Instruction Manual HI 83213 Multiparameter Bench Photometer for Municipal Wastewater www.hannainst.
Dear Customer, Thank you for choosing a Hanna product. Please read this instruction manual carefully before using the instrument. This manual will provide you with the necessary information for the correct use of the instrument. If you need additional technical information, do not hesitate to e-mail us at tech@hannainst.com. TABLE OF CONTENTS COPPER HR .................................................................... 37 COPPER LR ....................................................................
PRELIMINARY EXAMINATION Please examine this product carefully. Make sure that the instrument is not damaged. If any damage occurred during shipment, please notify your local Hanna Office. Each Meter is supplied complete with: • Four Sample Cuvettes and Caps • Cloth for wiping cuvettes (1 pcs) • 60 mL glass bottle for dissolved oxygen analysis (1 pcs) • Scissors • AC/DC Power Adapter • Instruction Manual Note: Save all packing material until you are sure that the instrument works correctly.
SPECIFICATIONS Life of the instrument Silicon Photocell 0 to 50°C (32 to 122°F); max 90% RH non-condensing Power Supply external 12 Vdc power adapter built-in rechargeable battery Dimensions 235 x 200 x 110 mm (9.2 x 7.87 x 4.33") Weight 0.9 Kg For specifications related to each method (e.g. range, precision, etc.) refer to the related measurement section. Light Life Light Detector Environment PRECISION AND ACCURACY Precision is how closely repeated measurements agree with each other.
Where: -log I/Io=Absorbance (A) Io =intensity of incident light beam I =intensity of light beam after absorption ελ =molar extinction coefficient at wavelength λ c =molar concentration of the substance d =optical path through the substance Therefore, the concentration "c" can be calculated from the absorbance of the substance as the other factors are known.
FUNCTIONAL DESCRIPTION INSTRUMENT DESCRIPTION 1) 2) 3) 4) 5) 6) 7) 8) Open Cuvette Lid Indexing mark Cuvette point Liquid Crystal Display (LCD) Splash proof keypad ON/OFF power switch Power input connector USB connector 6
KEYPAD DESCRIPTION The keypad contains 8 direct keys and 3 functional keys with the following functions: Press to perform the function displayed above it on the LCD. ESC Press to exit the current screen. Press to access the select method menu. Press to move up in a menu or a help screen, to increment a set value, to access second level functions. Press to move down in a menu or a help screen, to decrement a set value, to access second level functions. Press to log the current reading.
TIPS FOR AN ACCURATE MEASUREMENT The instructions listed below should be carefully followed during testing to ensure most accurate results. • Color or suspended matter in large amounts may cause interference, and should be removed by treatment with active carbon and filtration. • Ensure the cuvette is filled correctly: the liquid in the cuvette forms a convexity on the top; the bottom of this convexity must be at the same level as the 10 mL mark.
• Proper use of the powder reagent packet: (a) use scissors to open the powder packet; (b) push the edges of the packet to form a spout; (c) pour out the content of the packet. USING CUVETTES • Proper mixing is very important for reproducibility of the measurements. The right way of mixing a cuvette is specified for each method in the related chapter. (a) invert the cuvette a couple of times or for a specified time: hold the cuvette in the vertical position.
• Pay attention to push the cuvette completely down in the holder and to align the white point on the cap to the indexing mark on the meter. • In order to avoid reagent leaking and to obtain more accurate measurements, close the cuvette first with the supplied HDPE plastic stopper and then the black cap. • Each time the cuvette is used, the cap must be tightened to the same degree. • Whenever the cuvette is placed into the measurement cell, it must be dry outside, and free of fingerprints, oil or dirt.
HEALTH & SAFETY • The chemicals contained in the reagent kits may be hazardous if improperly handled. • Read the Material Safety Data Sheet (MSDS) before performing tests. • Safety equipment: Wear suitable eye protection and clothing when required, and follow instructions carefully. • Reagent spills: If a reagent spill occurs, wipe up immediately and rinse with plenty of water. If reagent contacts skin, rinse the affected area thoroughly with water. Avoid breathing released vapors.
OPERATIONAL GUIDE POWER CONNECTION AND BATTERY MANAGEMENT The meter can be powered from an AC/DC adapter (included) or from the built-in rechargeable battery. Note: Always turn the meter off before unplugging it to ensure no data is lost. When the meter switches ON, it verifies if the power supply adapter is connected.
