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SAFETY DATA SHEET

The Libman Company LIBMAN TOILET BOWL CLEANER ITEM # 2070

The Libman Company Page 1 of 7

Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Directives

SECTION 1. PRODUCT IDENTIFICATION

1.1 TRADE NAME (AS LABELED): Libman Toilet Bowl Cleaner Item #2070

SYNONYMS: N/A

CAS#: Mixture

1.2 PRODUCT USE: Clean and freshen the inside of a toilet.

1.3 MANUFACTURER'S NAME: The Libman Company

ADDRESS: 220 North Sheldon Arcola, IL 61910

BUSINESS PHONE: 1-877-818-3380

WEB SITE INFORMATION: www.libman.com

1.4 EMERGENCY PHONE NUMBERS: 1-877-818-3380

DATE OF CURRENT REVISION: November 11, 2015

DATE OF LAST REVISION: New

SECTION 2. HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: This product is a pale blue liquid with bubbles and a fresh scent.

Health Hazards: May cause serious eye irritation. May be irritating to the skin. May be a reproductive hazard.

Flammability Hazards: This product is considered a Non-Flammable liquid.

Reactivity Hazards: None.

Environmental Hazards: The environmental effects of this product have not been investigated, however release may

cause adverse environmental effects.

US DOT SYMBOLS CANADA (WHMIS) SYMBOL(S) EUROPEAN and (GHS) Hazard Symbol(s)

Non-Regulated

Material

Classified per WHMIS 2015

Signal Word: Danger!

2.1 EU LABELING AND CLASSIFICATION:

This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council

Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives.

EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC:

Index Number:

CAS# 1303-96-4 is not listed in Annex VI

216-700-6 is not listed in Annex VI

215-090-9 is not listed in Annex VI

Substances not listed either individually or in group entries must be self classified.

Component(s) Contributing to Classification(s)

Borax, Lauramine oxide, Sodium xylene sulfonate

2.2 LABEL ELEMENTS

GHS Hazard Classification(s):

Serious Eye Irritation Category 2A

Skin Irritation Category 3

Aquatic Acute Category 3

Reproductive Toxicity Category 1B

Hazard Statement(s): Precautionary Statement(s):

H319: Causes serious eye irritation

H316: Causes mild skin irritation

H402: Harmful to aquatic life

H360: May damage fertility or the unborn child

P264: Wash thoroughly after handling.

P280: Use protective gloves/protective clothing/eye

protection/face protection.

P273: Avoid release to the environment.

P201: Obtain special instructions before use.

P202: Do not handle until all safety precautions have

been read and understood.

Summary of content (7 pages)

PAGE 1
SAFETY DATA SHEET The Libman Company LIBMAN TOILET BOWL CLEANER ITEM # 2070 Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Directives SECTION 1. PRODUCT IDENTIFICATION 1.1 TRADE NAME (AS LABELED): SYNONYMS: CAS#: 1.2 PRODUCT USE: 1.3 MANUFACTURER'S NAME: ADDRESS: BUSINESS PHONE: WEB SITE INFORMATION: 1.
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The Libman Company SAFETY DATA SHEET LIBMAN TOILET BOWL CLEANER ITEM # 2070 Response Statement(s): Storage Statement(s): P305+P351+P338: IF IN EYES: Rinse cautiously with water P403+P235: Store in a well-ventilated place. Keep cool for several minutes. Remove contact lenses, if present and P405: Store locked up. easy to do. Continue rinsing. Disposal Statement(s): P337+P313P: IF EYE IRRITATION PERSISTS: Get medical P501: Dispose of contents/container in accordance advice / attention.
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The Libman Company SAFETY DATA SHEET LIBMAN TOILET BOWL CLEANER ITEM # 2070 SECTION 5. FIRE-FIGHTING MEASURES 5.1 FIRE EXTINGUISHING MATERIALS: Use fire extinguishing methods below: Water Spray: Yes Carbon Dioxide: Yes Foam: Yes Dry Chemical: Yes Halon: Yes Other: Any “C” Class 5.2 UNUSUAL FIRE AND EXPLOSION HAZARDS: Irritating and toxic fumes may be produced at high temperature. Use of water may result in the formation of a toxic aqueous solution.
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SAFETY DATA SHEET The Libman Company LIBMAN TOILET BOWL CLEANER ITEM # 2070 7.3 SPECIFIC USES: Clean and freshen the inside of a toilet. SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 EXPOSURE PARAMETERS: Chemical Name Borax Sodium Xylene Sulfonate Lauramine Oxide CAS# 1303-96-4 1300-72-7 1643-20-5 ACGIH TLV 5 mg/mᵌ Not listed Not listed OSHA TWA 10 mg/mᵌ Not listed Not listed 8.
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The Libman Company SAFETY DATA SHEET LIBMAN TOILET BOWL CLEANER ITEM # 2070 SECTION 10. STABILITY and REACTIVITY 10.1 REACTIVITY: This product is not reactive 10.2 STABILITY: Stable under conditions of normal storage and use. 10.3 POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur. 10.4 CONDITIONS TO AVOID: Avoid freezing and excessive temperatures. 10.5 MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Acids and oxidizing agents. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS: No data available. SECTION 11.
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The Libman Company 13.2 EU WASTE CODE: Not determined SAFETY DATA SHEET LIBMAN TOILET BOWL CLEANER ITEM # 2070 SECTION 14. TRANSPORTATION INFORMATION US DOT, IATA, IMO, ADR: 14.1 U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS: This product is classified (per 49 CFR 172.101) by the U.S. Department of Transportation, as follows.
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The Libman Company SAFETY DATA SHEET LIBMAN TOILET BOWL CLEANER ITEM # 2070 15.5 JAPANESE INFORMATION FOR PRODUCT: JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of this product are not listed as Class I Specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances by the Japanese MITI. 15.