SDS

SAFETY DATA SHEET
The Libman Company LIBMAN TUB AND TILE ITEM # 2069
The Libman Company Page 2 of 7
2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE:
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this
product are by contact with eyes. The symptoms of overexposure are described in the following paragraphs.
ACUTE:
INHALATION: May cause mild respiratory system irritation.
CONTACT WITH SKIN: May cause mild irritation.
EYE CONTACT: Avoid contact with the eyes. May cause severe irritation, swelling, tearing, or redness.
INGESTION: May cause irritation to the gastrointestinal tract, diarrhea, nausea or vomiting.
CHRONIC: No data available.
TARGET ORGANS: Acute: Eyes Chronic: No data available
SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS
Hazardous Ingredients: WT%
CAS# EINECS # Hazard Classification
Citric acid 6-8% 77-92-9 201-069-1
Eye Irritant Category 2
Alcohols, C9-11, ethoxylated <2% 68439-46-3 Not listed
Eye Damage 1, Acute Toxicity Category 4 (Oral)
Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or
respiratory sensitizers).
NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese
Industrial Standard JIS Z 7250: 2000
4. FIRST-AID MEASURES
4.1 DESCRIPTION OF FIRST AID MEASURES:
EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for several minutes. Remove
contact lenses if present and easy to do. Continue rinseing for at least 15 minutes. Seek medical attention.
SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists.
Remove contaminated clothing. Launder before re-use.
INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to
support vital functions. Seek medical attention.
INGESTION: If product is swallowed, call physician or poison control center for most current information. If
professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to
someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the
label and/or SDS with the victim to the health professional.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin or eye problems may be aggravated by
prolonged contact.
4.2 SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
Contact with eyes may cause severe irritation with redness and tearing
4.3 RECOMMENDATIONS TO PHYSICIANS:
Treat symptoms and eliminate overexposure.
SECTION 5. FIRE-FIGHTING MEASURES
5.1 FIRE EXTINGUISHING MATERIALS:
Use fire extinguishing methods below:
Water Spray: Yes Carbon Dioxide: Yes
Foam: Yes Dry Chemical: Yes
Halon: Yes Other: Any “C” Class
5.2 UNUSUAL FIRE AND EXPLOSION HAZARDS:
Irritating and toxic fumes may be produced at high temperature. Use of water may result in the formation of a toxic
aqueous solution. Do not allow run-off from fire fighting to enter drains or water courses.
Explosion Sensitivity to Mechanical Impact: No
Explosion Sensitivity to Static Discharge: No