• After the desired method is selected, follow the measurement described in the related section. • Before performing a test you should read all the instructions carefully. DATA MANAGEMENT The instrument features a data log function to help you keep track of all your analysis. The data log can hold 200 individual measurements. Storing, viewing and deleting the data is possible using the LOG and RCL keys.. Storing data: You can store only a valid measurement.
SETUP In the Setup mode the instrument’s parameters can be changed. Some parameters affect the measuring sequence and others are general parameters that change the behavior or appearance of the instrument. Press SETUP to enter the setup mode. Press ESC or SETUP to return to the main screen. A list of setup parameters will be displayed with currently configured settings. Press HELP for additional information. Press the keys to select a parameter and change the value as follows: Backlight Values: 0 to 8.
Date / Time This option is used to set the instrument’s date and time. Press the Modify key to change the date/time. Press the W X functional keys to highlight the value to be modified (year, month, day, hour, minute or second). Use the keys to change the value. Press the Accept key to confirm or ESC to return to the setup without saving the new date or time. Time format Option: AM/PM or 24 hour. Press the functional key to select the desired time format.
Instrument ID Option: 0 to 9999. This option is used to set the instrument’s ID (identification number). The instrument ID is used while exchanging data with a PC. Press the Modify key to access the instrument ID screen. Press the keys in order to set the desired value. Press the Accept key to confirm the value or ESC to return to the setup menu without saving the new value. Meter information Press the Select key to view the instrument model, firmware version, language version and instrument serial number.
ALUMINUM SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 1.00 mg/L 0.01 mg/L ±0.02 mg/L ±4% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the aluminon method. The reaction between aluminum and reagents causes a reddish tint in the sample.
• Add the content of one packet of HI 93712C-0 Bleaching powder to one of the two cuvettes. Replace the cap and shake vigorously until completely dissolved. This is the blank. #1 • Place the blank into the holder and close the lid. • Press Timer and the display will show the countdown prior to zeroing the blank. Alternatively wait for 15 minutes and then press Zero. The display will show “-0.0-” when the meter is zeroed and ready for measurement.
AMMONIA MEDIUM RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 10.00 mg/L 0.01 mg/L ±0.05 mg/L ±5% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 420 nm Adaptation of the ASTM Manual of Water and Environmental Technology, D1426-92, Nessler method. The reaction between ammonia and reagents causes a yellow tint in the sample.
• Remove the cuvette. • Add 4 drops of HI 93715A-0 First Reagent (6 drops for seawater analysis). Replace the cap and mix the solution. • Add 4 drops of HI 93715B-0 Second Reagent (10 drops for seawater analysis). Replace the cap and mix the solution. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 3 minutes and 30 seconds and press Read. When the timer ends the meter will perform the reading.
AMMONIA LOW RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 3.00 mg/L 0.01 mg/L ±0.04 mg/L ±4% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 420 nm Adaptation of the ASTM Manual of Water and Environmental Technology, D1426-92, Nessler method. The reaction between ammonia and reagents causes a yellow tint in the sample.
• Remove the cuvette. • Add 4 drops of HI 93700A-0 First Reagent (6 drops for seawater analysis). Replace the cap and mix the solution. • Add 4 drops of HI 93700B-0 Second Reagent (10 drops for seawater analysis). Replace the cap and mix the solution. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 3 minutes and 30 seconds and press Read. When the timer ends the meter will perform the reading.
BROMINE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 8.00 mg/L 0.01 mg/L ±0.08 mg/L ±3% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the Standard Methods for the Examination of Water and Wastewater, 18th edition, DPD method. The reaction between bromine and the reagent causes a pink tint in the sample.
• Remove the cuvette and add the content of one packet of HI 93716-0 DPD reagent. Replace the cap and shake gently for about 20 seconds to dissolve most of the reagent. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 2 minutes and 30 seconds and press Read. When the timer ends the meter will perform the reading. • The instrument displays the results in mg/L of bromine.
FREE CHLORINE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 2.50 mg/L 0.01 mg/L ±0.03 mg/L ±3% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the EPA DPD method 330.5. The reaction between free chlorine and the DPD reagent causes a pink tint in the sample.
• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement. • Remove the cuvette. Powder reagents procedure • Add the content of one packet of HI 93701 DPD reagent. Replace the cap and shake gently for 20 seconds (or 2 minutes for seawater analysis). • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 1 minute and press Read. When the timer ends the meter will perform the reading.
• Reinsert the cuvette into the instrument. • Press Read to start the reading. The instrument displays the results in mg/L of free chlorine. INTERFERENCES Interference may be caused by: Bromine, Iodine, Ozone, Oxidized forms of Chromium and Manganese. In case of water with hardness greater than 500 mg/L CaCO3, shake the sample for approximately 2 minutes after adding the powder reagent.
