SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA HTH Algae Guard Granules Version 2.1 Revision Date 2020.05.20 Print Date 2020.05.20 SECTION 1. IDENTIFICATION Product name : HTH Algae Guard Granules Manufacturer or supplier's details Company : Innovative Water Care, LLC 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 Telephone E-mail address Emergency telephone number : : : 1-800-511-6737 (Outside the USA: 1-423-780-2347) sds@sigurawater.
HTH Algae Guard Granules P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes.
HTH Algae Guard Granules In case of eye contact : If swallowed : Most important symptoms and effects, both acute and delayed Notes to physician : IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice.
HTH Algae Guard Granules Avoid inhalation of dust and fumes. : Store in a cool, dry and well ventilated place. Isolate from incompatible materials. Avoid creating dusts. : Strong oxidizing agents Conditions for safe storage Materials to avoid SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : No exposure limits exist for the constituents of this product.
HTH Algae Guard Granules Lower explosion limit : no data available Vapour pressure : Not applicable Relative vapour density : Not applicable Relative density : 3.
HTH Algae Guard Granules Serious eye damage/eye irritation Result: Corrosive Remarks: May cause irreversible eye damage. Respiratory or skin sensitisation Remarks: This material is not known or reported to be a skin or respiratory sensitizer. Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.
HTH Algae Guard Granules SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste Code : LONZA-N09.00602550 Waste from residues : If this product becomes a waste, it will be a nonhazardous waste. As a nonhazardous solid waste it should be disposed of in accordance with local, state and federal regulations. SECTION 14. TRANSPORT INFORMATION DOT UN number Proper shipping name Transport hazard class Packing group Labels Emergency Response Guidebook Number Environmental hazards Ref.
HTH Algae Guard Granules TDG UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc sulphate) : 9 : III : 9 : yes IATA UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : 3077 : Environmentally hazardous substance, solid, n.o.s.
HTH Algae Guard Granules RID UN number Proper shipping name : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc sulphate) : 9 : III : M7 : 90 : 9 : yes Transport hazard class Packing group Classification Code Hazard Identification Number Labels Environmental hazards Special precautions for user : 49CFR (DOT) Material is not regulated for ground transportation within the US if shipped in non-bulk packages.
HTH Algae Guard Granules See above: SECTION 2. Hazard Identification-GHS Classification SARA 313 Components zinc sulphate CAS-No. 7446-19-7 Concentration 98 Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61).
HTH Algae Guard Granules Components zinc sulphate CAS-No. 7446-19-7 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Canadian lists NPRI Components zinc sulphate CAS-No. 7446-19-7 The components of this product are reported in the following inventories: : This is an EPA registered pesticide. SECTION 16.
HTH Algae Guard Granules Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative 15 Revision Date : 2020.05.
SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA 90 Years of HTH Perfect Pools Ultimate Shock! Treatment Version 2.0 Revision Date 2020.03.12 Print Date 2020.04.27 SECTION 1.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep/ Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe vapours.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment Aluminum sulfate (2:3) 10043-01-3 0-2 SECTION 4. FIRST AID MEASURES General advice : If inhaled : In case of skin contact : In case of eye contact : If swallowed : Most important symptoms and effects, both acute and delayed Notes to physician : Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment Hazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment Further information on storage stability : Average daily temperature of 35° C / 95° F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Calcium dihydroxide 1305-62-0 TWA REL PEL (Total dust.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment Appearance Colour Odour Odour Threshold pH : : : : : powder white Chlorine-like no data available 10 - 10.7 solution Melting point/freezing point : Not applicable Boiling point/boiling range Flash point : : no data available Not applicable Evaporation rate : Not applicable Flammability (solid, gas) : This product is chemically reactive with many substances.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment Hazardous decomposition products : including, e.g., other pool treatment products, acids, organics, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, corrosive ,flammable or combustible materials. Do not allow product to contact any foreign matter, including other water treatment products.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment equal to 0.1% is identified as a known or anticipated carcinogen by NTP. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Further information Remarks: no data available SECTION 12.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment DOT UN number Proper shipping name Transport hazard class Packing group Labels Emergency Response Guidebook Number Environmental hazards : : : : : : 2880 Calcium hypochlorite, hydrated mixtures 5.1 II 5.1 140 UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : : : : : : 2880 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE 5.1 II 5.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment RID UN number Proper shipping name Transport hazard class Packing group Classification Code Hazard Identification Number Labels Environmental hazards : : : : : : : : 2880 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE 5.1 II O2 50 5.1 yes Special precautions for user : none Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not applicable SECTION 15.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment Components Calcium hypochlorite Sodium chloride Magnesium sulfate heptahydrate Calcium dihydroxide Calcium chloride dihydrate Calcium chlorate Calcium carbonate CAS-No. 7778-54-3 7647-14-5 10034-99-8 1305-62-0 10035-04-8 10137-74-3 471-34-1 New Jersey Right To Know Components Calcium hypochlorite Sodium chloride Magnesium sulfate heptahydrate Calcium dihydroxide Calcium chlorate Calcium carbonate Aluminum sulfate (2:3) CAS-No.
