SDS

ManualsBrandsHTH ManualsOutdoors5 lb. 1 in. Chlorinating Tablet

SAFETY DATA SHEET

HTH 3" Chlorinating Tablets

REVISION DATE : 08/03/2016 Page 1 of 11

FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL:

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®:

FOR ALL SDS QUESTIONS & REQUESTS, CALL:

1-800-654-6911 (OUTSIDE

USA: 1-423-780-2970)

1-800-424-9300 (OUTSIDE

USA: 1-703-527-3887)

1-800-511-MSDS (OUTSIDE

USA: 1-423-780-2347)

PRODUCT NAME: HTH 3" Chlorinating Tablets

EPA Registration Number: 1258-1278

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Arch Chemicals, Inc.

1200 Bluegrass Lakes Parkway

Alpharetta, GA 30004

REVISION DATE:

08/03/2016

SUPERCEDES:

02/11/2016

MSDS Number:

000000025303

SYNONYMS:

none

CHEMICAL FAMILY:

Chloroisocyanurates

DESCRIPTION / USE

Swimming pool water treatment

FORMULA:

NOT APPLICABLE/MIXTURE

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Acute toxicity (Oral)

Category 4

Skin corrosion

Category 1B

Serious eye damage

Category 1

Specific target organ toxicity -

single exposure

Category 3

GHS label elements

Hazard pictograms

Signal word

Danger

Hazard statements

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

Summary of content (11 pages)

PAGE 1
SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL SDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: HTH 3" Chlorinating Tablets EPA Registration Number: 1258-1278 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc.
PAGE 2
SAFETY DATA SHEET Precautionary statements : Prevention: P260 Do not breathe vapours. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
PAGE 3
SAFETY DATA SHEET SECTION 4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: IF INHALED: Move person to fresh air.
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SAFETY DATA SHEET SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Situations: Spill Mitigation Procedures Air Release: Water Release: Land Release: Additional Spill Information : Response to a large quantity spill (100 pounds or greater) or when dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air repirator or self contained breathing apparatus (SCBA), chemical resistant gloves, coveralls and boots.
PAGE 5
SAFETY DATA SHEET SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit.
PAGE 6
SAFETY DATA SHEET Evaporation Rate: Oxidizing: Volatiles, % by vol.: VOC Content HAP Content Not applicable Oxidizing Not applicable Not applicable Not applicable SECTION 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Conditions to Avoid: Chemical Incompatibility: Hazardous Decomposition Products: Decomposition Temperature: May be unstable at temperatures above 225 Deg. C (437 Deg. F) Not sensitive to mechanical shock. Not sensitive to static discharge.
PAGE 7
SAFETY DATA SHEET TRICHLORO-STRIAZINETRIONE ALUMINUM SULFATE, ANHYDROUS LC50 4 h (aerosol dust), (Nose Only) approximately 0.54 mg/l Rat LC50 1 h (aerosol dust), (Nose Only) approximately 2.16 mg/l Rat Inhalation LC50 no data available Product Animal Toxicity Oral LD50 value: LD50 Believed to be > 500 but < 5,000 mg/kg. Rat Dermal LD50 value: LD50 > 5,000 mg/kg Rabbit Inhalation LC50 no data available value: Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION.
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SAFETY DATA SHEET Mallard duck Bobwhite quail - Acute Oral LD50 1,600 mg/kg 8 d Dietary LC50 7,422 ppm Ecological Toxicity Values for: TRICHLORO-S-TRIAZINETRIONE Rainbow trout (Salmo gairdneri), - 96 h LC50 0.32 mg/l Bluegill sunfish - 96 h LC50 0.30 mg/l Daphnia magna, - 48 h LC50 0.
PAGE 9
SAFETY DATA SHEET Class Packing group Labels Emergency Response Guidebook Number TDG UN number Description of the goods Class Packing group Labels IATA UN number Description of the goods Class Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG-CODE UN number Description of the goods : : : : 9 III 9 171 : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
PAGE 10
SAFETY DATA SHEET Signal word Hazard statements : : DANGER! Harmful if swallowed. May be fatal if absorbed through skin. May be fatal if inhaled. Corrosive. Causes skin burns. Corrosive. Causes irreversible eye damage. This pesticide is toxic to fish. EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No.
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SAFETY DATA SHEET AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION SECTIONS REVISED: Major References : 1 Available upon request. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200.