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SAMSUNG SDI Co., Ltd.

Date: January 1

2020 Revision no.: 01

MODEL INR18650-29E

Page 1 of 29

Safety Data Sheet

Regulation : In accordance with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR

1910.1200

Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF

THE COMPANY/UNDERTAKING

Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with

normal use. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the OSHA

Hazard Communication Standard requirement. The information contained in this Safety Data Sheet contains

valuable information critical to the safe handling and proper use of the product. This SDS should be retained

and available for employees and other users of this product.

1.1 Product identifier

Substance name : INR18650-29E

Substance name : Lithium-ion batteries

Synonyms :

Lithium-ion Cell, Lithium-ion Pack, Lithium-ion Battery, Li-Ion Cell, Li-Ion Pack, Li-Ion Battery

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses : Lithium-ion batteries

Uses advised against : Use for recommended use only

Further Information : Not available

1.3 Details of the supplier of the safety data sheet

Supplier : SAMSUNG SDI Co., Ltd.

Street address/P.O. Box : 150-20, Gongse-ro, Giheung-gu, Yongin-si, Gyeonggi-do, Korea

Country ID/Postcode/Place : KOR/17084

Telephone number : 1-800-424-9300: US and Canada / 1-703-527-3887: International

Responsible Department: Quality team

E-mail address of competent person responsible for the SDS : Not available

National contact : 1-800-424-9300: US and Canada / 1-703-527-3887: International

1.4 Emergency Telephone

: 1-800-424-9300: US and Canada / 1-703-527-3887: International

Opening hours : Not available

Other comments : Not available

1.5 Further Information

Battery-System: Lithium-ion (Li-ion)

Nominal Voltage: 3.65 V

Rated Capacity: 2.85 Ah

Wh rating: 10.4 Wh

Anode (negative electrode): based on intercalation graphite

Cathode (positive electrode): based on lithiated metal oxide (Cobalt, Nickel or Manganese)

Remark:

Summary of content (39 pages)

