SAFETY DATA SHEET DDP Specialty Electronic Materials US, LLC Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Print Date: 03/08/2024 DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Signal word: DANGER! Hazards Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Disposal Dispose of contents/ container to an approved waste disposal plant. Other hazards No data available 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component CASRN Concentration Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 >= 10.0 - <= 30.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 >= 10.0 - <= 30.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 prolonged or repeated contact with skin. Avoid breathing vapor. Never use air pressure for transferring product. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 available oxygen. (Several of these materials present fire or explosion hazards.) NIOSH REL TWA 1,800 mg/m3 1,000 ppm This material contains a simple asphyxiant which may displace oxygen. Insure adequate ventilation to prevent an oxygen deficient atmosphere. The minimum requirement of 19.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Odor Mild Odor Threshold No test data available pH Not applicable Melting point/range No test data available Freezing point No test data available Boiling point (760 mmHg) Not applicable Flash point closed cup -104 °C ( -155 °F) Closed Cup Evaporation Rate (Butyl Acetate = 1) No test data available Flammability (solid, gas) No data available Lower explosion limit No test data av
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Teratogenicity Product test data not available. Refer to component data. Reproductive toxicity Product test data not available. Refer to component data. Mutagenicity Product test data not available. Refer to component data. Aspiration Hazard Product test data not available. Refer to component data.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Reproductive toxicity No relevant data found. Mutagenicity Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer Acute oral toxicity Typical for this family of materials. LD50, Rat, > 2,000 mg/kg Estimated. No deaths occurred at this concentration. Acute dermal toxicity Typical for this family of materials. LD50, Rabbit, > 2,000 mg/kg Estimated.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 cause pulmonary edema (fluid in the lungs.) Effects may be delayed. Decreased lung function has been associated with overexposure to isocyanates. The LC50 has not been determined. Sensitization Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. May cause allergic respiratory reaction.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Specific Target Organ Systemic Toxicity (Repeated Exposure) Based on available data, repeated exposures are not anticipated to cause significant adverse effects. Teratogenicity No relevant data found. Reproductive toxicity No relevant data found. Mutagenicity In vitro genetic toxicity studies were negative.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Mutagenicity For similar material(s): This material was not genotoxic in various mutagenicity and clastogenicity tests. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Sensitization No relevant information found. For respiratory sensitization: No relevant information found. Specific Target Organ Systemic Toxicity (Single Exposure) Available data are inadequate to determine single exposure specific target organ toxicity. Specific Target Organ Systemic Toxicity (Repeated Exposure) In animals, effects have been reported on the following organs: Kidney. Liver.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Reproductive toxicity In animal studies, did not interfere with reproduction. In animal studies, did not interfere with fertility. Mutagenicity In vitro genetic toxicity studies were negative. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l 4,4' -Methylenediphenyl diisocyanate Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 0.1 mg/l Chronic toxicity to fish Based on data from similar materials NOEC, Oncorhynchus mykiss (rainbow trout), 60 d, 4.5 mg/l Tris(1-chloro-2-propyl) phosphate Acute toxicity to fish Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested).
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Test Type: Half-life (indirect photolysis) Sensitization: OH radicals Atmospheric half-life: 0.24 d Method: Estimated. Methyl ether Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Isobutane Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.76 Measured Paraffin waxes and Hydrocarbon waxes, chlorinated Bioaccumulation: Bioconcentration potential is low (BCF less than 100 or log Pow greater than 7). Partition coefficient: n-octanol/water(log Pow): 7.4 Estimated.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Methyl ether Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient (Koc): 1.29 - 14 Estimated. Propane Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient (Koc): 24 - 460 Estimated. 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 Packing group This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. 16.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 04/17/2023 maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 Lethal Concentratio
