Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 17 SDS No. : 173097 V004.0 Revision: 13.06.2017 printing date: 01.08.2017 Replaces version from: 29.07.2015 LOCTITE 640 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 640 Contains: Hydroxypropyl methacrylate Acrylic acid Cumene hydroperoxide 2,2'-Ethylenedioxydiethyl dimethacrylate 1.2.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 2 of 17 2.2. Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. Precautionary statement: "***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 3 of 17 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 EC Number REACH-Reg No. 203-652-6 01-2119969287-21 content Classification 20- 40 % Skin Sens. 1B H317 Hydroxypropyl methacrylate 27813-02-1 248-666-3 01-2119490226-37 5- < 10 % Acrylic acid 79-10-7 201-177-9 01-2119452449-31 5- < 10 % Skin Sens. 1 H317 Eye Irrit. 2 H319 Flam. Liq. 3 H226 Acute Tox.
MSDS-No.: 173097 V004.0 LOCTITE 640 4.2. Most important symptoms and effects, both acute and delayed After eye contact: Corrosive, may cause permanent damage to eyes (impairment of vision). SKIN: Redness, inflammation. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. SKIN: Rash, Urticaria. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 5 of 17 7.2. Conditions for safe storage, including any incompatibilities Store in sealed original container. Refer to Technical Data Sheet 7.3. Specific end use(s) Adhesive SECTION 8: Exposure controls/personal protection 8.1.
MSDS-No.: 173097 V004.
MSDS-No.: 173097 V004.0 80-15-9 .alpha.,.alpha.-Dimethylbenzyl hydroperoxide 80-15-9 .alpha.,.alpha.-Dimethylbenzyl hydroperoxide 80-15-9 .alpha.,.alpha.-Dimethylbenzyl hydroperoxide 80-15-9 .alpha.,.alpha.
MSDS-No.: 173097 V004.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 9 of 17 Biological Exposure Indices: None 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Use only in well-ventilated areas. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374).
MSDS-No.: 173097 V004.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 11 of 17 Acute oral toxicity: Hazardous components CAS-No. 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 Hydroxypropyl methacrylate 27813-02-1 Acrylic acid 79-10-7 Cumene hydroperoxide 80-15-9 Methacrylic acid 79-41-4 Value type LD50 Value 10.837 mg/kg Route of application oral LD50 > 2.000 mg/kg LD50 Exposure time Species Method rat not specified oral rat OECD Guideline 401 (Acute Oral Toxicity) 1.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 12 of 17 Serious eye damage/irritation: Hazardous components CAS-No.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 13 of 17 Reproductive toxicity: Hazardous substances CAS-No. 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 Hydroxypropyl methacrylate 27813-02-1 Result / Classification Species Exposure time Species Method OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) OECD Guideline 416 (TwoGeneration Reproduction Toxicity Study) NOAEL P = 1.000 mg/kg NOAEL F1 = 1.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 14 of 17 Hazardous components CAS-No.
MSDS-No.: 173097 V004.0 LOCTITE 640 Methacrylic acid 79-41-4 EC10 Page 15 of 17 100 mg/l Bacteria 17 h not specified 12.2. Persistence and degradability Persistence and Biodegradability: No data available for the product. Hazardous components CAS-No.
MSDS-No.: 173097 V004.0 LOCTITE 640 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 Hydroxypropyl methacrylate 27813-02-1 Acrylic acid 79-10-7 Cumene hydroperoxide 80-15-9 Methacrylic acid 79-41-4 Page 16 of 17 Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.
MSDS-No.: 173097 V004.0 LOCTITE 640 Page 17 of 17 SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content <5% (2010/75/EC) 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2.
