SDS

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Safety Data Sheet

According to OSHA HCS 2012 (29 CFR 1910.1200), Health Canada HPR (SOR/2015-17), and Mexico NOM-018-STPS-2015

SECTION 1: Identification

Product Identifier

John Deere Turf-Gard® Supreme Motor Oil

Other means of identification

John Deere Turf-Gard® Supreme Motor Oil, SAE 10W-30

Code 776105

Issue date

19-Nov-2019

Relevant identified uses

Automotive Engine Oil

Uses advised against

All others

24 Hour Emergency Phone Number

CHEMTREC: 1-800-424-9300

CHEMTREC Mexico 01-800-681-9531

CHEMTREC Global +1 703 527 3887

Manufacturer/Supplier

Phillips 66 Lubricants

A Division of Phillips 66 Company

P.O. Box 421959

Houston, Texas 77242-1959

SDS Information

URL: www.phillips66.com/SDS

Phone: 800-762-0942

Email: SDS@P66.com

Customer Service

U.S.: 800-368-7128 or International: 1-832-765-2500

Technical Information

1-877-445-9198

SECTION 2: Hazard identification

SECTION 4: First aid measures

Eye Contact: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical

attention.

Skin Contact: First aid is not normally required. However, it is good practice to wash any chemical from the skin.

Inhalation: First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and into

fresh air in a position comfortable for breathing. Seek immediate medical attention.

Classified Hazards Hazards Not Otherwise Classified (HNOC)

No classified hazards

PHNOC: None known

HHNOC: None known

Label elements

SECTION 3: Composition/information on ingredients

Chemical Name CASRN Concentration¹

Distillates, petroleum, hydrotreated heavy

paraffinic

64742-54-7 <100

¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

No classified hazards

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

776105 - John Deere Turf-Gard® Supreme Motor Oil

Page 1/7

Issue date: 19-Nov-2019 Status: FINAL

Summary of content (33 pages)

