Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 15 SDS No. : 313071 V005.3 Revision: 08.01.2019 printing date: 14.08.2019 Replaces version from: 16.07.2015 LOCTITE 4860 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 4860 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 2 of 15 Hazard pictogram: Ethyl 2-cyanoacrylate Contains Triethyl O-acetylcitrate Signal word: Warning Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Supplemental information EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Precautionary statement: Prevention P261 Avoid breathing vapors.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 3 of 15 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 EC Number REACH-Reg No. 230-391-5 01-2119527766-29 content Classification 25- 50 % Eye Irrit. 2 H319 STOT SE 3 H335 Skin Irrit. 2 H315 Skin Sens. 1 H317 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Carc. 2 H351 Muta. 2 H341 Acute Tox. 4; Oral H302 Eye Dam. 1 H318 Skin Sens. 1 H317 M factor (Acute Aquat Tox): 10 Org. Perox.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 4 of 15 4.2. Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. SKIN: Redness, inflammation. SKIN: Rash, Urticaria. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 5 of 15 7.3. Specific end use(s) Adhesive SECTION 8: Exposure controls/personal protection 8.1.
SDS No.: 313071 V005.
SDS No.: 313071 V005.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 8 of 15 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.
SDS No.: 313071 V005.3 LOCTITE 4860 Oxidising properties Page 9 of 15 No data available / Not applicable 9.2. Other information No data available / Not applicable SECTION 10: Stability and reactivity 10.1. Reactivity Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols. 10.2. Chemical stability Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions See section reactivity 10.4.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 10 of 15 Acute inhalative toxicity: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Hazardous substances CAS-No. Dibenzoyl peroxide 94-36-0 Value type LC50 Value > 24,3 mg/l Test atmosphere Exposure time vapour 4h Species Method rat not specified Skin corrosion/irritation: Bonds skin in seconds.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 11 of 15 STOT-single exposure: No data available. STOT-repeated exposure:: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Hazardous substances CAS-No. Hydroquinone 123-31-9 Result / Value Route of application NOAEL >= 250 mg/kg oral: gavage Exposure time / Frequency of treatment 14 days 5 days/week.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 12 of 15 Toxicity (Algae): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Hazardous substances CAS-No.
SDS No.: 313071 V005.3 LOCTITE 4860 Hazardous substances CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 Triethyl O-acetylcitrate 77-89-4 Hydroquinone 123-31-9 Dibenzoyl peroxide 94-36-0 Page 13 of 15 LogPow Temperature Method 0,776 22 °C EU Method A.8 (Partition Coefficient) 1,34 not specified 0,59 EU Method A.8 (Partition Coefficient) 3,2 22 °C OECD Guideline 117 (Partition Coefficient (n-octanol / water), HPLC Method) 12.5. Results of PBT and vPvB assessment Hazardous substances CAS-No.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 14 of 15 SECTION 14: Transport information 14.1. UN number ADR RID ADN IMDG IATA 14.2. UN proper shipping name ADR RID ADN IMDG IATA 14.3. not applicable not applicable not applicable not applicable not applicable Special precautions for user ADR RID ADN IMDG IATA 14.7. Not dangerous goods Not dangerous goods Not dangerous goods Not dangerous goods III Environmental hazards ADR RID ADN IMDG IATA 14.6.
SDS No.: 313071 V005.3 LOCTITE 4860 Page 15 of 15 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H241 Heating may cause a fire or explosion. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation.
