SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA HTH Pool Care Algae Guard Granules Version 2.1 Revision Date 2020.05.20 Print Date 2020.09.03 SECTION 1. IDENTIFICATION Product name : HTH Pool Care Algae Guard Granules Manufacturer or supplier's details Company : Innovative Water Care, LLC 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 Telephone E-mail address Emergency telephone number : : : 1-800-511-6737 (Outside the USA: 1-423-780-2347) sds@sigurawater.
HTH Pool Care Algae Guard Granules Hazard pictograms : Signal word : Danger Hazard statements : H302 Harmful if swallowed. H316 Causes mild skin irritation. H318 Causes serious eye damage. Precautionary statements : Prevention: P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/ face protection. P280 Wear protective gloves.
HTH Pool Care Algae Guard Granules SECTION 4. FIRST AID MEASURES General advice : If inhaled : In case of skin contact : In case of eye contact : If swallowed : Most important symptoms and effects, both acute and delayed Notes to physician : Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911.
HTH Pool Care Algae Guard Granules prior to the start of any response. Evacuate all non-essential personnel. For disposal considerations see section 13. Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Sweep up and shovel into suitable containers for disposal. Do not flush into surface water or sanitary sewer system. Avoid dust formation. SECTION 7.
HTH Pool Care Algae Guard Granules Odour Odour Threshold pH : : : no data available no data available 4-6 Concentration: 10 % solution Melting point/freezing point Boiling point/boiling range : : no data available Not applicable Flash point Evaporation rate : : no data available Not applicable Flammability (solid, gas) : Product is not known to be flammable, combustible, pyrophoric or explosive.
HTH Pool Care Algae Guard Granules SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, skin, eyes, ingestion Acute toxicity Acute oral toxicity : LD50 (Rat): > 2,949 mg/kg Acute dermal toxicity : LD50 (Rat): Believed to be > 2,000 mg/kg Acute toxicity (other routes of admin- : istration) Remarks: Corrosive to the eyes and mildly irritating to the skin and respiratory tract. Skin corrosion/irritation Assessment: Causes mild skin irritation.
HTH Pool Care Algae Guard Granules Ecotoxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects Ozone-Depletion Potential : Regulation: US. EPA Clean Air Act (CAA) Section 602 OzoneDepleting Substances (40 CFR 82, Subpt. A, App A & B) Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S.
HTH Pool Care Algae Guard Granules TDG UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc sulphate) : 9 : III : 9 : yes IATA UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : 3077 : Environmentally hazardous substance, solid, n.o.s.
HTH Pool Care Algae Guard Granules RID UN number Proper shipping name : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc sulphate) : 9 : III : M7 : 90 : 9 : yes Transport hazard class Packing group Classification Code Hazard Identification Number Labels Environmental hazards Special precautions for user : 49CFR (DOT) Material is not regulated for ground transportation within the US if shipped in non-bulk packages.
HTH Pool Care Algae Guard Granules See above: SECTION 2. Hazard Identification-GHS Classification SARA 313 Components zinc sulphate CAS-No. 7446-19-7 Concentration 98 Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61).
HTH Pool Care Algae Guard Granules Components zinc sulphate CAS-No. 7446-19-7 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Canadian lists NPRI Components zinc sulphate CAS-No. 7446-19-7 The components of this product are reported in the following inventories: : This is an EPA registered pesticide. SECTION 16.
HTH Pool Care Algae Guard Granules Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative 15 Revision Date : 2020.05.
SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA HTH Pool Care Shock Ultra Version 2.0 Revision Date 2020.03.12 Print Date 2020.09.03 SECTION 1. IDENTIFICATION Product name : HTH Pool Care Shock Ultra Manufacturer or supplier's details Company : Innovative Water Care, LLC 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 Telephone E-mail address Emergency telephone number : : : 1-800-511-6737 (Outside the USA: 1-423-780-2347) sds@sigurawater.
HTH Pool Care Shock Ultra H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep/ Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe vapours. P264 Wash hands thoroughly after handling.
HTH Pool Care Shock Ultra Aluminum sulfate (2:3) 10043-01-3 0-2 SECTION 4. FIRST AID MEASURES General advice : If inhaled : In case of skin contact : In case of eye contact : If swallowed : Most important symptoms and effects, both acute and delayed Notes to physician : Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911.
HTH Pool Care Shock Ultra Hazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity.
HTH Pool Care Shock Ultra Further information on storage stability : Average daily temperature of 35° C / 95° F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Calcium dihydroxide 1305-62-0 TWA REL PEL (Total dust.) PEL (Respirable fraction.
HTH Pool Care Shock Ultra Appearance Colour Odour Odour Threshold pH : : : : : powder white Chlorine-like no data available 10 - 10.7 solution Melting point/freezing point : Not applicable Boiling point/boiling range Flash point : : no data available Not applicable Evaporation rate : Not applicable Flammability (solid, gas) : This product is chemically reactive with many substances.
