SDS

Date Printed: 6/29/2016
FIRST AID - INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce
vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, do not induce vomiting. If victim is
conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything
by mouth to an unconscious person. Treat symptomatically and supportively. Do not induce vomiting unless advised by a physician.
Call nearest Poison Control Center or Physician immediately.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Containers can rupture and release highly toxic material if exposed to heat. Substance
is non-combustible but reacts with many metals to form explosive hydrogen gas. Use water spray to keep fire-exposed containers
cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid runoff into sewers and waterways. Provide ventilation
and approach spill from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with
sodium bicarbonate (NaHCO3). Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust.
Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep container closed when not in
use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
Citric Acid, Anhydrous 77-92-9 100.0 N.E. N.E. N.E. N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of
hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-
ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of
this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. Wear safety glasses with side shields (or
goggles) and a face shield.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information
regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
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