Material Safety Data Sheet The Dow Chemical Company ™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Print Date: 22 Jan 2013 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Health Effects Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Storage Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Shelf life: Use within Do not store above: 12 Months 49 °C 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value ACGIH TWA 0.005 ppm OSHA Table Z-1 Ceiling 0.2 mg/m3 0.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF 9.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. Toxicological Information Acute Toxicity Ingestion As product: Single dose oral LD50 has not been determined. Estimated. LD50, rat > 2,000 mg/kg Dermal As product: The dermal LD50 has not been determined. Estimated.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Fish Acute & Prolonged Toxicity Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 h: > 1,000 mg/l Aquatic Invertebrate Acute Toxicity Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 h: > 1,000 mg/l Aquatic Plant Toxicity Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static te
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, Respiration inhibition, 3 h: 784 mg/l Aquatic Invertebrates Chronic Toxicity Value Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, NOEC: 32 mg/l Data for Component: Isobutane No relevant data found. Data for Component: Propane No relevant data found.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Theoretical Oxygen Demand: 1.17 mg/mg Data for Component: Isobutane Biodegradation may occur under aerobic conditions (in the presence of oxygen). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.44E-12 cm3/s 4.4 d Estimated. Theoretical Oxygen Demand: 3.58 mg/mg Data for Component: Propane No relevant data found.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 Mobility in soil Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Mobility in soil: In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF 14. Issue Date: 12/10/2012 Transport Information DOT Non-Bulk CONSUMER COMMODITY RECLASSIFIED AS ORM-D MATERIAL DOT Bulk NOT AVAILABLE IN BULK CONTAINERS IMDG Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950 EMS Number: F-D,S-U Marine pollutant.: Yes ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF Issue Date: 12/10/2012 The following product components are cited in the Pennsylvania Hazardous Substance List and/or the Pennsylvania Environmental Substance List, and are present at levels which require reporting. Component CAS # Amount Diphenylmethane Diisocyanate, isomers and 9016-87-9 >= 15.0 - <= 30.0 % homologues 4,4' -Methylenediphenyl diisocyanate 101-68-8 >= 5.0 - <= 10.0 % Isobutane 75-28-5 >= 5.0 - <= 10.
™ Product Name: GREAT STUFF Pond & Stone Insulating Foam Sealant 12oz HC EF TWA ACGIH DOW IHG WEEL HAZ_DES Action Level Issue Date: 12/10/2012 Time Weighted Average American Conference of Governmental Industrial Hygienists, Inc. Dow Industrial Hygiene Guideline Workplace Environmental Exposure Level Hazard Designation A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded.