PAGE 1
Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.
PAGE 2
776105 - John Deere Turf-Gard® Supreme Motor Oil Page 2/7 Issue date: 19-Nov-2019 Status: FINAL _____________________________________________________________________ Ingestion: First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Most important symptoms and effects, both acute and delayed: Inhalation of oil mists or vapors generated at elevated temperatures may cause respiratory irritation.
PAGE 3
776105 - John Deere Turf-Gard® Supreme Motor Oil Page 3/7 Issue date: 19-Nov-2019 Status: FINAL _____________________________________________________________________ disposal, in accordance with local regulations. Recommended measures are based on the most likely spillage scenarios for this material; however local conditions and regulations may influence or limit the choice of appropriate actions to be taken. See Section 13 for information on appropriate disposal.
PAGE 4
776105 - John Deere Turf-Gard® Supreme Motor Oil Page 4/7 Issue date: 19-Nov-2019 Status: FINAL _____________________________________________________________________ SECTION 9: Physical and chemical properties Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications.
PAGE 5
776105 - John Deere Turf-Gard® Supreme Motor Oil Page 5/7 Issue date: 19-Nov-2019 Status: FINAL _____________________________________________________________________ Specific Target Organ Toxicity (Single Exposure): No information available on the mixture, however none of the components have been classified for target organ toxicity (or are below the concentration threshold for classification).
PAGE 6
776105 - John Deere Turf-Gard® Supreme Motor Oil Page 6/7 Issue date: 19-Nov-2019 Status: FINAL _____________________________________________________________________ UN Number: Not regulated UN proper shipping name: None Transport hazard class(es): None Packing Group: None Environmental Hazard(s): This product does not meet the DOT/UN/IMDG/IMO criteria of a marine pollutant Special precautions for user: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, P
PAGE 7
76105 - John Deere Turf-Gard® Supreme Motor Oil Page 7/7 Issue date: 19-Nov-2019 Status: FINAL _____________________________________________________________________ adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use.
PAGE 8
SAFETY DATA SHEET Issuing Date 20-Jul-2017 Revision Date 20-Jul-2017 Revision Number 1 NGHS / English _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
PAGE 9
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Serious eye damage/eye irritation Carcinogenicity Reproductive toxicity Effects on or via lactation Specific target organ toxicity (repeated exposure) Corrosive to metals Category 1 Category 1A Category 1A Yes Category 1 Category 1 This is a battery. In case of rupture: the above hazards exist.
PAGE 10
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Spill Absorb spillage to prevent material damage Precautionary Statements - Storage Store locked up Store in a well-ventilated place.
PAGE 11
10599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get immediate medical advice/attention.
PAGE 12
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ breathe dust. Refer to protective measures listed in Sections 7 and 8. Other Information Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7.
PAGE 13
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). See section 15 for national exposure control parameters. Other Exposure Guidelines Appropriate engineering controls Showers Eyewash stations Ventilation systems.
PAGE 14
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Dynamic viscosity No data available Other Information Explosive properties Oxidizing properties Softening Point Molecular Weight VOC Content (%) Liquid Density Bulk Density Particle Size Particle Size Distribution No information available No information available No information available No information available No information available N
PAGE 15
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Information on toxicological effects Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Difficulty in breathing. Numerical measures of toxicity Acute Toxicity The following values are calculated based on chapter 3.1 of the GHS document . 624.00 mg/kg ATEmix (oral) 4,500.
PAGE 16
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ X - Present Reproductive toxicity Classification based on data available for ingredients. Contains a known or suspected reproductive toxin. May cause harm to breastfed babies. STOT - single exposure No information available. STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure.
PAGE 17
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ California Hazardous Waste Codes 792 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical name Lead 7439-92-1 Sulfuric acid 7664-93-9 Antimony 7440-36-0 California Hazardous Waste Toxic Toxic Corrosive Toxic 14. TRANSPORT INFORMATION DOT UN-No.
PAGE 18
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ RID UN-No. Proper Shipping Name Hazard Class Classification code Description ADR/RID-Labels UN2794 BATTERIES, WET, FILLED WITH ACID 8 C11 UN2794, BATTERIES, WET, FILLED WITH ACID, 8 8 ADR UN-No.
PAGE 19
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).
PAGE 20
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Chemical name New Jersey Massachusett Pennsylvania Rhode Island s X X X X Lead 7439-92-1 Sulfuric acid 7664-93-9 Antimony 7440-36-0 Illinois X X X X X X X X X X X 16.
PAGE 21
SAFETY DATA SHEET Issuing Date 20-Jul-2017 Revision Date 20-Jul-2017 Revision Number 1 NGHS / English _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
PAGE 22
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Serious eye damage/eye irritation Carcinogenicity Reproductive toxicity Effects on or via lactation Specific target organ toxicity (repeated exposure) Corrosive to metals Category 1 Category 1A Category 1A Yes Category 1 Category 1 This is a battery. In case of rupture: the above hazards exist.
PAGE 23
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Spill Absorb spillage to prevent material damage Precautionary Statements - Storage Store locked up Store in a well-ventilated place.
PAGE 24
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get immediate medical advice/attention.
PAGE 25
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ breathe dust. Refer to protective measures listed in Sections 7 and 8. Other Information Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7.
PAGE 26
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). See section 15 for national exposure control parameters. Other Exposure Guidelines Appropriate engineering controls Showers Eyewash stations Ventilation systems.
PAGE 27
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Dynamic viscosity No data available Other Information Explosive properties Oxidizing properties Softening Point Molecular Weight VOC Content (%) Liquid Density Bulk Density Particle Size Particle Size Distribution No information available No information available No information available No information available No information available N
PAGE 28
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Information on toxicological effects Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Difficulty in breathing. Numerical measures of toxicity Acute Toxicity The following values are calculated based on chapter 3.1 of the GHS document . 624.00 mg/kg ATEmix (oral) 4,500.
PAGE 29
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ X - Present Reproductive toxicity Classification based on data available for ingredients. Contains a known or suspected reproductive toxin. May cause harm to breastfed babies. STOT - single exposure No information available. STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure.
PAGE 30
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ California Hazardous Waste Codes 792 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical name Lead 7439-92-1 Sulfuric acid 7664-93-9 Antimony 7440-36-0 California Hazardous Waste Toxic Toxic Corrosive Toxic 14. TRANSPORT INFORMATION DOT UN-No.
PAGE 31
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ RID UN-No. Proper Shipping Name Hazard Class Classification code Description ADR/RID-Labels UN2794 BATTERIES, WET, FILLED WITH ACID 8 C11 UN2794, BATTERIES, WET, FILLED WITH ACID, 8 8 ADR UN-No.
PAGE 32
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).
PAGE 33
1110599 - LEAD ACID BATTERY WET FILLED WITH Revision Date 20-Jul-2017 ACID _____________________________________________________________________________________________ Chemical name New Jersey Massachusett Pennsylvania Rhode Island s X X X X Lead 7439-92-1 Sulfuric acid 7664-93-9 Antimony 7440-36-0 Illinois X X X X X X X X X X X 16.