SDS
SAFETY DATA SHEET
The Libman Company LIBMAN TOILET BOWL CLEANER ITEM # 2070
The Libman Company Page 2 of 7
Response Statement(s):
P305+P351+P338: IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337+P313P: IF EYE IRRITATION PERSISTS: Get medical
advice / attention.
P332+P313: If skin irritation occurs: Get medical advice /
attention.
P308+P313: IF exposed or concerned: Get medical
advice/attention.
Storage Statement(s):
P403+P235: Store in a well-ventilated place. Keep cool
P405: Store locked up.
Disposal Statement(s):
P501: Dispose of contents/container in accordance
with local/regional/national/international regulations
2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE:
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this
product are by contact with eyes and skin. The symptoms of overexposure are described in the following paragraphs.
ACUTE:
INHALATION: May cause mild respiratory system irritation.
CONTACT WITH SKIN: May cause mild to moderate irritation.
EYE CONTACT: Avoid contact with the eyes. May cause severe irritation, swelling, tearing, or redness.
INGESTION: May cause irritation to the gastrointestinal tract, diarrhea, nausea or vomiting.
CHRONIC: No data available.
TARGET ORGANS: Acute: Eyes, Skin Chronic: No data available
SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS
Hazardous Ingredients: WT%
CAS# EINECS # Hazard Classification
Borax 2-5% 1303-96-4 Not listed
Reproductive Hazard Category 1B
Sodium Xylene Sulfonate 1-4% 1300-72-7 215-090-9
Eye Irritant Category 2
Lauramine Oxide <2% 1643-20-5 216-700-6
Skin Irrit. Cat 2, Eye Dam. Cat 1, Aquatic Acute Cat 1
Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or
respiratory sensitizers).
NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese
Industrial Standard JIS Z 7250: 2000
4. FIRST-AID MEASURES
4.1 DESCRIPTION OF FIRST AID MEASURES:
EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for several minutes. Remove
contact lenses if present and easy to do. Continue rinseing for at least 15 minutes. Seek medical attention.
SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists.
Remove contaminated clothing. Launder before re-use.
INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to
support vital functions. Seek medical attention.
INGESTION: If product is swallowed, call physician or poison control center for most current information. If
professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to
someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the
label and/or SDS with the victim to the health professional.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin or eye problems may be aggravated by
prolonged contact.
4.2 SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
Contact with eyes may cause severe irritation with redness and tearing
4.3 RECOMMENDATIONS TO PHYSICIANS:
Treat symptoms and eliminate overexposure.