN1999
Russia:TWA=1mg/m
3
,STEL=3mg/m
3
,JUN2003
Sweden:NGV=0.1mg/m
3
(resp.dust),JAN1999
Switzerland:MAK-W=0.15mg/m
3
,JAN1999
Thailand:TWA=10mg/m
3
(resp.dust),JAN1993
Thailand:TWA=30mg/m
3
(totaldust),JAN1993
UnitedKingdom:TWA=0.3mg/m
3
(respirable),2005
In Argentina, Bulgaria, Colombia, Jordan, Singapore,
VietnamcheckACGIHTLV
IRONOXIDE:
Russia:STEL=4mg/m
3
,JUN2003
MAGNESIUMCARBONATE:
Australia:TWA=10mg/m
3
,JAN1993
Belgium:TWA=10mg/m
3
,JAN1993
France:VME=10mg/m
3
,JAN1999
Korea:TWA=10mg/m
3
,2006
Mexico: TWA = 10 mg/m
3
; STEL = 20 mg/m
3
 (inhalable),
2004
TheNetherlands:MAC-TGG=10mg/m
3
,2003
NewZealand:TWA=10mg/m
3
(inspirabledust),JAN2002
Norway:TWA=0.6mg(F)/m
3
,JAN1999
Russia:STEL=10mg/m
3
,JUN2003
Switzerland:MAK-W=6mg/m
3
,JAN1999
UnitedKingdom:TWA=10mg/m
3
(inhalable),2005
UnitedKingdom:TWA=4mg/m
3
(respirable),2005
In Argentina, Bulgaria, Colombia, Jordan, Singapore,
VietnamcheckACGIHTLV

The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA
regulationsfoundin29CFRSubpartI(beginningat1910.132),equivalentstandardsofCanada(includingCSAStandardZ94.4-02and
CSAStandardZ94.3-02),standardsofEUmemberstates(includingEN529:2005forrespiratoryPPE,CEN/TR15419:2006forhand
protection,andCR13464:1999forface/eyeprotection).Pleasereferenceapplicableregulationsandstandardsforrelevantdetails.
RESPIRATORY PROTECTION:  None needed under normal conditions of use and handling.   Maintain airborne
contaminant concentrations below exposure limits listed above if applicable.  If necessary, refer to U.S. OSHA 29 CFR
1910.133,CanadianCSAStandardZ94.3-02,ortheEuropeanStandardCR13464:1999.Oxygenlevelsbelow19.5%are
considered IDLH by OSHA.  In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece,
supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard
(1910.134-1998). Thefollowing are NIOSH Respiratory Protection EquipmentGuidelines forsome componentsof these
products:
CARBONBLACK
CONCENTRATION
 RESPIRATORYPROTECTION
Upto17.5mg/m3: AnyDustandMistRespirator.
Upto35mg/m3: AnyDustandMistRespiratorexceptsingle-useandquarter-maskrespirators,oranySupplied-AirRespirator(SAR).
Upto87.5mg/m3: AnySARoperatedin acontinuous-flowmode,oranyPowered,Air-PurifyingRespirator(PAPR)withadustandmist
filter.
Upto175mg/m3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any PAPR with a tight-fitting
facepiece and a high-efficiency particulate filter, or any Self-Contained Breathing Apparatus (SCBA) with a full
facepiece,oranySARwithafullfacepiece.
Upto1750mg/m3: AnySARoperatedinapressure-demandorotherpositive-pressuremode.
EmergencyorPlannedEntryintoUnknownConcentrationsorIDLHConditions:AnySCBAthathasafullfacepieceandisoperatedinapressure-
demandorotherpositive-pressuremode,oranySARthathasafullfacepieceandisoperatedinapressure-demandor
otherpositive-pressuremodeincombinationwithanauxiliaryself-containedbreathingapparatusoperatedinpressure-
demandorotherpositive-pressuremode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any appropriate escape-type,
SCBA.
InPresenceofPolycyclicaromaticHydrocarbons:
BasedonNIOSHRELatConcentrationsAbovetheNIOSHREL,orWhereThereisNoREL,atAnyDetectableConcentration:AnySCBAthathasa
full facepiece and is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepieceandisoperatedinapressure-demandorotherpositive-pressuremodeincombinationwithanauxiliarySCBA
operatedinpressure-demandorotherpositive-pressuremode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any appropriate escape-type,
SCBA.
CRYSTALLINESILICA

CONCENTRATION
 RESPIRATORYPROTECTION
Upto0.5mg/m
3
: AnyAir-PurifyingRespiratorwithahigh-efficiencyparticulatefilter.
Upto1.25mg/m
3
: Any Powered, Air-Purifying Respirator (PAPR) with a high-efficiency particulate filter, or any Supplied-Air Respirator
(SAR)operatedinacontinuous-flowmode.
Upto2.5mg/m
3
: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any PAPR with a tight-fitting
facepieceandahigh-efficiencyparticulatefilter.
Upto25mg/m
3
: AnySARoperatedinapressure-demandorotherpositive-pressuremode.
EmergencyorPlannedEntryintoUnknownConcentrationsorIDLHConditions:AnySCBAthathasafullfacepieceandisoperatedinapressure-
demandorotherpositive-pressuremode,oranySARthathasafullfacepieceandisoperatedinapressure-demandor
other positive-pressure mode in combination with an auxiliarySCBA operated in pressure-demandor other positive-
pressuremode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any appropriate escape-type,
SCBA.
EYEPROTECTION:Noneneededundernormaluseandhandling.Wearsafetygogglesifdustsorotherparticulatesare
present.  If necessary refer to U.S. OSHA 29 CFR 1910.133, Canadian CSA Standard Z94.3-02, or the European
StandardCR13464:1999.
HANDPROTECTION
:Noneneededundernormalconditionsofuseandhandling.Wearappropriategloveforworkbeing
done.Resistanceofspecificmaterialscanvaryfromproducttoproduct.Evaluateresistanceunderconditionsofuseand
maintainglovescarefully.Usetripleglovesforspillresponse,asstatedinSection6(AccidentalReleaseMeasures)ofthis
MSDS.  If necessary, refer to U.S. OSHA 29 CFR 1910.138, appropriate Standards of Canada and the European
StandardCEN/TR15419:2006.