TOTAL CHLORINE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 3.50 mg/L 0.01 mg/L ±0.03 mg/L ±3% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the EPA DPD method 330.5. The reaction between the chlorine and the DPD reagent causes a pink tint in the sample.
• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement. • Remove the cuvette. Powder reagents procedure • Add 1 packet of HI 93711 DPD reagent. Replace the cap and shake gently for 20 seconds (or 2 minutes for seawater analysis). • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 2 minutes and 30 seconds and press Read.
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 2 minutes and 30 seconds and press Read. When the timer ends the meter will perform the reading. • The instrument displays the results in mg/L of total chlorine. Note: free and total chlorine have to be measured separately with fresh unreacted samples following the related procedure if both values are requested.
CHROMIUM VI HIGH RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0 to 1000 μg/L 1 μg/L ±5 μg/L ±4% of reading at 25 °C ±1 μg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the ASTM Manual of Water and Environmental Technology, D1687-92, Diphenylcarbohydrazide method. The reaction between chromium VI and the reagent causes a purple tint in the sample.
• Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 6 minutes and press Read. When the timer ends the meter will perform the reading. The instrument displays concentration in μg/L of chromium VI. • Press or to access the second level functions. • Press the Chem Frm key to convert the result in μg/L of Chromate (CrO42¯) and Dichromate (Cr2O72¯). • Press or to return to the measurement screen.
CHROMIUM VI LOW RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0 to 300 μg/L 1 μg/L ±1 μg/L ±4% of reading at 25 °C ±1 μg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the ASTM Manual of Water and Environmental Technology, D1687-92, Diphenylcarbohydrazide method. The reaction between chromium VI and the reagent causes a purple tint in the sample.
• Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 6 minutes and press Read. When the timer ends the meter will perform the reading. The instrument displays concentration in μg/L of chromium VI. • Press or to access the second level functions. • Press the Chem Frm key to convert the result in μg/L of Chromate (CrO42¯) and Dichromate (Cr2O72¯). • Press or to return to the measurement screen.
COLOR OF WATER SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0 to 500 PCU (Platinum Cobalt Units) 1 PCU ±10 PCU ±5% of reading at 25 °C ± 1 PCU Tungsten lamp with narrow band interference filter @ 420 nm Adaptation of the Standard Methods for the Examination of Water and Wastewater, 18th edition, Colorimetric Platinum Cobalt method. REQUIRED ACCESSORIES 0.45 μm membrane for true color measurement. For other accessories see page 72.
• Fill the second cuvette up to the mark with unfiltered sample and replace the cap. This is the apparent color. 10 mL #2 • Filter 10 mL of sample through a filter with a 0.45 μm membrane into the third cuvette, up to the 10 mL mark and replace the cap. This is the true color. #3 #2 • Insert the apparent color cuvette (# 2) into the instrument and close the lid. • Press Read to start the reading. • The meter displays the value of apparent color in PCU.
COPPER HIGH RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 5.00 mg/L 0.01 mg/L ±0.02 mg/L ±4% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 575 nm Adaptation of the EPA method. The reaction between copper and the bicinchoninate reagent causes a purple tint in the sample.
• Remove the cuvette. • Add the content of one packet of HI 93702-0 Bicinchoninate. Replace the cap and shake gently for about 15 seconds. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 45 seconds and press Read. When the timer ends the meter will perform the reading. • The instrument displays the results in mg/L of copper.
COPPER LOW RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0 to 1000 μg/L 1 μg/L ±10 μg/L ±5% of reading at 25 °C ±1 μg/L Tungsten lamp with narrow band interference filter @ 575 nm Adaptation of the EPA method. The reaction between copper and the bicinchoninate reagent causes a purple tint in the sample.
• Remove the cuvette. • Add the content of one packet of HI 95747-0 Bicinchoninate. Replace the cap and shake gently for about 15 seconds. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 45 seconds and press Read. When the timer ends the meter will perform the reading. • The instrument displays the results in μg/L of copper.
IODINE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.0 to 12.5 mg/L 0.1 mg/L ±0.1 mg/L ±5% of reading at 25 °C ±0.1 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the Standard Methods for the Examination of Water and Wastewater, 18th edition, DPD method. The reaction between iodine and the reagent causes a pink tint in the sample.
• Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 2 minutes and 30 seconds and press Read. When the timer ends the meter will perform the reading. • The instrument displays concentration in mg/L of iodine. INTERFERENCES Interference may be caused by: Bromine, Chlorine, Ozone, Oxidized forms of Chromium and Manganese.
NICKEL HIGH RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 7.00 g/L 0.01 g/L ±0.07 ±4% of reading at 25 °C ±0.02 g/L Tungsten lamp with narrow band interference filter @ 575 nm Adaptation of the photometric method. The reaction between nickel and the reagent causes a blue tint in the sample.
• Remove the cuvette and add the content of one packet of HI 93726-0 reagent. Replace the cap and shake gently until completely dissolved. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 1 minute and press Read. When the timer ends the meter will perform the reading. • The instrument displays concentration in g/L of nickel. INTERFERENCES Interference may be caused by copper.
NICKEL LOW RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.000 to 1.000 mg/L 0.001 mg/L ±0.010 mg/L ±7% of reading at 25 °C ±0.001 mg/L Tungsten lamp with narrow band interference filter @ 575 nm Adaptation of the PAN method. The reaction between nickel and the reagents causes an orange tint in the sample. REQUIRED REAGENTS Code HI 93740A-0 HI 93740B-0 HI 93740C-0 HI 93703-51 Description Phthalate-phosphate 0.
• Press Timer and the display will show a countdown prior to adding reagent C or, alternatively, wait for 15 minutes. Add one packet of HI 93740C-0 EDTA reagent to each beaker, cap and swirl to mix until completely dissolved. • Fill one cuvette up to the mark with 10 mL of the blank. 10 mL • Place the cuvette into the holder and close the lid. • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for measurement.
INTERFERENCES Interference may be caused by: Co2+ must not be present Fe2+ must not be present Al3+ above 32 mg/L Ca2+ above 1000 mg/L (as CaCO3) Cd2+ above 20 mg/L Cl¯ above 8000 mg/L Cr3+ above 20 mg/L Cr6+ above 40 mg/L Cu2+ above 15 mg/L F¯ above 20 mg/L Fe3+ above 10 mg/L K+ above 500 mg/L Mg2+ above 400 mg/L Mn2+ above 25 mg/L Mo6+ above 60 mg/L Na+ above 5000 mg/L Pb2+ above 20 mg/L Zn2+ above 30 mg/L 47 Nickel LR
NITRATE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.0 to 30.0 mg/L 0.1 mg/L ±0.5 mg/L ±10% of reading at 25 °C ±0.1 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the cadmium reduction method. The reaction between nitrate and the reagent causes an amber tint in the sample.
• Replace the cap and immediately shake vigorously up and down for exactly 10 seconds. Continue to mix by inverting the cuvette gently for 50 seconds, while taking care not to induce air bubbles. Powder will not completely dissolve. Time and way of shaking could sensitively affect the measurement. • Reinsert the cuvette into the instrument, taking care not to shake it.
NITRITE HIGH RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0 to 150 mg/L 1 mg/L ±4 mg/L ±4% of reading at 25 °C ±1 mg/L Tungsten lamp with narrow band interference filter @ 575 nm Adaptation of the Ferrous Sulfate method. The reaction between nitrite and the reagent causes a greenish-brown tint in the sample.
• Add the content of one packet of HI 93708-0 reagent. Replace the cap and shake gently until completely dissolved. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 10 minutes and press Read. When the timer ends the meter will perform the reading. The instrument displays concentration in mg/L of nitrite. • Press or to access the second level functions.
NITRITE LOW RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 1.15 mg/L 0.01 mg/L ±0.06 mg/L ±4% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the EPA Diazotization method 354.1. The reaction between nitrite and the reagent causes a pink tint in the sample.
• Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 6 minutes and press Read. When the timer ends the meter will perform the reading. The instrument displays concentration in mg/L of nitrite. • Press or to access the second level functions. • Press the Chem Frm key to convert the result in mg/L of nitrogen-nitrite (NO2¯-N) and sodium nitrite (NaNO2). • Press or to return to the measurement screen.
DISSOLVED OXYGEN SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.0 to 10.0 mg/L 0.1 mg/L ±0.4 mg/L ±3% of reading at 25 °C ± 0.1 mg/L Tungsten lamp with narrow band interference filter @ 420 nm Adaptation of the Standard Methods for the Examination of Water and Wastewater, 18th edition, Azide modified Winkler method. The reaction between dissolved oxygen and the reagents causes a yellow tint in the sample.
