Certifications 2

ManualsBrandsSTANLEY BY BLACK & DECKER ManualsWarning & Safety Signs0-47-440

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STANLEYCHALKSMSDS

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STANLEYCHALKSMSDS

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8.EXPOSURECONTROLS-PERSONALPROTECTION(Continued)

BODYPROTECTION:Usebodyprotectionappropriatefortask.Full-bodychemicalprotectiveclothingisrecommendedfor

emergencyresponseprocedures. If necessary,refer tothe OSHA Technical Manual (Section VII: Personal Protective

Equipment)appropriateStandardsofCanada,ortheEuropeanStandardCEN/TR15419:2006.

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Ifahazardofinjurytothe

feetexistsduetofallingobjects,rollingobjects,whereobjectsmaypiercethesolesofthefeetorwhereemployee’sfeetmay

beexposedtoelectricalhazards,usefootprotection,asdescribedinU.S.OSHA29CFR1910.136andtheCanadianCSA

StandardZ195-02,ProtectiveFootwear.

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9.PHYSICALandCHEMICALPROPERTIES

SOLUBILITYINORGANICSOLVENTS:Notknown.

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SOLUBILITYINWATER:BlackandBlueChalks:Insoluble.RedChalk:0.1%;WhiteChalk:Insoluble.

RELATIVEVAPORDENSITY(air=1)

:Notestablished. EVAPORATIONRATE(n-BuAc=1):Notestablished.

MELTING/FREEZINGPOINT

:Notestablished.    BOILINGPOINT:Notestablished.

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VAPORPRESSURE:Notestablished.      pH:Notavailable.

ODORTHRESHOLD

:Notapplicable.       DECOMPOSITIONTEMPERATURE:120°C(248°F)

SPECIFICGRAVITY(water=1)

:BlackChalk:2.49-2.52;BlueChalk:2.60-2.62;RedChalk:3.1-3.3;WhiteChalk:2.71

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APPEARANCE, ODOR AND COLOR:  These products are colored (black, red, white or blue), finely divided, odorless

powderedsolids.

HOW TO DETECT THIS SUBSTANCE IN EVENT OF ACCIDENTAL SPILL (warning properties)

:  The color of these

productsmaybeamethodtoidentifythemineventofanaccidentalspill.

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10.STABILITYandREACTIVITY

STABILITY:Normallystable.

DECOMPOSITION PRODUCTS

:  Thermal:  Thermal decomposition of this product can produce iron oxides, aluminum

oxides,silicondioxide,sulfurdioxide,magnesiumoxides,carbonoxidesandcalciumoxides.TheBlueChalkmayrelease

hydrogensulfideincontactwithacids.Hydrolysis:Noneknown.

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MATERIALSWITHWHICHSUBSTANCE IS INCOMPATIBLE: Calcium carbonate ignites on contact with fluorine. It is

incompatible with acids, aluminum, and ammonium salts and mercury/hydrogen mixtures.  Due to other components,

these products may also be incompatible with formaldehyde, strong oxidizing agents, hydrofluoric acid, manganese

trifluoride,sodium,andxenonhexafluoride.

HAZARDOUSPOLYMERIZATION

:Willnotoccur.

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CONDITIONSTOAVOID:Avoidexposuretoorcontactwithlight,extremetemperatures,andincompatiblechemicals.

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PARTIV

Isthereanyotherusefulinformationaboutthismaterial?

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11.TOXICOLOGICALINFORMATION

SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE:  The

mostsignificantroutesofindustrialexposuretothisproductarebyskinor

eyecontactandinhalation.

INHALATION

:  If dusts or particulates from these products are inhaled,

irritationofthenose,throat,andlungscanoccur.Symptomsmayinclude

sneezing,coughing,nasalcongestion,anddifficultybreathing.Symptoms

are generally alleviated upon exposure to fresh air.  If heated, chronic

exposure to concentrations of silicon dioxide fume may cause chronic

obstructivelungdisease.Inhalationofironoxidefumeordustiscauseof

pulmonary roentgenographic appearance called siderosis, or an

accumulationofironthatleadstoreducedlungcapacity.Theseproducts

contain Crystalline Silica, which is a known human carcinogen.  Chronic

inhalationexposuretothismaterialmaycausesilicosis,pulmonaryfibrosis,

bronchitisorpresentahazardofcancer,duetothepresenceofCrystalline

Silica.

CONTACT WITH SKIN or EYES

:  Skin contact may cause abrasion,

redness, and discomfort.  Prolonged or repeated skin overexposure may

cause dermatitis (dry, red skin).  Direct eye contact with these products

may cause stinging, tearing, and redness.  Dust can cause mechanical

irritation to the eye.  Repeated contact of iron dusts with the eyes can

causeconjunctivitis,orcancausediscolorationoftheeyes.

SKIN ABSORPTION

:  This product does not pose a hazard of skin

absorption.

INGESTION

:Ingestionisanunlikelyrouteofoccupationalexposuretothis

product.  In the unlikely event that dusts from the product are ingested

nausea,vomiting,anddiarrheamayresult.

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HEALTHHAZARD

FLAMMABILITYHAZARD

PHYSICALHAZARD

PROTECTIVEEQUIPMENT

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EYES

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RESPIRATORY

HANDS

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BODY

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(BLUE)

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(RED)

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ForRoutineIndustrialUseandHandlingApplications

SEESECTION8

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HAZARDOUSMATERIALIDENTIFICATIONSYSTEM

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(ORANGE)

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SEESECTION8

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HazardScale:

=

Minimal

=Slight

=Moderate

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3=Serious4=Severe*=Chronichazard