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Lebanon Seaboard Corporation

SAFETY DATA SHEET

Revision Date: 04/10/2015

Product Name: Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6

EPA No: 961-419

Recommended use

This product is a mixed fertilizer/herbicide for landscape use.

Supplier/Manufacturer

Lebanon Seaboard Corporation

1600 East Cumberland Street

Lebanon PA 17042 USA

Tel: (800) 233-0628 (717-273-1685) Supplier Email: customerservice@lebsea.com

Emergency telephone numbers in USA

800-233-0628 Chemtrec (Spill): 1-800-424-9300 Prosar (Health): 888-208-1368

Acute toxicity - Oral Category 4

Acute toxicity - Dermal Category 4

Acute toxicity - Inhalation (Dusts/Mists) Category 4

Carcinogenicity: Crystalline silica- IARC Group 1: sufficient evidence for carcinogenicity in humans .

The International Agency for Research on Cancer (IARC) lists chlorophenoxy herbicides in its Group 2B

(limited evidence for Carcinogenicity in humans.)

The US EPA has given the chlorophenoxy Herbicides 2,4-D

‡

, 2,4-DP, MCPP, and MCPA a Class D

classification (not classifiable as to human carcinogenicity.)

A recent World Health Organization (WHO) review of 2,4-D

‡

toxicology has concluded that 2,4-D is not a

carcinogen based on more current 2,4-D lifetime feeding studies in rats and mice did not show

carcinogenic effects.

‡

2, 4-Dichlorophenoxyacetic acid 2-ethylhexyl ester (2,4-D ester) is an analogue of 2,4-D. Toxicological and exposure

data is typically referenced to the related parent compound, 2,4-D, as is done here.

OSHA Signal Word: Danger

EPA Signal Word: Caution

Hazard Statements:

H302: Harmful if swallowed. (Category 4)

H313: May be harmful in contact with skin. (Category 5)

H333: May be harmful if inhaled. (Category 5)

H350: May cause cancer by repeated and prolonged inhalation. (Category 1B)

May irritate the digestive tract if ingested.

Keep out of reach of children.

Pictograms:

Precautionary Statements for handling: Also see Section 7.

P201: Obtain special instructions before use.

P202: Do not handle until all safety precautions have been read and understood.

P261: Avoid breathing dust.

P281: Use personal protective equipment as required.

P308: If exposed or concerned, seek medical advice.

P405: Store locked up.

P264: Wash hands thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P301+ 312: IF SWALLOWED: Rinse mouth. Immediately call a POISON CENTER or doctor/physician.

2. HAZARDS IDENTIFICATION

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

Summary of content (8 pages)

PAGE 1
Lebanon Seaboard Corporation SAFETY DATA SHEET Revision Date: 04/10/2015 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY Product Name: Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 EPA No: 961-419 Recommended use This product is a mixed fertilizer/herbicide for landscape use. Supplier/Manufacturer Lebanon Seaboard Corporation 1600 East Cumberland Street Lebanon PA 17042 USA Tel: (800) 233-0628 (717-273-1685) Supplier Email: customerservice@lebsea.
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Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 Revision Date: 04/10/2015 Precautionary Statements for disposal - Dispose in accordance with all federal, state and local regulations. Hazards not otherwise classified (HNOC): None Unknown acute toxicity <3% of the mixture consists of ingredients of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Dolomite* CAS No. Weight % 16389-88-1 23.68 2, 4-Dichlorophenoxyacetic acid 2-ethylhexyl ester (2,4-D ester) 1928-43-4 1.
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Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 Revision Date: 04/10/2015 Note: Excessive amounts of any burnable dusts can produce explosive mixtures if allowed to disperse in the air in confined areas where ignition sources occur. Prevent excessive dust dispersal in areas of use, storage, or production. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and standard protective gear.
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Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 Revision Date: 04/10/2015 Skin and Body Protection Gloves and coveralls recommended. Respiratory Protection Avoid breathing dust. Dust mask recommended for dusty or misty conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations.
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Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 Revision Date: 04/10/2015 Strong acids or alkali, or other reactive substances. Hazardous Decomposition Products May emit toxic fumes under fire conditions, such as Nitrogen oxides (NOx), Ammonia, Oxides of sulfur, Hydrogen chloride and Carbon monoxide. 11. TOXICOLOGICAL INFORMATION Product Toxicity: Acute Oral Toxicity: Acute Dermal Toxicity: Acute Inhalation Toxicity: >2000 mg/kg (rat) >2000 mg/kg (rabbit) >2.07 mg/l (rat).
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Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 Revision Date: 04/10/2015 The herbicide ingredients are toxic to aquatic invertebrates, fish, and aquatic plants. Use with care when applying to turf areas adjacent to any bodies of water. Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Drift and runoff from treated turf may adversely affect aquatic organisms in adjacent bodies of water.
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Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 Revision Date: 04/10/2015 TSCA STATUS: This product is exempt from TSCA Regulation under FIFRA Section 3(2)(G)(ii) when used as a pesticide. Hazardous Waste Regulations: Product contains more than 200 mg/Kg of 2,4-D ester.
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Preen Lawn Stepsaver Weed Control Plus Fertilizer 24-0-6 Revision Date: 04/10/2015 relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.