Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 11 sds no. : 427527 V002.1 LOCTITE 454 Revision: 18.11.2013 printing date: 01.09.2014 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 454 Contains: Ethyl 2-cyanoacrylate 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 2 of 11 Hazard pictogram: Signal word: Warning Hazard statement: H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Supplemental information EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Precautionary statement: Prevention P261 Avoid breathing vapors. P280 Wear protective gloves/eye protection.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 3 of 11 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 EC Number REACH-Reg No.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 4 of 11 Eye contact: If the eye is bonded closed, release eyelashes with warm water by covering with wet pad. Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help to debond the adhesive. Keep eye covered until debonding is complete, usually within 1-3 days. Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 5 of 11 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. 7.2. Conditions for safe storage, including any incompatibilities For optimum shelf life store in original containers under refrigerated conditions at 2 - 8°C (35.6 - 46.4 °F) Do not store together with food or other consumables (coffee, tea, tobacco, etc.). 7.3.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 6 of 11 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 7 of 11 10.2. Chemical stability Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions See section reactivity 10.4. Conditions to avoid Stable under normal conditions of storage and use. 10.5. Incompatible materials See section reactivity 10.6. Hazardous decomposition products None if used for intended purpose. SECTION 11: Toxicological information 11.1.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 8 of 11 Skin corrosion/irritation: Hazardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 Result slightly irritating Exposure time 24 h Species Method rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Exposure time 72 h Species Method rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Test type Species Method Serious eye damage/irritation: Hazardous components CAS-No.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 9 of 11 Hazardous components CAS-No. Value type Value Bis(2-hydroxy-3-tert-butyl-5methylphenyl)methane 119-47-1 Bis(2-hydroxy-3-tert-butyl-5methylphenyl)methane 119-47-1 LC50 Bis(2-hydroxy-3-tert-butyl-5methylphenyl)methane 119-47-1 Hydroquinone 123-31-9 Hydroquinone 123-31-9 Hydroquinone 123-31-9 Exposure time Species > 500 mg/l Acute Toxicity Study Fish 48 h Oryzias latipes EC50 > 1.000 mg/l Daphnia 48 h EC50 > 1.
MSDS-No.: 427527 V002.1 LOCTITE 454 Page 10 of 11 Product disposal: Cured adhesive: Dispose of as water insoluble non-toxic solid chemical in authorised landfill or incinerate under controlled conditions. Dispose of in accordance with local and national regulations.
MSDS-No.: 427527 V002.1 LOCTITE 454 RID ADNR IMDG IATA 14.7. Page 11 of 11 not applicable not applicable not applicable Primary packs containing less than 500ml are unregulated by this mode of transport and may be shipped unrestricted. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content <3% (1999/13/EC) 15.2.
