Revision date: 24/05/2016 Revision: 1 SAFETY DATA SHEET PC Clene 100 Tub Wipes According to Regulation (EC) No 1907/2006, Annex II, as amended. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name PC Clene 100 Tub Wipes Product number APCC100, ZA 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Cleaning agent. Uses advised against No specific uses advised against are identified. 1.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes SECTION 3: Composition/information on ingredients 3.2. Mixtures 1-Methoxy-2-propanol 1-5% CAS number: 107-98-2 EC number: 203-539-1 REACH registration number: 012119457435-35-XXXX Classification Flam. Liq. 3 - H226 STOT SE 3 - H336 The full text for all hazard statements is displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information If in doubt, get medical attention promptly.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Harmful gases or vapours. 5.3. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapours. Evacuate area.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Long-term exposure limit (8-hour TWA): WEL 100 ppm 375 mg/m³ Short-term exposure limit (15-minute): WEL 150 ppm 560 mg/m³ Sk Ethanol Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³ Diethyl phthalate Long-term exposure limit (8-hour TWA): WEL 5 mg/m³ Short-term exposure limit (15-minute): WEL 10 mg/m³ WEL = Workplace Exposure Limit Sk = Can be absorbed through the skin. 8.2.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Vapour pressure 2.33 kPa @ 20°C Vapour density Not available. Relative density Not available. Bulk density Not available. Solubility(ies) Not available. Partition coefficient Not available. Auto-ignition temperature Not available. Decomposition Temperature Not available. Viscosity Not available. Explosive properties Not considered to be explosive.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Skin corrosion/irritation Animal data Based on available data the classification criteria are not met. Serious eye damage/irritation Serious eye damage/irritation Based on available data the classification criteria are not met. Respiratory sensitisation Respiratory sensitisation Based on available data the classification criteria are not met.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Notes (oral LD₅₀) LD₅₀ 3739 mg/kg, Oral, Rat REACH dossier information. Based on available data the classification criteria are not met. ATE oral (mg/kg) 3,739.0 Acute toxicity - dermal Notes (dermal LD₅₀) LD₅₀ >2000 mg/kg, Dermal, Rat REACH dossier information. Based on available data the classification criteria are not met. Skin corrosion/irritation Animal data Dose: 0.5 mL, 4 hours, Rabbit Erythema/eschar score: No erythema (0).
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Animal data Dose: 0.5 mL, 4 hours, Rabbit Erythema/eschar score: No erythema (0). Oedema score: No oedema (0). REACH dossier information. Based on available data the classification criteria are not met. Serious eye damage/irritation Serious eye damage/irritation Not irritating. Skin sensitisation Skin sensitisation Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising. REACH dossier information.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Genotoxicity - in vitro Gene mutation: Negative. REACH dossier information. Based on available data the classification criteria are not met. Genotoxicity - in vivo Chromosome aberration: Negative. REACH dossier information. Based on available data the classification criteria are not met. Carcinogenicity Carcinogenicity NOAEL 32 mg/kg/day, Dermal, Rat REACH dossier information. Based on available data the classification criteria are not met.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Acute toxicity - inhalation Notes (inhalation LC₅₀) LD₅₀ 124.7 mg/l, Inhalation, Rat REACH dossier information. Based on available data the classification criteria are not met. Skin corrosion/irritation Animal data Dose: 0.2 mL, 24 hours, Rabbit Primary dermal irritation index: 0 REACH dossier information. Based on available data the classification criteria are not met.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Carcinogenicity IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans. Specific target organ toxicity - repeated exposure STOT - repeated exposure NOAEL 1650 mg/kg/day, Oral, Mouse REACH dossier information. Based on available data the classification criteria are not met. Aspiration hazard Aspiration hazard 1.003 cSt @ 25°C/77°F REACH dossier information. Aspiration hazard if swallowed.