SDS

Date Printed: 10/10/2022
Overexposure to methyl ethyl ketone in laboratory animals has been associated with liver abnormalities, kidney and lung damage.
Fetotoxic/embryotoxic effects from inhalation have been seen in rats exposed to >1000ppm during gestation. Contains carbon black.
Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of
time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other
animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North
American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified
as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated
during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of
surfaces or spray mist and the actual concentration of carbon black in the formula. Contains Titanium Dioxide. Titanium Dioxide is
listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur
during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying.
Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the
actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
78-93-3 Methyl Ethyl Ketone 2483 mg/kg Rat 5000 mg/kg Rabbit N.E.
123-86-4 n-Butyl Acetate 10768 mg/kg Rat >17600 mg/kg Rabbit > 21 mg/L Rat
79-20-9 Methyl Acetate 5000 mg/kg Rat >5000 mg/kg Rabbit >49 mg/L Rat
13463-67-7 Titanium Dioxide >10000 mg/kg Rat 6000 N.E.
64742-95-6 Solvent Naphtha, Light Aromatic 8400 mg/kg Rat >2000 mg/kg Rabbit N.E.
1333-86-4 Carbon Black >15400 mg/kg Rat N.E. N.E.
67-68-5 Dimethyl Sulfoxide 28300 mg/kg Rat 40000 mg/kg Rat >5.33 mg/L Rat
919-30-2 3-Aminopropyltriethoxysilane 1780 mg/kg Rat 4290 mg/kg Rabbit N.E.
872-50-4 N-Methyl 2-Pyrrolidone 3914 mg/kg Rat 8000 mg/kg Rabbit 20 mg/L Rat
41556-26-7 bis(1,2,2,6,6-Pentamethyl-4-Piperidinyl)
Sebacate
2615 mg/kg Rat N.E. N.E.
64742-82-1 Petroleum Naphtha, Hydrodesulfurized Heavy >5000 mg/kg Rat >2000 mg/kg Rabbit N.E.
67-56-1 Methanol 6200 mg/kg Rat 15840 mg/kg Rabbit N.E.
7631-86-9 Amorphous Silica 7900 mg/kg Rat >5000 mg/kg Rabbit 25 mg/L
128-37-0 Butylated Hydroxytoluene 890 mg/kg Rat >2000 mg/kg Rat N.E.
N.E. - Not Established
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL: Do not incinerate closed containers. This product as supplied is a USEPA defined ignitable hazardous waste. Dispose
of unusable product as a hazardous waste (D001) in accordance with local, state, and federal regulation. EPA Hazardous Waste
Number (RCRA): D035 (Methyl ethyl ketone). Dispose of in accordance with U.S. EPA 40 CFR 262 for concentrations at or above the
Regulatory level. Regulatory level >= 200.0 mg/L.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name:
Paint and Related Spray
Products in Ltd Qty
Aerosols Aerosols, flammable Aerosols
Hazard Class: N.A. 2 2.1 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: Yes Yes Yes Yes
No Information
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