Safety Data Sheet according to (EC) No 1907/2006 as amended Page 1 of 20 SDS No. : 332387 V003.1 Revision: 20.05.2021 printing date: 13.09.2021 Replaces version from: 09.05.2019 LOCTITE 4204 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 4204 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 2 of 20 Hazard pictogram: Contains Ethyl 2-cyanoacrylate S ignal word: Warning Hazard statement: H315 Causes skin irritation. H319 Causes serious eye irritation. H335 M ay cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. S upplemental information Contains: phthalic anhydride; M ethyl acrylate; maleic anhydride M ay produce an allergic reaction. Cyanoacrylate. Danger. Bonds skin and eyes in seconds.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 3 of 20 Declaration of the ingredients according to CLP (EC) No 1272/2008: Haz ardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 EC Number REACH-Reg No. 230-391-5 01-2119527766-29 content Classification 50- 100 % Eye Irrit. 2 H319 ST OT SE 3 H335 Skin Irrit.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 4 of 20 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: M ove to fresh air. If symptoms persist, seek medical advice. Skin contact: Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water. Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 5 of 20 6.2. Environmental precautions Do not empty into drains / surface water / ground water. 6.3. Methods and material for containment and cleaning up Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor. Cured material can be disposed of as non-hazardous waste. Dispose of contaminated material as waste according to Section 13. 6.4.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 6 of 20 SECTION 8: Exposure controls/personal protection 8.1.
SDS No.: 332387 V003.1 Methyl acrylate 96-33-3 [MET HYL ACRYLATE] Methyl acrylate 96-33-3 [MET HYL ACRYLATE] Hydroquinone 123-31-9 [HYDROQUINONE] Maleic anhydride 108-31-6 [MALEIC ANHYDRIDE] LOCTITE 4204 10 0,01 Page 7 of 20 Skin designation: Can be absorbed through the skin.
SDS No.: 332387 V003.
SDS No.: 332387 V003.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 10 of 20 Biological Exposure Indices: None 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Polyethylene or polypropylene gloves are recommended when using large volumes.
SDS No.: 332387 V003.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 12 of 20 SECTION 11: Toxicological information General toxicological information: Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth. Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals In dry atmosphere with < 50% humidity, vapours may irritate the eyes and respiratory system 11.1.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 13 of 20 Acute inhalative toxicity: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 14 of 20 Germ cell mutagenicity: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 15 of 20 Carcinogenicity The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous components CAS-No.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 16 of 20 Aspiration hazard: No data available. SECTION 12: Ecological information General ecological information: Do not empty into drains / surface water / ground water. Biological and Chemical Oxygen Demands (BOD and COD) are insignificant. 12.1. Toxicity Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 17 of 20 Toxicity (Algae): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 18 of 20 12.4. Mobility in soil Haz ardous substances CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 phthalic anhydride 85-44-9 Methyl acrylate 96-33-3 Hydroquinone 123-31-9 maleic anhydride 108-31-6 LogPow Temperature Method 0,776 22 °C EU Method A.8 (Partition Coefficient) 1,6 EU Method A.8 (Partition Coefficient) 0,739 25 °C 0,59 OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask Method) EU Method A.
SDS No.: 332387 V003.1 LOCTITE 4204 Page 19 of 20 SECTION 14: Transport information 14.1. UN number ADR RID ADN IM DG IATA 14.2. Not dangerous Not dangerous Not dangerous Not dangerous III goods goods goods goods not applicable not applicable not applicable not applicable not applicable S pecial precautions for user ADR RID ADN IM DG IATA 14.7. goods goods goods goods Environmental hazards ADR RID ADN IM DG IATA 14.6.
SDS No.: 332387 V003.1 VOC content (2010/75/EC) LOCTITE 4204 Page 20 of 20 <3% 15.2. Chemical safety assessment A chemical safety assessment has been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H225 Highly flammable liquid and vapor. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage.
