MSDS
Date Printed: 5/14/2015
Carbon Black 1333-86-4 1.0
3 mg/m3
(Inhalable Dust)
N.E. 3.5 mg/m3 N.E.
Methanol 67-56-1 1.0 200 ppm 250 ppm 200 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in
volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors
and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control
airborne levels below recommended exposure limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
9. Physical and Chemical Properties
Appearance:
Aerosolized Mist
Physical State:
Liquid
Odor:
Solvent Like
Odor Threshold:
N.E.
Relative Density:
0.783
pH:
N.A.
Freeze Point, °C:
N.D.
Viscosity:
No Information
Solubility in Water:
Negligible
Partition Coefficient, n-octanol/
water:
No Information
Decompostion Temp., °C:
No Information
Boiling Range, °C:
-11 - 999
Explosive Limits, vol%:
0.9 - 36.0
Flammability:
Supports Combustion
Flash Point, °C:
-105
Evaporation Rate:
Faster than Ether
Auto-ignition Temp., °C:
No Information
Vapor Density:
Heavier than Air
Vapor Pressure:
No Information
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible
sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde. By open
flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: May form peroxides of unkown stability. This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. High
vapor concentrations are irritating to the eyes, nose, throat and lungs. Harmful if inhaled. Avoid breathing fumes, spray, vapors, or
mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Poison, may be fatal or cause blindness if swallowed. Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been
observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several
insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar
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