90 Years of HTH Perfect Pools Ultimate Shock! Treatment Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Researc
SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA HTH Metal & Stain Defense Granules Version 2.0 Revision Date 2020.03.12 Print Date 2020.05.29 SECTION 1. IDENTIFICATION Product name : HTH Metal & Stain Defense Granules Manufacturer or supplier's details Company : Innovative Water Care, LLC 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 Telephone E-mail address Emergency telephone number : : : 1-800-511-6737 (Outside the USA: 1-423-780-2347) sds@sigurawater.
HTH Metal & Stain Defense Granules P337 + P313 If eye irritation persists: Get medical advice/ attention. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Mixture Hazardous components Chemical name / Synonyms Tetrasodium (1hydroxyethylidene)bisphosphonate CAS-No.
HTH Metal & Stain Defense Granules Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Sweep up and shovel into suitable containers for disposal. Do not flush into surface water or sanitary sewer system. Avoid dust formation. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not take internally. Avoid contact with skin, eyes and clothing.
HTH Metal & Stain Defense Granules Flash point Evaporation rate : : no data available Not applicable Flammability (solid, gas) : Combustible above 93 deg. C / 200 deg. F. Flammability (liquids) Upper explosion limit : : no data available no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 0.7 (59 °F / 15 °C) Density : 0.
HTH Metal & Stain Defense Granules Acute oral toxicity : LD50 (Rat): Believed to be > 2,850 mg/kg Acute inhalation toxicity : Remarks: no data available Acute dermal toxicity : LD50 (Rabbit): Believed to be > 5,000 mg/kg Acute toxicity (other routes of admin- : istration) Remarks: May cause mild eye irritation and moderate to severe skin irritation. Inhalation of dust may cause mucous membrane irritation (includes upper respiratory tract). Ingestion may cause gastrointestinal discomfort.
HTH Metal & Stain Defense Granules Mobility in soil no data available Other adverse effects Ozone-Depletion Potential : Regulation: US. EPA Clean Air Act (CAA) Section 602 OzoneDepleting Substances (40 CFR 82, Subpt. A, App A & B) Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : No aquatic toxicity data is available for this product.
HTH Metal & Stain Defense Granules : TDG Not dangerous goods UN number Proper shipping name Transport hazard class Packing group : : : : IATA Not applicable Not applicable Not applicable Not applicable Not dangerous goods UN number Proper shipping name Transport hazard class Packing group : : : : IMDG Not applicable Not applicable Not applicable Not applicable Not dangerous goods UN number Proper shipping name Transport hazard class Packing group : : : : Not applicable Not applicable Not applicab
HTH Metal & Stain Defense Granules SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards See above: SECTION 2. Hazard Identification-GHS Classification SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
HTH Metal & Stain Defense Granules Components Tetrasodium (1-hydroxyethylidene)bisphosphonate CAS-No. 3794-83-0 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Canadian lists NPRI Canadian National Pollutant Release Inventory (NPRI): No component is listed on NPRI.
HTH Metal & Stain Defense Granules Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative First formulated version in SAP. Revision Date : 2020.03.
