Material Safety Data Sheet THE DOW CHEMICAL COMPANY Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Issue Date: 03/11/2014 Print Date: 12 Nov 2014 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Issue Date: 03/11/2014 Hazards of product: WARNING! May cause allergic skin reaction. May cause allergic respiratory reaction. May cause lung injury. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause central nervous system effects. May cause anesthetic effects. May cause respiratory tract irritation. Toxic fumes may be released in fire situations. May react with water.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam 4. Issue Date: 03/11/2014 First-aid measures Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Issue Date: 03/11/2014 may be applied in large quantities as a fine spray when other extinguishing agents are not available. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam 6 Months 8. Issue Date: 03/11/2014 15 - 27 °C Exposure Controls / Personal Protection Exposure Limits Component List Type Value ACGIH TWA 0.005 ppm OSHA Table Z-1 Ceiling 0.2 mg/m3 0.02 ppm AIHA WEEL TWA 4,240 mg/m3 1,000 ppm | 4,4’ -Methylenediphenyl diisocyanate | 1,1,1,2-Tetrafluoroethane Personal Protection Eye/Face Protection: Use chemical goggles.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Boiling Point (760 mmHg) Flash Point - Closed Cup Evaporation Rate (Butyl Acetate = 1) Flammability (solid, gas) Flammable Limits In Air Vapor Pressure Vapor Density (air = 1) Specific Gravity (H2O = 1) Solubility in water (by weight) Partition coefficient, noctanol/water (log Pow) Autoignition Temperature Decomposition Temperature Kinematic Viscosity Explosive properties Oxidizing properties Molecular Weight 10.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Issue Date: 03/11/2014 Dermal As product: The dermal LD50 has not been determined. Estimated. LD50, rabbit > 2,000 mg/kg Inhalation As product: The LC50 has not been determined. Eye damage/eye irritation May cause moderate eye irritation. May cause slight temporary corneal injury. Skin corrosion/irritation Prolonged contact may cause skin irritation with local redness. May stain skin.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Issue Date: 03/11/2014 EC50, Eisenia fetida (earthworms), 14 d: > 1,000 mg/kg Data for Component: 4,4’ -Methylenediphenyl diisocyanate The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Rate Constant Atmospheric Half-life 6.20E-15 cm3/s 1,700 d Theoretical Oxygen Demand: 0.47 mg/mg Issue Date: 03/11/2014 Method Estimated. Bioaccumulative potential Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Issue Date: 03/11/2014 Hazard Class: 2.2 ID Number: UN3500 DOT Bulk Proper Shipping Name: CHEMICAL UNDER PRESSURE, N.O.S. Technical Name: 1,1,1,2-Tetrafluoroethane Hazard Class: 2.2 ID Number: UN3500 IMDG Proper Shipping Name: CHEMICAL UNDER PRESSURE, N.O.S. Technical Name: 1,1,1,2-Tetrafluoroethane Hazard Class: 2.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam homologues 4,4’ -Methylenediphenyl diisocyanate 101-68-8 Issue Date: 03/11/2014 30.0 - 60.0 % Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute.
Product Name: FROTH-PAK™ 650 AF HFC CLASS A ISO Spray Polyurethane Foam Issue Date: 03/11/2014 activities such as exposure monitoring and medical surveillance if exceeded. THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product.