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Notes (dermal LD₅₀) LD₅₀ >2000 mg/kg, Dermal, Rat REACH dossier information. Based on available data the classification criteria are not met. Skin corrosion/irritation Animal data Dose: 0.5 mL, 15 minutes, Rabbit Erythema/eschar score: Well defined erythema (2). Oedema score: Slight oedema - edges of area well defined by definite raising (2). REACH dossier information. Highly irritating.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes p-Cymene Acute toxicity - oral Notes (oral LD₅₀) LD₅₀ ~4750 mg/kg, Oral, Rat REACH dossier information. Based on available data the classification criteria are not met. Skin corrosion/irritation Skin corrosion/irritation Irritating to skin., Defatting, drying and cracking of skin., REACH dossier information. Serious eye damage/irritation Serious eye damage/irritation Causes serious eye irritation. REACH dossier information.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Acute toxicity - fish LC₅₀, 96 hours: 1370 mg/l, Pimephales promelas (Fat-head Minnow) Acute toxicity - aquatic invertebrates EC₅₀, 48 hours: 30.1 mg/l, Ceriodaphnia dubia Acute toxicity - aquatic plants EC₅₀, 96 hours: 2.2 mg/l, Pseudokirchneriella subcapitata Chronic toxicity - aquatic invertebrates NOEC, 21 days: 0.78 mg/l, Daphnia magna 2-Methoxypropanol Acute toxicity - fish LC₅₀, 96 hours: >1006 mg/l, Algae, Estimated value.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Acute toxicity - fish LC₅₀, 24 hours: 23 mg/l, Onchorhynchus mykiss (Rainbow trout) LC₅₀, 48 hours: 14 mg/l, Onchorhynchus mykiss (Rainbow trout) LC₅₀, 72 hours: 12 mg/l, Onchorhynchus mykiss (Rainbow trout) LC₅₀, 96 hours: 12 mg/l, Onchorhynchus mykiss (Rainbow trout) REACH dossier information. Acute toxicity - aquatic invertebrates LC₅₀, 48 hours: 90 mg/l, Daphnia magna REACH dossier information.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes 2,2',2''-Nitrilotriethanol Persistence and degradability The product is readily biodegradable. Phototransformation Water - DT₅₀ : 3.5 hours Biodegradation Water - Degradation 100%: 5 days Diethanolamine Phototransformation Water - DT₅₀ : 4.154 hours Biodegradation The substance is readily biodegradable. Water - Degradation 93%: 28 days 2-Methoxypropanol Biodegradation No data available.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Persistence and degradability The product is biodegradable. Phototransformation Water - DT₅₀ : 0.44-1.41 hours p-Cymene Biodegradation Water - Degradation 88%: 14 days 12.3. Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Not available. 1-Methoxy-2-propanol Bioaccumulative potential No data available on bioaccumulation.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Partition coefficient log Pow: 2.76 Pin-2(3)-ene Bioaccumulative potential BCF: 1845, Estimated value. Bioaccumulation is unlikely. Partition coefficient log Pow: 4.487 p-Cymene Bioaccumulative potential No data available on bioaccumulation. 12.4. Mobility in soil Mobility No data available. 1-Methoxy-2-propanol Mobility Mobile. Surface tension 70.7 mN/m @ 20°C 2,2',2''-Nitrilotriethanol Mobility Soluble in water.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Adsorption/desorption coefficient Water - Log Koc: 2.34 @ 21°C REACH dossier information. Henry's law constant 0.0399 Pa m³/mol @ °C Calculation method. REACH dossier information. Citral Mobility The product is partly soluble in water and may spread in the aquatic environment. Adsorption/desorption coefficient Water - Log Koc: 2.169 @ 25°C Estimated value. Henry's law constant 0.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes Diethyl phthalate Results of PBT and vPvB assessment This substance is not classified as PBT or vPvB according to current EU criteria. Citral Results of PBT and vPvB assessment This substance is not classified as PBT or vPvB according to current EU criteria. Pin-2(3)-ene Results of PBT and vPvB assessment This substance is not classified as PBT or vPvB according to current EU criteria.
Revision date: 24/05/2016 Revision: 1 PC Clene 100 Tub Wipes 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations Health and Safety at Work etc. Act 1974 (as amended).