Safety Data Sheet according to (EC) No 1907/2006 Page 1 of 13 SDS No. : 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Revision: 08.06.2015 printing date: 08.02.2016 Replaces version from: 13.03.2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE® 4204 INSTANT ADHESIVE Contains: Ethyl 2-cyanoacrylate 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 2 of 13 Hazard pictogram: Signal word: Warning Hazard statement: H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. Supplemental information EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Contains Phthalic anhydride. May produce an allergic reaction.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 3 of 13 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 EC Number REACH-Reg No. 230-391-5 01-2119527766-29 content Classification > 50- < 100 % Eye Irrit. 2 H319 STOT SE 3 H335 Skin Irrit.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 4 of 13 Ingestion: Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly separate the solidified product from the mouth (several hours). 4.2. Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. SKIN: Redness, inflammation. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. 4.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 5 of 13 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Store in a cool, dry place. For optimum shelf life store in original containers under refrigerated conditions at 2 - 8°C (35.6 - 46.4 °F) 7.3. Specific end use(s) Adhesive SECTION 8: Exposure controls/personal protection 8.1.
MSDS-No.: 332387 V001.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE pH Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties Page 7 of 13 No data available / Not applicable > 149 °C (> 300.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 8 of 13 Inhalative toxicity: May cause respiratory irritation. Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals In dry atmosphere with < 50% humidity, vapours may irritate the eyes and respiratory system Skin irritation: Causes skin irritation. Bonds skin in seconds.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 9 of 13 Respiratory or skin sensitization: Hazardous components CAS-No.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Hazardous components CAS-No. Value type Value Bismaleimide 105391-33-1 LC50 Phthalic anhydride 85-44-9 Phthalic anhydride 85-44-9 Page 10 of 13 Exposure time Species Method 0,5 mg/l Acute Toxicity Study Fish 48 h Oryzias latipes LC50 313 mg/l Fish 48 h Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) DIN 38412-15 EC50 68 mg/l Algae 72 h Selenastrum sp.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Phthalic anhydride 85-44-9 Hydroquinone 123-31-9 Page 11 of 13 Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Not fulfilling PBT (persistent/bioaccummulative/toxic) criteria 12.6. Other adverse effects No data available. SECTION 13: Disposal considerations 13.1.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 12 of 13 SECTION 14: Transport information 14.1. UN number ADR RID ADN IMDG IATA 14.2. UN proper shipping name ADR RID ADN IMDG IATA 14.3. not applicable not applicable not applicable not applicable not applicable Special precautions for user ADR RID ADN IMDG IATA 14.7. Not dangerous goods Not dangerous goods Not dangerous goods Not dangerous goods III Environmental hazards ADR RID ADN IMDG IATA 14.6.
MSDS-No.: 332387 V001.1 LOCTITE® 4204 INSTANT ADHESIVE Page 13 of 13 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
