SAFETY DATA SHEET Issuing Date 27-Oct 2014 Revision Date 20-Oct-2014 Revision Number 1 1.
Prevention Response Storage Disposal Hazards not otherwise classified Wear protective gloves. Wear eye or face protection. Avoid breathing dust. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Skin contact Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Irritating to mouth, throat and stomach. Over-exposure signs/symptoms Inhalation No specific data. Skin contact Adverse symptoms may include the following: irritation redness Adverse symptoms may include the Eye contact following: pain or irritation watering redness No specific data.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from personnel entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Occupational exposure limits Ingredient name CAS # Exposure limits carbon black respirable 1333-86-4 OSHA PEL 1989 (United States, 3/1989). TWA: 3.5 mg/m³ 8 hours. ACGIH TLV (United States, 6/2013). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 3.5 mg/m³ 8 hours.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Color Odor Odor threshold Solid. Black. Ethereal. Not available. pH Not available. Not available. Not available. [Product does not sustain combustion.] Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Solubility in water Auto-ignition temperature Decomposition temperature Viscosity VOC (% content) Not available.
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Symptoms related to the physical, chemical and toxicological characteristics Eye contact Adverse symptoms may include the following: pain or irritation watering redness Inhalation Skin contact No specific data. Adverse symptoms may include the following: irritation redness No specific data. Ingestion Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate Not effects available. Potential delayed effects Not available.
Mobility in soil Soil/water partition coefficient (KOC) Other adverse effects Not available. No known significant effects or critical hazards. 13. DISPOSAL CONSIDERATIONS Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Special provisions 8, 146, 335, B54, IB8, IP3, N20, T1, TP33 Packaging instructions: 956 Cargo Aircraft Only Quantity limitation: 400 kg Packaging instructions: 956 Limited Quantities – Passenger Aircraft Quantity limitation: 30 kg Packaging instructions: Y956 Special provisions 16 Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
State regulations Massachusetts New York New Jersey Pennsylvania Minnesota Hazardous Substances California Prop. 65 None of the components are listed. None of the components are listed. The following components are listed: CARBON BLACK The following components are listed: CARBON BLACK None of the components are listed. WARNING: This product contains a chemical known to the State of California to cause cancer.
SAFETY DATA SHEET Issuing Date 27-Oct 2014 Revision Date 20-Oct-2014 Revision Number 1 1.
Hazard statements Harmful if swallowed or in contact with skin. Precautionary statements Prevention Response Storage Disposal Hazards not otherwise classified Wear protective gloves. Wear protective clothing. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell.
Over-exposure signs/symptoms Inhalation No specific data. Skin contact No specific data. Eye contact No specific data. Ingestion No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. No specific treatment. Specific treatments See toxicological information (Section 11) 5.
For non-emergency personnel For emergency responders No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
titanium dioxide Appropriate engineering controls Environmental exposure controls 13463-67-7 ACGIH TLV (United States, 3/2012). TWA: 10 mg/m³ 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/m³ 8 hours. Form: Total dust OSHA PEL (United States, 6/2010). TWA: 15 mg/m³ 8 hours. Form: Total dust No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical States Solid. Color White. Odor Pungent. Sulfurous. {Strong] Odor threshold Not available. pH Not available. Melting point Not available. Boiling point Not available. Flash point Closed cup: >93.3°C (>199.9°F)[Setaflash.] [Product does not sustain combustion.] Evaporation rate Not available. Flammability (solid, gas) Flammable in the presence of the following materials or conditions: open flames, sparks and static discharge.
11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity Product/ingredient name Result Species 2,4,6-tris LD50 Dermal (dimethylaminomethyl)phenol LD50 Oral Irritation/Corrosion Product/ingredient name Result Exposure Rat 1280 mg/kg - Rat 1200 mg/kg - Species Score Exposure Observation Rabbit - - Rat - Skin - Severe irritant Rat - 24 hours 50 Micrograms 0.025 Mililiters 0.
Inhalation Skin contact Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Harmful in contact with skin. Ingestion Harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Eye contact No specific data. Inhalation No specific data. Skin contact No specific data. Ingestion No specific data.
Mobility in soil Soil/water partition coefficient (KOC) Not available. Other adverse effects No known significant effects or critical hazards. 13. DISPOSAL CONSIDERATIONS Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
15. REGULATORY INFORMATION U.S. Federal regulations TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, reaction products with silica TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan inventory (CSNN): Not determined. Substances of very high concern None of the components are listed. 16.
