MATERIAL SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL MSDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: HTH® SUPER CHLORINATING TABLETS EPA Registration Number: 1258-1338 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc.
MATERIAL SAFETY DATA SHEET Hazardous Materials Identification System / National Fire Protection Association Classifications Hazard Ratings : Health Flammability Physical / Instability HMIS NFPA 3 2 0 0 2 2 PPI / Special hazard. Oxidizer Immediate (Acute) Health Effects Inhalation Toxicity: This product in the form of solid tablets is not an inhalation hazard.
MATERIAL SAFETY DATA SHEET Ingestion: Sensitization: Chronic Target Organ Toxicity: Supplemental Health Hazard Information : There are no known or reported effects from chronic ingestion except for effects similar to those experienced from single exposure. The acute corrosivity of this product, makes chronic ingestion of significant amounts unlikely. This material tested negative for skin sensitization in animals. There are no known or reported target organ effects from chronic exposure.
MATERIAL SAFETY DATA SHEET Ingestion: Notes to Physician: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Probable mucosal damage may contraindicate the use of gastric lavage. 5.
MATERIAL SAFETY DATA SHEET Water Release: Land Release: Additional Spill Information : This material is heavier than water. This material is soluble in water. Stop water flow or divert water flow around spill if possible and safe to do so. Begin monitoring for available chlorine and pH immediately. Do not contaminate spill material with any organic materials, ammonia, ammonium salts or urea. Clean up all spill material with clean, dry dedicated equipment and place in a clean dry container.
MATERIAL SAFETY DATA SHEET Respiratory Protection : Respirator Type : Skin Protection : Eye Protection: Protective Clothing Type: General Protective Measures: Wear a NIOSH approved respirator if levels above the exposure limits are possible. A NIOSH approved full-face air purifying respirator equipped with combination chlorine/P100 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit.
MATERIAL SAFETY DATA SHEET 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Conditions to Avoid: Chemical Incompatibility: Hazardous Decomposition Products: Decomposition Temperature: May be unstable at temperatures above 225 Deg. C (437 Deg. F) Not sensitive to mechanical shock. Not sensitive to static discharge. Product will not undergo hazardous polymerization. Product is an oxidizer. Sparks, open flame, other ignition sources, and elevated temperatures.
MATERIAL SAFETY DATA SHEET Product Animal Toxicity Oral LD50 value: Dermal LD50 value: Inhalation LC50 value: Skin Irritation: Eye Irritation: Skin Sensitization: Acute Toxicity: Subchronic / Chronic Toxicity: Reproductive and Developmental Toxicity: LD50 490 mg/kg Rat LD50 > 2,000 mg/kg Rabbit LC50 4 h (aerosol dust), (Nose Only) Approximately 0.54 MG/L (aerosol dust), (Nose Only) Approximately 2.16 MG/L Rat DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS.
MATERIAL SAFETY DATA SHEET Rainbow trout (Salmo gairdneri), Bluegill sunfish Daphnia magna, Mallard duck Mallard duck Bobwhite quail - 96 h LC50 0.32 mg/l 96 h LC50 0.30 mg/l 48 h LC50 0.21 mg/l 8 DAYS Dietary LC50 > 10,000 ppm Acute Oral LD50 1,600 mg/kg 8 DAYS Dietary LC50 7,422 ppm Ecological Toxicity Values for: TRICHLORO-S-TRIAZINETRIONE Rainbow trout (Salmo gairdneri), - 96 h LC50 0.32 mg/l Bluegill sunfish - 96 h LC50 0.30 mg/l Daphnia magna, - 48 h LC50 0.
MATERIAL SAFETY DATA SHEET hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D. Disposal Methods : As a nonhazardous solid waste it should be disposed of in accordance with local, state and federal regulations. Potential US EPA Waste Codes : Not applicable 14. TRANSPORT INFORMATION Land (US DOT): Water (IMDG): UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
MATERIAL SAFETY DATA SHEET Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: ZUS_SAR302 TPQ (threshold planning None established quantity) Reportable Quantity (49 CFR 172.101, Appendix): ZUS_CERCLA Reportable quantity ZUS_SAR302 Reportable quantity ZINC AND COMPOUNDS Value: None established Supplier Notification Requirements (40 CFR 372.
MATERIAL SAFETY DATA SHEET Pennsylvania: Hazardous substance list 1990-01-01 ZINC COMPOUNDS Environmental hazard, hazardous substance New Jersey: CAS # 87-90-1 7446-19-7 ZUSNJ_RTK COMPONENT NAME TRICHLORO-S-TRIAZINETRIONE ZINC SULFATE New Jersey Right to Know Hazardous Substance List (RTK-HSL) 2007-03-01 TRICHLOROISOCYANURIC ACID SYMCLOSENE 1,3,5-TRIAZINE-2,4,6(1H,3H,5H)TRIONE, 1,3,5-TRICHLOROSpecial Health Hazard - Reactive - Second Degree New Jersey Right to Know Hazardous Substance List (RTK-HSL) 198
MATERIAL SAFETY DATA SHEET Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 148 Trichloroisocyanuric acid 16. OTHER INFORMATION MSDS REVISION STATUS : Major References : Available upon request. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT.