PAGE 1
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E Safety Data Sheet Regulation : In accordance with Regulation (EU) 2015/830 1910.1200 (REACH), Annex II, and OSHA 29 CFR Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with normal use. This battery is an article pursuant to 29 CFR 1910.
PAGE 2
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. SAMSUNG SDI Co., Ltd. makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities from reliance on it.
PAGE 3
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E Primary Routes(s) of Exposure: These chemicals are contained in a sealed enclosure. Risk of exposure occurs only if the cell or pack is mechanically, thermally, electrically or physically abused to the point of compromising the enclosure. If this occurs, exposure to the electrolyte solution contained within can occur by inhalation, ingestion, eye contact and skin contact.
PAGE 4
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E 7440-508 231-1596 - 10 Copper Cu Acute Tox. 4, H302 Eye Irrit. 2, H319 Acute Tox. 3, H331 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 1203165-1 620-4004 - 6 Lithium nickel dioxide Lithium nickelate Skin Sens. 1, H317 STOT RE 1, H372 ** Carc. 1A, H350i 7429-905 231-0723 - 5 Aluminium Al Pyr. Sol. 1, H250 Water-react. 2, H261(pyrophoric) Flam. Sol. 1, H228 Water-react.
PAGE 5
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E Section IV – FIRST-AID MEASURES 4.1 Description of first aid measures Following eye contact : - Rinse eyes with plenty of water for at least 15 minutes and seek medical attention. Following skin contact : - Remove contaminated clothing and wash before reuse. - Immediately rinse contact area with plenty of clean water. - Provide first aid to contacted area to prevent infection. - Get medical attention.
PAGE 6
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - In the event of a battery fire, cool it by spraying water directly on the battery. - When handling a overheated battery, wear heat-resistant protective equipment. Section VI – ACCIDENTAL RELEASE MEASURES 6.
PAGE 7
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E 7.2 Conditions for safe storage, including any incompatibilities Technical measures and storage conditions : Not available Packaging materials : Not available Requirements for storage rooms and vessels : - Storage at room temperature (approx. 20℃) at approx. 40% of the nominal capacity - Keep in closed original container. 7.
PAGE 8
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E Lithium hexafluorophosp hate(1-) Not applicable Not available Not applicable Not applicable Not applicable 3 Not available Not available TWA = 15 mppcf (mineral dusts) Not applicable Not applicable TWA = 2.5 mg/m (resp) Not applicable Not applicable Not available TWA = 1 mg/m³ Ca TWA = 0.
PAGE 9
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E 8.2 Exposure controls 8.2.1 Appropriate engineering controls : Substance/mixture related measures to prevent exposure during identified uses: - Avoid charging batteries in areas where hydrogen gas accumulate. - Use local exhaust ventilation to maintain concentrations of hydrogen below the Lower Explosive collect and transport flammable gases in ventilation systems.
PAGE 10
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E Section IX – PHYSICAL AND CHEMICAL PROPERTIES 9.
PAGE 11
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Keep away from heat/sparks/open flames/hot surfaces. No smoking. - Friction, heat, sparks or flames - Dusts or shavings from borings, turnings, cuttings, etc. - Do not exceed manufacturer’s recommendation for charging or use battery for an application for which it was not specifically designed. - Do not electrically short. 10.5 Incompatible materials - Avoid contact with acids and oxidizers.
PAGE 12
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Silicon : Rat LD50 > 5000 mg/kg (OECD Guideline 401, GLP) - Trade secret 2 : Rat LD50 = ca. 500 mg/kg (OECD Guideline 423, GLP) - Lithium carbonate : Rat LD50 = 525 mg/kg - Carbon black : Rat LD50 > 10000 mg/kg (OECD Guideline 401, GLP) - Carboxymethyl cellulose sodium salt : Rat LD50 = 27000 mg/kg (Food Research. Vol. 13, Pg. 29, 1948.
PAGE 13
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Dimethyl carbonate : In the skin irritation test using rabbits, the test material was not irritating. (OECD Guideline 404) - Polyethylene : In the skin irritation test using rabbits, the test material was mildly irritating. - Ethylene carbonate : In the skin irritation test using rabbits, the test material was not classified.
PAGE 14
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Graphite : In the eyes irritation test with rabbits, the test material was slightly irritating. it was fully reversible within 7 days. (OECD Guideline 405, GLP) - Ethyl methyl carbonate : In the eye irritation test using rabbits, the test material was not irritating. (OECD Guideline 405, GLP) - Nickel : In the eyes irritation test with rabbits, the test material was slightly irritating.
PAGE 15
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Graphite : In the skin sensitization test using mice, the test material was not skin sensitizing. (OECD Guideline 429, GLP) - Ethyl methyl carbonate : In the skin sensitization test using guinea pigs, the test material was not skin sensitizing. (OECD Guideline 406, GLP) - Nickel : Nickel hypersensitivity dermatitis may be initiated by contact with nickel on the skin.
PAGE 16
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Nickel IARC: Group 2B (Nickel, metallic and alloys) NTP: R OSHA: Present ACGIH: A5 KOREA-ISHL: Carcinogenicity2 (metal) EU Regulation 1272/2008: Carc.
PAGE 17
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Polyethylene : No toxicity was observed in in vitro mutagenicity test using Salmonella typhimurium strain. - Ethylene carbonate : Negative reactions were observed in vitro (Bacterial Reverse Mutation Assay(OECD Guideline 471, GLP)).
