Material Safety Data Sheet THE DOW CHEMICAL COMPANY Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Print Date: 11/12/2014 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Hazard Summary Issue Date: 07/29/2014 CAUTION!! May cause eye irritation. May be harmful if inhaled. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause central nervous system effects; may cause respiratory tract irritation. Isolate area. Keep upwind of spill. Contents under pressure. 3.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 4. FIRST AID MEASURES Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 absolutely necessary. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. 5. FIREFIGHTING MEASURES Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Methods and materials for containment and cleaning up: Contain spilled material if possible. Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional information. 7. HANDLING AND STORAGE Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: no data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Possibility of hazardous reactions: Will not occur by itself. Conditions to avoid: Product can oxidize at elevated temperatures.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Prolonged excessive exposure may cause adverse effects. In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. May cause respiratory irritation and central nervous system depression. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats).
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Contains component(s) which were negative in some in vitro genetic toxicity studies and positive in others. Contains component(s) which were negative in some animal genetic toxicity studies and positive in others. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Dimethyl Siloxanes and Silicones, 3-Hydroxypropyl Methyl, Ethoxylated Acute inhalation toxicity The LC50 has not been determined. 1,1,1,2-Tetrafluoroethane Acute inhalation toxicity LC50, rat, 4 Hour, vapour, > 1,500 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicological information on this product or its components appear in this section when such data is available.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Toxicity to bacteria EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 32 mg/l LOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, > 32 mg/l 1,1,1,3,3 - Pentafluoropropane Acute toxicity to fish Material is practically non-toxic to aqu
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 LC50, Pimephales promelas (fathead minnow), static test, 96 Hour, > 10,000 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l 2-エチルヘキサン酸カリウム塩 Acute toxicity to fish Based on information for a similar material: Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Acute toxicity to aquatic invertebrates EC50, Daphnia magna (Water flea), 48 Hour, 980 mg/l Toxicity to bacteria EC50, Pseudomonas putida, static test, 6 Hour, Growth inhibition, > 730 mg/l Persistence and degradability Sucrose , propylene oxide Biodegradability: Based on information for a similar material: Material is inherently biodegradable (reaches > 20% biodegradation in OECD test(s) for inherent biodegra
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Theoretical Oxygen Demand: 1.58 mg/mg Polyethylene glycol Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. 10-day Window: Pass Biodegradation: 85 % Exposure time: 28 d Method: OECD Test Guideline 301F or Equivalent Theoretical Oxygen Demand: 1.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 4 % Exposure time: 28 d Method: OECD Test Guideline 301D or Equivalent Theoretical Oxygen Demand: 0.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): -1.98 at 20 °C Estimated. Bioconcentration factor (BCF): 100 Fish Measured Dimethyl Siloxanes and Silicones, 3-Hydroxypropyl Methyl, Ethoxylated Bioaccumulation: No relevant data found.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 Partition coefficient(Koc): < 1 Estimated. Dimethyl Siloxanes and Silicones, 3-Hydroxypropyl Methyl, Ethoxylated No relevant data found. 1,1,1,2-Tetrafluoroethane Potential for mobility in soil is high (Koc between 50 and 150). Partition coefficient(Koc): 97 Estimated. 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Issue Date: 07/29/2014 This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative.
Product name: FROTH-PAK™ 650BF HFC CLASS A POLYOL Spray Polyurethane Foam Legend TWA US WEEL Issue Date: 07/29/2014 8-hr TWA USA. Workplace Environmental Exposure Levels (WEEL) Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company.
