SDS
R-600a, Isobutane 
Safety Data Sheet 
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation  (February 11, 2015). 
Hazardous Combustion Products: Carbon oxides (CO, CO
2
). Hydrocarbons. Toxic vapors. 
Other Information: Use water spray to disperse vapors. 
Reference to Other Sections 
Refer to Section 9 for flammability properties. 
SECTION 6: ACCIDENTAL RELEASE MEASURES 
 6.1.  Personal Precautions, Protective Equipment and Emergency Procedures 
General Measures: Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level. Eliminate 
every possible source of ignition. Do not get in eyes, on skin, or on clothing. Do not breathe vapors or gas. 
 6.1.1.  For Non-Emergency Personnel 
Protective Equipment: Use appropriate personal protection equipment (PPE). 
Emergency Procedures: Evacuate unnecessary personnel. 
6.1.2.  For Emergency Personnel 
Protective Equipment: Equip cleanup crew with proper protection. 
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, 
protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. 
Evacuate unnecessary personnel, isolate, and ventilate area. Ventilate area. 
6.2.  Environmental Precautions 
Prevent entry to sewers and public waters. 
6.3.  Methods and Materials for Containment and Cleaning Up 
For Containment: Stop leak, if possible without risk. As an immediate precautionary measure, isolate spill or leak area in all 
directions. 
Methods for Cleaning Up: Stop the source of the release, if safe to do so. Consider the use of water spray to disperse vapors. Isolate 
the area until gas has dispersed. Ventilate and gas test area before entering. Contact competent authorities after a spill. 
 6.4.  Reference to Other Sections 
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations. 
SECTION 7: HANDLING AND STORAGE 
7.1.  Precautions for Safe Handling 
Additional Hazards When Processed: Handle empty containers with care because residual vapors are flammable. Ruptured 
cylinders may rocket. Do not pressurize, cut, or weld containers. Ensure adequate ventilation. Asphyxiating gas at high 
concentrations. 
Precautions for Safe Handling:  Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking 
and when leaving work. Avoid prolonged contact with eyes, skin and clothing. Do not breathe gas. 
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. 
7.2.  Conditions for Safe Storage, Including Any Incompatibilities 
Technical Measures: Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. 
Storage Conditions: Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight, 
extremely high or low temperatures and incompatible materials. Keep in fireproof place. Cylinders should be stored upright with 
valve protection cap in place and firmly secured to prevent falling. Incompatible Materials: Strong acids, strong bases, strong 
oxidizers. 
7.3.  Specific End Use(s) 
Refrigerant.  For professional use only. 
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 
8.1.  Control Parameters 
 For substances listed in section 3 that are not listed here,  there are no established Exposure limits from the manufacturer, supplier, 
importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL), Canadian provincial 
governments, or the Mexican government. 
Isobutane (75-28-5) 
USA ACGIH  ACGIH STEL (ppm)  1000 ppm 
USA NIOSH  NIOSH REL (TWA) (mg/m³)  1900 mg/m³ 
USA NIOSH  NIOSH REL (TWA) (ppm)  800 ppm 
Manitoba  OEL STEL (ppm)  1000 ppm 
Newfoundland & Labrador  OEL STEL (ppm)  1000 ppm 
11/17/2016  EN (English US)  3/7