• Let the sample stand and the flocculent agent will start to settle. • After approximately 2 minutes, when the upper half of the bottle becomes limpid, add 10 drops of HI 93732C-0. • Replace the cap and invert the bottle until the settled flocculent dissolves completely. The sample is ready for measurement when it is yellow and completely limpid. • Fill the cuvette up to the mark with 10 mL of the unreacted (original) sample, and replace the cap. This is the blank.
pH SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 6.5 to 8.5 pH 0.1 pH ±0.1 pH at 25 °C ±0.1 pH Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the Phenol Red method. The reaction with the reagent causes a yellow to red tint in the sample.
• Remove the cuvette and add 5 drops of HI 93710-0 Phenol Red Indicator. Replace the cap and mix the solution. • Reinsert the cuvette into the instrument. • Press the Read key to start the reading. The instrument displays the pH value.
PHOSPHATE HIGH RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Dev. Light Source Method 0.0 to 30.0 mg/L 0.1 mg/L ±1 mg/L ±4% of reading at 25 °C ±0.1 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the Standard Methods for the Examination of Water and Wastewater, 18th edition, Amino Acid method. The reaction between phosphate and reagents causes a blue tint in the sample.
• Add the content of one packet of HI 93717B-0 Phosphate HR Reagent B to the cuvette. Replace the cap and shake gently until completely dissolved. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 5 minutes and press Read. When the timer ends the meter will perform the reading. The instrument displays the results in mg/L of phosphate (PO43¯). • Press or to access the second level functions.
PHOSPHATE LOW RANGE SPECIFICATIONS Range Resolution Accuracy Typical EMC Dev. Light Source Method 0.00 to 2.50 mg/L 0.01 mg/L ±0.04 mg/L ±4% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 610 nm Adaptation of the Ascorbic Acid method. The reaction between phosphate and the reagent causes a blue tint in the sample.
• Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 3 minutes and press Read. When the timer ends the meter will perform the reading. The instrument displays concentration in mg/L of phosphate (PO43¯). • Press or to access the second level functions. • Press the Chem Frm key to convert the result in mg/L of phosphorus (P) and phosphorus pentoxide (P2O5). • Press or to return to the measurement screen.
PHOSPHORUS SPECIFICATIONS Range Resolution Accuracy Typical EMC Dev. Light Source Method 0.0 to 15.0 mg/L 0.1 mg/L ±0.3 mg/L ±4% of reading at 25 °C ±0.2 mg/L Tungsten lamp with narrow band interference filter @ 525 nm Adaptation of the Standard Methods for the Examination of Water and Wastewater, 18th edition, Amino Acid method. The reaction between phosphate and reagents causes a blue tint in the sample.
• Add the content of one packet of HI 93706B-0 Phosphorus Reagent B (Amino Acid) to the cuvette. Replace the cap and shake gently until completely dissolved. • Reinsert the cuvette into the instrument. • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait for 5 minutes and press Read. When the timer ends the meter will perform the reading. The instrument displays the results in mg/L of phosphorus (P). • Press or to access the second level functions.
SILVER SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.000 to 1.000 mg/L 0.005 mg/L ±0.020 mg/L ±5% of reading at 25 °C ± 0.001 mg/L Tungsten lamp with narrow band interference filter @ 575 nm. Adaptation of the PAN method. The reaction between silver and reagents causes an orange tint in the sample.
• Add exactly 1.0 mL of HI 93737B-0 Buffer reagent to the second beaker (the sample) and swirl gently to mix. Press Timer and the display will show the countdown prior to adding reagent C or, alternatively, wait for 2 minutes. #2 • Then add exactly 1.0 mL of HI 93737C-0 Indicator reagent to each beaker and swirl. Press Timer or, alternatively, wait for 2 minutes. #1 #2 #1 #2 • Then, in both cases, add 1.0 mL of HI 93737D-0 Fixing reagent to each beaker and swirl.
• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for measurement. • Fill a second cuvette up to the mark with 10 mL of the reacted sample. 10 mL #2 • Add 3 drops of Dispersing Agent (HI 93703-51), replace the cap and invert gently to mix for about 10 seconds. #2 • Insert the second cuvette into the instrument. • Press Read to start the reading. The instrument displays the results in mg/L of silver.
ZINC SPECIFICATIONS Range Resolution Accuracy Typical EMC Deviation Light Source Method 0.00 to 3.00 mg/L 0.01 mg/L ±0.03 mg/L ±3% of reading at 25 °C ±0.01 mg/L Tungsten lamp with narrow band interference filter @ 575 nm Adaptation of the Standard Methods for the Examination of Water and Wastewater, 18th edition, Zincon method. The reaction between zinc and the reagents causes an orange to a dark violet tint in the sample.
