Safety Data Sheet according to Regulation (EC) No1907/2006 Page 1 of 17 SDS No. : 450730 V004.1 LOCTITE 648 Revision: 07.07.2014 printing date: 04.09.2014 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 648 Contains: 2-Hydroxyethyl methacrylate Acrylic acid Hydroxypropyl methacrylate Maleic acid 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 2 of 17 Classification (DPD): Sensitizing R43 May cause sensitisation by skin contact. Xi - Irritant R36/37/38 Irritating to eyes, respiratory system and skin. 2.2. Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects.
MSDS-No.: 450730 V004.1 LOCTITE 648 Label elements (DPD): Xi - Irritant Risk phrases: R36/37/38 Irritating to eyes, respiratory system and skin. R43 May cause sensitisation by skin contact. Safety phrases: S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. Contains: 2-Hydroxyethyl methacrylate, Hydroxypropyl methacrylate, Maleic acid 2.3. Other hazards None if used properly.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 4 of 17 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. 3,3,5 Trimethylcyclohexyl methacrylate 7779-31-9 EC Number REACH-Reg No.
MSDS-No.: 450730 V004.
MSDS-No.: 450730 V004.1 LOCTITE 648 4.2. Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. SKIN: Rash, Urticaria. SKIN: Redness, inflammation. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 7 of 17 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Store at room temperature. Store in original containers at 8-21°C (46.4-69.8°F) and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product. 7.3. Specific end use(s) Adhesive SECTION 8: Exposure controls/personal protection 8.1.
MSDS-No.: 450730 V004.
MSDS-No.: 450730 V004.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 10 of 17 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 11 of 17 10.3. Possibility of hazardous reactions See section reactivity 10.4. Conditions to avoid Stable under normal conditions of storage and use. 10.5. Incompatible materials See section reactivity 10.6. Hazardous decomposition products carbon oxides. SECTION 11: Toxicological information 11.1.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 12 of 17 Acute dermal toxicity: Hazardous components CAS-No. Acrylic acid 79-10-7 Hydroxypropyl methacrylate 27813-02-1 Maleic acid 110-16-7 Methacrylic acid 79-41-4 Methacrylic acid 79-41-4 Value type LD50 Value 640 mg/kg Route of application dermal Exposure time Species Method rabbit BASF Test LD50 > 5.000 mg/kg dermal rabbit LD50 1.560 mg/kg dermal rabbit Acute toxicity estimate (ATE) LD50 500 mg/kg dermal Expert judgement 500 - 1.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 13 of 17 Repeated dose toxicity Hazardous components CAS-No.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 14 of 17 Hazardous components CAS-No.
MSDS-No.: 450730 V004.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 16 of 17 SECTION 13: Disposal considerations 13.1. Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. Contribution of this product to waste is very insignificant in comparison to article in which it is used Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated.
MSDS-No.: 450730 V004.1 LOCTITE 648 Page 17 of 17 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R10 Flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R21/22 Harmful in contact with skin and if swallowed. R23 Toxic by inhalation. R34 Causes burns. R35 Causes severe burns. R36 Irritating to eyes.
