SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA HTH Spa Bromine Tablets Version 1.0 Revision Date 2021.06.09 Print Date 2021.07.19 SECTION 1. IDENTIFICATION Product name : HTH Spa Bromine Tablets Manufacturer or supplier's details Company : Innovative Water Care, LLC 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 Telephone E-mail address Emergency telephone number : : : 1-800-511-6737 (Outside the USA: 1-423-780-2347) sds@sigurawater.
HTH Spa Bromine Tablets Hazard statements : H272 May intensify fire; oxidizer. H302 + H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. Precautionary statements : Prevention: P210 Keep away from heat. P220 Keep/ Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe dust or mist.
HTH Spa Bromine Tablets SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Mixture Hazardous components Chemical name / Synonyms 1-Bromo-3-chloro-5,5-dimethylimidazolidine2,4-dione 1,3-Dichloro-5,5-dimethylhydantoin 1,3-dichloro-5-ethyl-5-methylimidazolidine2,4-dione CAS-No. 16079-88-2 118-52-5 89415-87-2 Concentration (% w/w) 50 - 60 25 - 35 10 - 20 SECTION 4.
HTH Spa Bromine Tablets Further information : Use water spray to cool unopened containers. In case of fire, use normal fire-fighting equipment and the personal protective equipment recommended in Section 8 to include a NIOSH approved self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Additional protective clothing must be worn to prevent personal contact with this material.
HTH Spa Bromine Tablets 1,3-Dichloro-5,5dimethylhydantoin 1,3-Dichloro-5,5dimethylhydantoin 118-52-5 TWA 0.2 mg/m3 ACGIH 118-52-5 STEL REL STEL TWA 0.4 mg/m3 0.2 mg/m3 0.4 mg/m3 0.2 mg/m3 ACGIH NIOSH/GUIDE NIOSH/GUIDE ACGIH STEL REL STEL 0.4 mg/m3 0.2 mg/m3 0.
HTH Spa Bromine Tablets Evaporation rate : Not applicable Flammability (solid, gas) : Combustible above 93 deg. C / 200 deg. F. Flammability (liquids) Self-ignition : no data available : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : Not applicable Relative vapour density : no data available Relative density : no data available Density : no data available Water solubility : 5.
HTH Spa Bromine Tablets SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Eyes Ingestion Inhalation Skin Acute toxicity Acute oral toxicity : LD50 (Rat): = 468 - 477 mg/kg Acute dermal toxicity : LD50 (Rabbit): Believed to be > 2,000 mg/kg Acute toxicity (other routes of admin- : istration) Remarks: Corrosive to the eyes and mildly to moderately irritating to the skin and respiratory tract.
HTH Spa Bromine Tablets Remarks: Not known or reported to cause subchronic or chronic toxicity. Further information Remarks: no data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): = 0.5 mg/l Exposure time: 96 h LC50 (Lepomis macrochirus (Bluegill sunfish)): = 1.2 mg/l Exposure time: 96 h LC50 (Cyprinodon variegatus (sheepshead minnow)): = 1.
HTH Spa Bromine Tablets SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : If this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D001. As a hazardous solid waste, it must be disposed of in accordance with local, state and federal regulations. SECTION 14.
HTH Spa Bromine Tablets TDG UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : 3085 : OXIDIZING SOLID, CORROSIVE, N.O.S. (Halogenated hydantoins) : 5.1 : III : 5.1 (8) : yes IATA UN number Proper shipping name Transport hazard class Packing group Labels Environmental hazards : 3085 : Oxidizing solid, corrosive, n.o.s. (Halogenated hydantoins) : 5.1 : III : 5.
HTH Spa Bromine Tablets RID UN number Proper shipping name Transport hazard class Packing group Classification Code Hazard Identification Number Labels Environmental hazards : 3085 : OXIDIZING SOLID, CORROSIVE, N.O.S. (Halogenated hydantoins) : 5.1 : III : OC2 : 58 : 5.1 (8) : yes Special precautions for user : none Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not applicable SECTION 15.
HTH Spa Bromine Tablets This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
HTH Spa Bromine Tablets This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Canadian lists NPRI Canadian National Pollutant Release Inventory (NPRI): No component is listed on NPRI. The components of this product are reported in the following inventories: TSCA : This is an EPA registered pesticide. SECTION 16. OTHER INFORMATION Full text of other abbreviations ACGIH NIOSH/GUIDE : : US. ACGIH Threshold Limit Values US.
HTH Spa Bromine Tablets Revision Date : 2021.06.09 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.