• Place the cap and insert the cuvette into the instrument and close the lid. • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for measurement. • Remove the cuvette and add 0.5 mL of HI 93731B-0 Cyclohexanone to the cuvette. Note: To prevent any contamination from the polycarbonate cap, prior to replacing it, close the sample cuvette with the supplied HDPE plastic stopper. • Replace the cap and mix the sample for 15 seconds. • Insert the sample into the instrument.
ERRORS AND WARNINGS The instrument shows clear warning messages when erroneous conditions appear and when measured values are outside the expected range. These messages are described below. No Light: The light source is not functioning properly. Light Leak: There is an excess amount of ambient light reaching the detector. Inverted cuvettes: The sample and the zero cuvettes are inverted. Battery Low: The battery capacity is lower than 10%. Light Low: The instrument cannot adjust the light level.
DATA MANAGEMENT The analyzed data can be managed using Hanna’s product HI92000, Windows ® Compatible Software. Windows® is registered Trademark of "Microsoft Co.
STANDARD METHODS Description Aluminum Ammonia MR Ammonia LR Bromine Chlorine, Free Chlorine, Total Chromium VI HR Chromium VI LR Color of Water Copper HR Copper LR Iodine Nickel HR Nickel LR Nitrate Nitrite HR Nitrite LR Oxygen, Dissolved pH Phosphate HR Phosphate LR Phosphorus Silver Zinc Range 0.00 to 1.00 mg/L 0.00 to 10.00 mg/L 0.00 to 3.00 mg/L 0.00 to 8.00 mg/L 0.00 to 2.50 mg/L 0.00 to 3.50 mg/L 0 to 1000 μg/L 0 to 300 μg/L 0 to 500 PCU 0.00 to 5.00 mg/L 0 to 1000 μg/L 0.0 to 12.5 mg/L 0.00 to 7.
ACCESSORIES REAGENT SETS HI 93700-01 HI 93700-03 HI 93701-01 HI 93701-03 HI 93701-F HI 93701-T HI 93702-01 HI 93702-03 HI 93706-01 HI 93706-03 HI 93707-01 HI 93707-03 HI 93708-01 HI 93708-03 HI 93710-01 HI 93710-03 HI 93711-01 HI 93711-03 HI 93712-01 HI 93712-03 HI 93713-01 HI 93713-03 HI 93715-01 HI 93715-03 HI 93716-01 HI 93716-03 HI 93717-01 HI 93717-03 HI 93718-01 HI 93718-03 HI 93723-01 HI 93723-03 HI 93726-01 HI 93726-03 HI 93728-01 HI 93728-03 100 ammonia LR tests 300 ammonia LR tests 100 free chlor
HI 93731-01 100 zinc tests HI 93731-03 300 zinc tests HI 93732-01 100 dissolved oxygen tests HI 93732-03 300 dissolved oxygen tests HI 93737-01 50 silver tests HI 93737-03 150 silver tests HI 93740-01 50 nickel LR tests HI 93740-03 150 nickel LR tests HI 93749-01 100 chromium VI LR tests HI 93749-03 300 chromium VI LR tests HI 93703-52-2 Glycine Powder, Optional Reagent for 100 tests HI 95747-01 100 copper LR tests HI 95747-03 300 copper LR tests OTHER ACCESSORIES HI 731318 HI 731321 HI 731325W HI 740034 HI
WARRANTY All Hanna Instruments meters are warranted for two years against defects in workmanship and materials when used for its intended purpose and maintained according to the instructions. This warranty is limited to repair or replacement free of charge. Damages due to accident, misuse, tampering or lack of prescribed maintenance are not covered. If service is required, contact your dealer. If under warranty, report the model number, date of purchase, serial number and the nature of the failure.
HANNA LITERATURE Hanna publishes a wide range of catalogs and handbooks for an equally wide range of applications. The reference literature currently covers areas such as: • Water Treatment • Process • Swimming Pools • Agriculture • Food • Laboratory and many others. New reference material is constantly being added to the library. For these and other catalogs, handbooks and leaflets contact your dealer or the Hanna Customer Service Center nearest to you.
Hanna Instruments Inc. Highland Industrial Park 584 Park East Drive Woonsocket, RI 02895 USA Technical Support for Customers Tel. (800) 426 6287 Fax (401) 765 7575 E-mail tech@hannainst.com www.hannainst.
