SDS
DATE: 12/04/2015 COMPANY NAME: GIANI, Inc. PRODUCT CODE: CHOCOLATE BROWN Page 3
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Effect of Overexposure - inhalation: No adverse effects due to inhalation are expected.
Effect of Overexposure - skin contact: causes skin irritation. allergic reactions are possible. prolonged or repeated
contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash).
Effect of Overexposure - eye contact: liquid, aerosols and vapors of this product are irritating and can cause pain,
tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes.
Effect of overexposure - ingestion: this material may be harmful or fatal if swallowed. irritating to mouth, throat and
stomach.
Primary route(s) of entry: eye contact, ingestion, inhalation, skin absorption, skin contact
STOT - Single Exposure
Based on single exposure toxicity values, not classified.
STOT - Repeated Exposure Target Organs: Lungs
Based on repeated exposure toxicity values, not classified.
Carcinogenicity: The information below indicates whether each agency has listed any ingredient as a carcinogen if present at
levels greater than or equal to 0.1 %.
CAS-No. Name NTP OSHA IARC
14808-60-7 Quartz Group 1 Not labeled by OSHA Group 1
1333-86-4 Carbon Black Not labeled by NTP Not labeled by OSHA Group 2B
National Toxicological Program (NTP), Occupational Safety & Health Association (OSHA), International Agency for Research on
Cancer (IARC) Group 1: Carcinogenic to Humans, Group 2A: Probably Carcinogenic to Humans, Group 2B: Possibly Carcinogenic
to Humans, Group 3: Not Classifiable as to its Carcinogenicity to Humans
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Name Oral LD50 (mg/kg) Dermal LD50 (mg/kg) Vapor LC50 (mg/L)
57-55-6 Propylene Glycol > 5000 (rat) >2000 (rabbit) 4 h > 20 (rat)
1309-37-1 Red Iron Oxide > 5000 mg/l (rat) 5500 (rat)
9014-85-1 Ethoxylated 2,4,7,9- 6,300 (rat) > 2,000 (rabbit) 1 h >20 (rabbit)
tetramethyl 5 decyn-4,7-diol
34590-94-8 dipropylene glycol monomethyl ether >5,000 (rat) 9510 mg/kg (rabbit) 7 h 3.35 mg/l (rat)
25322-69-4 polypropylene glycol 681 (rat) N.D. N.D.
1333-86-4 Carbon Black (amorphous) >8000 (rat) N.D. N.D.
* INHALATION: Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be
occurring. Inhalation of dust may have the following serious chronic health effects: Silicosis: Excessive inhalation of respirable
crystalline silica dust may cause a progressive, disabling and sometimes fatal lung disease called silicosis. Symptoms include
cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. This disease is exacerbated by
smoking. Individuals with silicosis are predisposed to develop mycobacterial infections (tuberculous and non-tuberculous) and
fungal infections. Inhalation of air with a very high concentration of respirable silica dust can cause the most serious forms of
silicosis in a matter of months or a few years. Some epidemiologic studies have concluded that there is a significant risk of
developing silicosis even at airborne exposure levels that are equal to the recommended NIOSH REL, the ACGIH TLV, the OSHA
PEL and the MSHA Exposure Limit. Cancer Status: The International Agency for Research on Cancer has determined that
crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 -
carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in
conjunction with the use of these materials. The National Toxicology Program classifies respirable crystalline silica as “known to be
a human carcinogen”. Refer to the Eleventh Report on Carcinogens (2005). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2). Other Data with Possible
Relevance to Human Health: There is some evidence that breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder
manifested by fibrosis of the lungs, skin and other internal organs) rheumatoid arthritis, systemic lupus, erythematosus,
sarcoidosis, chronic bronchitis, chronic obstructive pulmonary disease (COPD), emphysema, chronic kidney disease and end-
stage renal disease.
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Section 12 - Ecological Information
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Ecotoxicity
Do not flush into surface water or sanitary sewer system.
Ecotoxicity Toxic to aquatic life. Based on acute aquatic toxicity values, not classified.
Toxicity to fish (Acute toxicity) Low acute toxicity to fish
Toxicity to daphnia and other Low acute toxicity to aquatic invertebrates.
aquatic invertebrates (Acute
toxicity)
Toxicity to algae (Acute toxicity) Low toxicity to algae.
Toxicity to fish (Chronic toxicity) Data not available
Toxicity to daphnia and other Low chronic toxicity to aquatic invertebrates.
aquatic invertebrates (Chronic
toxicity) Data not available
Toxicity to bacteria (Acute Low toxicity to sewage microbes.
toxicity)
Persistence and Degradability Expected to be biodegradable
Bioaccumulation/ Accumulation Not expected to bioaccumualte
Mobility No information available
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Section 13 - Disposal Considerations
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Waste Disposal Methods Hazardous waste code Dispose of contents/container in accordance with
local/regional/national/international regulations. Chemical waste generators must
determine whether a discarded chemical is classified as a hazardous waste. Chemical
waste generators must also consult local, regional, and national hazardous waste
regulations to ensure complete and accurate classification.
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Section 14 - Transport Information
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Important Note: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination.
Consult your company's Hazardous Materials/Dangerous Goods expert for information specific to your situation.
DOT – Not Regulated
DOT Proper Shipping Name: Paint Related Material Non Hazardous
DOT Hazard Class: Not Regulated
DOT UN/NA Number: Not Regulated
This material is not regulated as a dangerous good and can be shipped as a NON HAZARDOUS
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Section 15 - Regulatory Information
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FEDERAL REGULATIONS:
This product is considered non-hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
None
SARA 302 Extremely Hazardous Material: No
SARA 304 CERCLA Product
Chemical Name CAS Number Pct by Wt. RQ (lbs)
This product contains no known chemicals regulated under SARA 302/304.
SARA 311/312 Hazardous
Based upon available information, this material is not classified as a health and/or physical hazard according to Section 311 & 312.
SARA (313) Components in concentrations above the de minimus levels that are listed as toxic chemicals in 40 CFR Part 372
pursuant to the requirements in section 313 of SARA.
Name CAS-No.
Manganese compound
State Regulations
New Jersey right-to-know: CAS No.
Propylene Glycol 57-55-6
C.I. Pigment Red 101 1309-37-1
Crystalline Silica 14808-60-7
Calcium Carbonate 1317-65-3
Polypropylene glycol 25322-69-4
Talc 14807-96-6
Carbon Black (amorphous) 1333-86-4
Pennsylvania right-to-know:
Propylene Glycol 57-55-6
C.I. Pigment Red 101 1309-37-1
Crystalline Silica 14808-60-7
Calcium Carbonate 1317-65-3