HTH Pool Care Shock Ultra Hazardous decomposition products : including, e.g., other pool treatment products, acids, organics, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, corrosive ,flammable or combustible materials. Do not allow product to contact any foreign matter, including other water treatment products. Contamination or improper use may cause a fire of great intensity, explosion or the release of toxic gases.
HTH Pool Care Shock Ultra equal to 0.1% is identified as a known or anticipated carcinogen by NTP. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Further information Remarks: no data available SECTION 12.
HTH Pool Care Shock Ultra DOT UN number Proper shipping name Transport hazard class Packing group Labels Emergency Response Guidebook Number Environmental hazards : : : : : : 2880 Calcium hypochlorite, hydrated mixtures 5.1 II 5.1 140 UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : : : : : : 2880 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE 5.1 II 5.
HTH Pool Care Shock Ultra RID UN number Proper shipping name Transport hazard class Packing group Classification Code Hazard Identification Number Labels Environmental hazards : : : : : : : : 2880 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE 5.1 II O2 50 5.1 yes Special precautions for user : none Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not applicable SECTION 15.
HTH Pool Care Shock Ultra SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S.
HTH Pool Care Shock Ultra Components Calcium hypochlorite Sodium chloride Magnesium sulfate heptahydrate Calcium dihydroxide Calcium chloride dihydrate Calcium chlorate Calcium carbonate CAS-No. 7778-54-3 7647-14-5 10034-99-8 1305-62-0 10035-04-8 10137-74-3 471-34-1 New Jersey Right To Know Components Calcium hypochlorite Sodium chloride Magnesium sulfate heptahydrate Calcium dihydroxide Calcium chlorate Calcium carbonate Aluminum sulfate (2:3) CAS-No.
HTH Pool Care Shock Ultra Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - Internatio
SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA HTH Pool Care Metal, Stain & Scale Control Version 2.0 Revision Date 2020.03.12 Print Date 2020.09.03 SECTION 1.
HTH Pool Care Metal, Stain & Scale Control P337 + P313 If eye irritation persists: Get medical advice/ attention. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Mixture Hazardous components Chemical name / Synonyms Tetrasodium (1hydroxyethylidene)bisphosphonate CAS-No.
HTH Pool Care Metal, Stain & Scale Control Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Sweep up and shovel into suitable containers for disposal. Do not flush into surface water or sanitary sewer system. Avoid dust formation. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not take internally. Avoid contact with skin, eyes and clothing.
HTH Pool Care Metal, Stain & Scale Control Flash point Evaporation rate : : no data available Not applicable Flammability (solid, gas) : Combustible above 93 deg. C / 200 deg. F. Flammability (liquids) Upper explosion limit : : no data available no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 0.7 (59 °F / 15 °C) Density : 0.
HTH Pool Care Metal, Stain & Scale Control Acute oral toxicity : LD50 (Rat): Believed to be > 2,850 mg/kg Acute inhalation toxicity : Remarks: no data available Acute dermal toxicity : LD50 (Rabbit): Believed to be > 5,000 mg/kg Acute toxicity (other routes of admin- : istration) Remarks: May cause mild eye irritation and moderate to severe skin irritation. Inhalation of dust may cause mucous membrane irritation (includes upper respiratory tract). Ingestion may cause gastrointestinal discomfort.
HTH Pool Care Metal, Stain & Scale Control Mobility in soil no data available Other adverse effects Ozone-Depletion Potential : Regulation: US. EPA Clean Air Act (CAA) Section 602 OzoneDepleting Substances (40 CFR 82, Subpt. A, App A & B) Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : No aquatic toxicity data is available for this product.
HTH Pool Care Metal, Stain & Scale Control : TDG Not dangerous goods UN number Proper shipping name Transport hazard class Packing group : : : : IATA Not applicable Not applicable Not applicable Not applicable Not dangerous goods UN number Proper shipping name Transport hazard class Packing group : : : : IMDG Not applicable Not applicable Not applicable Not applicable Not dangerous goods UN number Proper shipping name Transport hazard class Packing group : : : : Not applicable Not applicable Not
HTH Pool Care Metal, Stain & Scale Control SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards See above: SECTION 2. Hazard Identification-GHS Classification SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
HTH Pool Care Metal, Stain & Scale Control Components Tetrasodium (1-hydroxyethylidene)bisphosphonate CAS-No. 3794-83-0 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Canadian lists NPRI Canadian National Pollutant Release Inventory (NPRI): No component is listed on NPRI.
HTH Pool Care Metal, Stain & Scale Control Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative First formulated version in SAP. Revision Date : 2020.03.
