SAFETY DATA SHEET 03611 Section 1. Identification Product name Product code Other means of identification : KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Paint (APWA) Red : 03611 : Not available. Product type : Aerosol. Relevant identified uses of the substance or mixture and uses advised against Not applicable.
Section 2. Hazards identification Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. May damage the unborn child. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure.
Section 3. Composition/information on ingredients Ingredient name % by weight CAS number Toluene Propane Butane Lt. Aliphatic Hydrocarbon Solvent 1-Methyl-2-Pyrrolidone 21.6 12.2 5.8 1.7 0.1 108-88-3 74-98-6 106-97-8 64742-89-8 872-50-4 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Section 4.
Section 5. Fire-fighting measures Special protective actions for fire-fighters Special protective equipment for fire-fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Section 8. Exposure controls/personal protection Hygiene measures Eye/face protection : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Section 9. Physical and chemical properties Viscosity : Kinematic (room temperature): <0.07 cm2/s (<7 cSt) Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt) Aerosol product Type of aerosol : Spray Heat of combustion : 0.00002232 kJ/g Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable.
Section 11. Toxicological information Mutagenicity Not available. Carcinogenicity Not available. Classification Product/ingredient name OSHA IARC NTP Toluene - 3 - Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity (single exposure) Name Category Route of exposure Target organs Toluene Category 3 Not applicable. Propane Category 3 Not applicable. Butane Category 3 Not applicable. Lt.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.
Section 12. Ecological information Toxicity Product/ingredient name Result Species Exposure Toluene Acute EC50 12500 µg/l Fresh water 72 hours Acute LC50 5500 µg/l Fresh water Chronic NOEC 1000 µg/l Fresh water Acute LC50 >100000 ppm Fresh water Algae - Pseudokirchneriella subcapitata Crustaceans - Gammarus pseudolimnaeus - Adult Daphnia - Daphnia magna Juvenile (Fledgling, Hatchling, Weanling) Fish - Oncorhynchus kisutch - Fry Daphnia - Daphnia magna Fish - Oncorhynchus mykiss Acute LC50 1.
Section 14. Transport information DOT Classification TDG Classification Mexico Classification IATA IMDG UN number UN1950 UN1950 UN1950 UN1950 UN1950 UN proper shipping name AEROSOLS AEROSOLS AEROSOLS AEROSOLS, flammable AEROSOLS Transport hazard class(es) 2.1 2.1 2.1 Packing group - - - - - Environmental hazards No. No. No. No. No.
Section 16. Other information Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J.