SDS

November 2012 Version 1.1 Li-SOCl
2
single cells and multi-cell battery systems Page 2
2. HAZARD IDENTIFICATION
The Li-SOCl
2
batteries described in this Battery Information Sheet are sealed units which are not hazardous under normal
operating conditions in accordance with manufacturer’s recommendations, as stated in the user’s manual or other similar
documentation. Under normal use, the battery integrity is maintained and the active components it contains are isolated
from the outside.
In particular, the battery should not be submitted to any mechanical (opening, puncture, immersion), thermal (burning,
heating to temperatures above the normal temperature range of the product) or electrical abuse (short-circuit, recharge,
forced discharge), which will lead to the activation of safety valves and/or the rupture of the battery container.
Any accidental release of the inner components of the cell, or their combustion products could be highly hazardous.
Battery content exposition to air humidity/liquid water may be followed by severe battery vent/explosion/fire, depending
on the hazard causes and circumstances.
Protection from charging:
Whenever lithium batteries are not the single power source in a circuit, the following measures recommended by
Underwriters Laboratories are relevant. The cells should not be connected in series with an electrical power source that
would increase the load through the cells. The electronic circuit shall include one of the following:
A. Two suitable diodes or the equivalent in series with the cells to prevent any reverse (charging) current. The second
diode is used to provide protection in the event that one would fail. Quality control, or equivalent procedures,
shall be established by the device manufacturer to check that the diode polarity is correct for each unit.
or
B. A blocking diode or the equivalent to prevent any reverse (charging) current and a resistor to limit current in case
of diode failure. The resistor should be sized to limit the reverse (charging) current to the maximum value
according to the data sheet of the cell.
3. COMPOSITION, INFORMATION OR INGREDIENTS
Each unit cell consists of a hermetically sealed metallic can containing a number of chemicals and materials of construction
of which the following are potentially hazardous upon release to air.
Component CAS Number EINECS/ELINCS Content (wt. %)*
Lithium metal 7439-93-2 231-102-5 2-6
Thionyl dichloride 7719-09-7 231-748-8 18-47
Aluminium chloride 7446-70-0 231-208-1 1-5
Gallium chloride 13450-90-3 236-610-0 0-2
Lithium chloride 7447-41-8 231-212-3 1-2
Carbon 1333-86-4 215-609-9 2-5
PTFE 9002-84-0 N/A 0-1
Stainless steel, Nickel and inert material N/A N/A remainder
* Quantities may vary with cell model
4. HANDLING AND STORAGE
IMPORTANT NOTICE: Lithium-thionyle chloride batteries are not rechargeable and should not be tentatively charged or
recharged. Manufacturer’s recommendations should be followed regarding maximum current and operating
temperature range. Applying pressure or deforming the battery may lead to disassembly and cause eye, skin and throat
irritation.