PAGE 18
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E In the developmental toxicity test using rabbits, adverse effects were not observed, respectively. (OECD Guideline 414, GLP) - Ethylene carbonate : In the reproductive toxicity test using mouse, adverse effects were not observed, respectively. (GLP) In the developmental toxicity test using rabbits, adverse effects were not observed, respectively.
PAGE 19
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Cobalt lithium dioxide : In the acute toxicity tests with rats, there were no signs of gross toxicity, adverse pharmacologic effects, or abnormal behaviour. (OECD Guideline 425, 402, GLP) - Dimethyl carbonate : In the acute oral toxicity test using rats, hypoactivity, ataxia and loss of the righting reflex were observed.
PAGE 20
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Cobalt lithium dioxide : In the repeated oral toxicity test in 90 days with rats, toxicity to organs was not observed. (OECD Guideline 408, GLP) - Dimethyl carbonate : In the repeated oral toxicity tests using rats, toxicity to organs was not observed. (OECD Guideline 408, GLP) - Polyethylene : Reported progressive systemic sclerosis in patients repeatedly exposed to chemicals.
PAGE 21
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Iron : 96hr-LC0(Danio rerio) > 100000 mg/L (OECD Guideline 203) - Copper : 96hr-LC50(Oncorhynchus mykiss) = 0.164 mg/L - Aluminium : 96hr-LC50(Pimephales promelas) = 1.16 mg/L (GLP) - Cobalt lithium dioxide : 96hr-LC50(Oncorhynchus mykiss) = 1.
PAGE 22
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.
PAGE 23
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Lithium carbonate : 21day-NOEC(Daphnia magna) = 1.7 mg/L (OECD Guideline 211, GLP) - Succinonitrile : 21day-NOEC(Daphnia magna) = 0.784 mg/L (OECD Guideline 211, GLP) Algae - Copper : 19day-NOEC(giant kelp Macrocystis pyrifera) = 0.0102 mg/L - Cobalt lithium dioxide : 72hr-NOEC(Pseudokirchneriella subcapitata) = 0.
PAGE 24
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E - Dimethyl carbonate : Bioaccumulation is expected to be low according to the BCF < 500 ( BCF < 3.2 ) - Lithium hexafluorophosphate(1-) : Bioaccumulation is expected to be low according to the BCF < 500 ( BCF = 53~58 ) - Nickel : Bioaccumulation is expected to be low according to the BCF < 500 ( BCF = 45 ) - 1-methyl-2-pyrrolidone : Bioaccumulation is expected to be low according to the BCF < 500 ( BCF = 3.
PAGE 25
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.
PAGE 26
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E Other EU regulations: - 1-Methyl-2-pyrrolidinone : Regulated (SVHC list) U.S.A regulations U.S.A management information (OSHA Regulation) : Not regulated U.S.A management information (CERCLA Regulation) : - Copper : 5,000 lb - Nickel : 100 lb U.S.A management information (EPCRA 302 Regulation) : Not regulated U.S.A management information (EPCRA 304 Regulation) : Not regulated U.S.
PAGE 27
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.
PAGE 28
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E Date Updated : 01 Feb. 2019 Version : Rev. 00 16.2 Abbreviations and acronyms ACGIH = American Conference of Government Industrial Hygienists CLP = Classification Labelling Packaging Regulation ; Regulation (EC) No 1272/2008 CAS No.
PAGE 29
SAMSUNG SDI Co., Ltd. Date: January 1st 2020 Revision no.: 01 MODEL INR18650-29E SIGMA-ALDRICH; http://www.sigmaaldrich.com/united-states.html Chemspider; http://www.chemspider.com/ IARC Monographs on the Evaluation of Carcinogenic Risks to Humans; http://monographs.iarc.fr National Toxicology Program; http://ntp.niehs.nih.gov/results/dbsearch/ TOMES-LOLI® ; http://www.rightanswerknowledge.com/loginRA.asp American Conference of Governmental Industrial Hygienists TLVs and BEIs.
PAGE 30
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 Date of issue: 16/09/2019 Revision date: 16/09/2019 Version: 1.0 SECTION 1: Identification 1.1. Identification Product form : Article Trade name : Li-MnO2 Button Cell(Lithium Metal Battery) Other means of identification : CR1220 40mAh Voltage : 3.0V Battery Weight: 0.78g 1.2.
PAGE 31
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Stainless Steel Manganese oxide (MnO2) (CAS-No.) 12597-68-1 (CAS-No.) 1313-13-9 66.666 19.615 Propylene carbonate (CAS-No.
PAGE 32
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 5.2. Specific hazards arising from the chemical Fire hazard : Battery can be overheated by an external source or by internal shorting and develop metal hydroxide mist. Toxic vapor may release in case of fire. Containers may explode when heated.
PAGE 33
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a cool and dry area, but prevent condensation on cell or battery terminals. High temperature may damage the performance of the battery. Protect from physical damage and short circuits.
PAGE 34
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 Skin and body protection: Under normal condition of use and handling no special protection is required for sealed battery. It is recommended to wear appropriate protective clothing when the battery case is broken.
PAGE 35
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.
PAGE 36
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
PAGE 37
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 Ethylene glycol dimethyl ether (110-71-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag S - S - indicates a substance that is identified in a final Significant New Use Rule. 15.2.
PAGE 38
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.
PAGE 39
Li-MnO2 Button Cell(Lithium Metal Battery) Safety Data Sheet This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 15.3. US State regulations No additional information available SECTION 16: Other information Issue date : 16/09/2019 Revision date : 16/09/2019 Data sources : Loli. ECHA reference.