Certifications 2
STANLEYCHALKSMSDS
STANLEYCHALKSMSDS
PAGE8OF10
15.REGULATORYINFORMATION(Continued)
ADDITIONALU.S.REGULATIONS(continued):
U.S.SARATHRESHOLDPLANNINGQUANTITY
:TherearenospecificThresholdPlanningQuantitiesforthecomponents
oftheseproducts.ThedefaultFederalMSDSsubmissionandinventoryrequirementfilingthresholdof10,000lb(4,540kg)
thereforeapplies,per40CFR370.20.
U.S.CERCLAREPORTABLEQUANTITY(RQ)
:Notapplicable.
U.S.TSCAINVENTORYSTATUS
:ComponentsoftheseproductsareontheTSCAInventory.
OTHERU.S.FEDERALREGULATIONS
:Notapplicable.
CALIFORNIASAFEDRINKINGWATERANDTOXICENFORCEMENTACT(PROPOSITION65)
:CrystallineSilicaison
the CaliforniaProposition65 lists. Carbon Black,with particles of respirable size, ison the Proposition 65 Lists as well.
WARNING!TheseproductscontaincompoundsknowntotheStateofCaliforniatocausecancer.
LABELING(Precautionary Statements)ANSILABELING(Z129.1)
: CAUTION! MAYCAUSEEYEANDRESPIRATORY
TRACTIRRITATION. CONTAINSCRYSTALLINESILICA,WHICHISA KNOWNHUMANCARCINOGEN.INGESTION
MAYBEHARMFUL.Avoidbreathingdusts.Avoidcontactwithskin,eyes,andclothing.Keepcontainerclosed.Usewith
adequateventilation.Preventdustaccumulation.Washthoroughlyafterhandling.Weargloves,goggles,dustmask,and
appropriatebodyprotectionduringoperationsthatcangeneratedust.FIRST-AID:Incaseofcontact,flushskinoreyeswith
plentyofwater.Ifinhaled,removetofreshair.Ifingesteddonotinducevomiting.Getmedicalattentionifadverseeffects
continueafteroverexposureends.INCASEOFFIRE:Usewaterfog,drychemical,CO
2
,or“alcohol”foam.INCASEOF
SPILL:Sweepupspill,avoidingthegenerationofairbornedusts.Placeresidualinappropriatecontainerandseal.Consult
MaterialSafetyDataSheetforadditionalinformation.
ADDITIONALCANADIANREGULATIONS:
CANADIANDSL/NDSLINVENTORYSTATUS
:ThecomponentsoftheseproductsareontheDSLInventory.
OTHERCANADIANREGULATIONS
:Notapplicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS
: The components of
theseproductsarenotontheCEPAPrioritySubstancesLists.
CANADIANWHMISCLASSIFICATIONandSYMBOLS
:ClassD2A-ChronicToxicEffects
EUROPEANUNIONINFORMATION
:
EU LABELING/CLASSIFICATION
: These products do meet the definition of any hazard class, as defined by the
EuropeanUnionCouncilDirective67/548/EECorsubsequentDirectives.
EUCLASSIFICATION:Notapplicable. EURISKPHRASES:Notapplicable. EUSAFETYPHRASES:Notapplicable.
16.OTHERINFORMATION
PREPAREDBY: CHEMICALSAFETYASSOCIATES,Inc.
POBox36519,LaMesa,CA91944-3519
(800)441-3365
DATEOFPRINTING: December12,2007
Theinformationcontainedhereinisbasedondataconsideredaccurate.However,nowarrantyisexpressedorimpliedregardingtheaccuracyofthesedataortheresultstobeobtainedfromtheuse
thereof.StanleyWorksassumesnoresponsibilityforinjurytothevendeeorthirdpersonsproximatelycausedbythematerialifreasonablesafetyproceduresarenotadheredtoasstipulatedinthedata
sheet.Additionally,StanleyWorksassumesnoresponsibilityforinjurytovendeeorthirdpersonsproximatelycausedbyabnormaluseofthematerialevenifreasonablesafetyproceduresarefollowed.
Furthermore,vendeeassumestheriskinhisuseofthematerial.
DEFINITIONSOFTERMS
AlargenumberofabbreviationsandacronymsappearonanMSDS.Someofthese,whicharecommonlyused,includethefollowing:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each
constituent.
EXPOSURELIMITSINAIR:
CEILINGLEVEL:Theconcentrationthatshallnotbeexceededduringanypartoftheworking
exposure.
DFGMAKGermCellMutagenCategories:1:Germcellmutagenswhichhavebeenshown
toincreasethemutantfrequencyintheprogenyofexposedhumans.2:Germcellmutagens
which have been shown to increase the mutant frequency in the progeny of exposed
mammals.3A:Substanceswhichhavebeenshowntoinducegeneticdamageingermcells
ofhumanofanimals,orwhichproducemutageniceffectsinsomaticcellsofmammalsinvivo
andhavebeenshowntoreachthegermcellsinanactiveform.3B:Substanceswhichare
suspected of being germ cell mutagens because of their genotoxic effects in mammalian
somaticcellinvivo;inexceptionalcases,substancesforwhichtherearenoinvivodata,but
whichareclearlymutagenicinvitroandstructurallyrelatedtoknowninvivomutagens.4:Not
applicable(Category4carcinogenicsubstancesarethosewithnon-genotoxicmechanismsof
action.Bydefinition,germcellmutagensaregenotoxic.Therefore,aCategory4forgermcell
mutagenscannotapply.Atsometimeinthefuture,itisconceivablethataCategory4could
be established for genotoxic substances with primary targets other than DNA [e.g. purely
aneugenicsubstances]ifresearchresultsmakethisseemsensible.)5:Germcellmutagens,
thepotencyofwhich isconsideredtobe solowthat,providedtheMAKvalueisobserved,
theircontributiontogeneticriskforhumansisexpectednottobesignificant.
EXPOSURELIMITSINAIR(continued):
DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the
developing embryo or fetus has been unequivocally demonstrated. Exposure of pregnant
womencanleadtodamageofthedevelopingorganism,evenwhenMAKandBAT(Biological
ToleranceValueforWorkingMaterials)valuesareobserved. GroupB:Currentlyavailable
informationindicatesariskofdamagetothedevelopingembryoorfetusmustbeconsidered
to be probable. Damage to the developing organism cannot be excluded when pregnant
womenareexposed,evenwhenMAKandBATvaluesareobserved.GroupC:Thereisno
reasontofearariskofdamagetothedevelopingembryoorfetuswhenMAKandBATvalues
areobserved.GroupD:ClassificationinoneofthegroupsA-Cisnotyetpossiblebecause,
althoughthedataavailablemayindicateatrend,theyarenotsufficientforfinalevaluation.
IDLH-Immediately Dangerous to Life and Health: This level represents a concentration
from which one can escape within 30-minutes without suffering escape-preventing or
permanentinjury.
LOQ:LimitofQuantitation.
MAK:FederalRepublicofGermanyMaximumConcentrationValuesintheworkplace.
NE:NotEstablished.Whennoexposureguidelinesareestablished,anentryofNEismade
forreference.
NIC:NoticeofIntendedChange.
NIOSHCEILING:Theexposurethatshallnotbeexceededduringanypartoftheworkday.If
instantaneousmonitoringisnotfeasible,theceilingshallbeassumedasa15-minuteTWA
exposure (unless otherwise specified) that shall not be exceeded at any time during a
workday.