Revision date: 15/03/2018 Revision: 1 SAFETY DATA SHEET Carterclene According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830 of 28 May 2015. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Carterclene Product number CTC-a, ECTC400H, ZP 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Cleaning agent.
Revision date: 15/03/2018 Revision: 1 Carterclene Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Revision date: 15/03/2018 Revision: 1 Carterclene 2-Aminoethanol CAS number: 141-43-5 <1% EC number: 205-483-3 REACH registration number: 012119486455-28-XXXX Classification Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Corr. 1B - H314 Eye Dam. 1 - H318 STOT SE 3 - H335 Ammonia 10 - <25% CAS number: 1336-21-6 <1% EC number: 215-647-6 REACH registration number: 012119488876-14-XXXX M factor (Acute) = 1 Classification Skin Corr. 1B - H314 Eye Dam.
Revision date: 15/03/2018 Revision: 1 Carterclene 2,6-Di-tert-butyl-p-cresol <1% CAS number: 128-37-0 EC number: 204-881-4 M factor (Acute) = 1 M factor (Chronic) = 1 Classification Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 The full text for all hazard statements is displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information Get medical attention immediately. Show this Safety Data Sheet to the medical personnel.
Revision date: 15/03/2018 Revision: 1 Carterclene Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Bursting aerosol containers may be propelled from a fire at high speed.
Revision date: 15/03/2018 Revision: 1 Carterclene SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Avoid exposing aerosol containers to high temperatures or direct sunlight. Avoid discharge to the aquatic environment. Do not handle until all safety precautions have been read and understood.
Revision date: 15/03/2018 Revision: 1 Carterclene 2,6-Di-tert-butyl-p-cresol Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ WEL = Workplace Exposure Limit Sk = Can be absorbed through the skin. 8.2. Exposure controls Protective equipment Appropriate engineering controls Provide adequate ventilation.
Revision date: 15/03/2018 Revision: 1 Carterclene Colour Colourless. Odour Fruity. pH pH (concentrated solution): 11-12 Melting point Not available. Initial boiling point and range Not available. Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Not available. Vapour pressure Not available. Vapour density Not available. Bulk density 0.97 kg/l Solubility(ies) Miscible with water.
Revision date: 15/03/2018 Revision: 1 Carterclene Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapours. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity - oral Notes (oral LD₅₀) Based on available data the classification criteria are not met. ATE oral (mg/kg) 149,960.
Revision date: 15/03/2018 Revision: 1 Carterclene Inhalation Spray/mists may cause respiratory tract irritation. Ingestion Due to the physical nature of this product, it is unlikely that ingestion will occur. Skin contact Repeated exposure may cause skin dryness or cracking. Eye contact May be slightly irritating to eyes. May cause discomfort. Route of exposure Ingestion Inhalation Skin and/or eye contact Target organs No specific target organs known. Toxicological information on ingredients.
Revision date: 15/03/2018 Revision: 1 Carterclene ATE inhalation (vapours mg/l) 11.0 Skin corrosion/irritation Animal data Dose: 0.5 mL, 4 hours, Rabbit Erythema/eschar score: Well defined erythema (2). Oedema score: No oedema (0). REACH dossier information. Irritating. Serious eye damage/irritation Serious eye damage/irritation Dose: 0.1 mL, 24 hours, Rabbit Causes serious eye irritation. Skin sensitisation Skin sensitisation Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising.
Revision date: 15/03/2018 Revision: 1 Carterclene Animal data Dose: 0.5 mL, 4 hours, Rabbit Erythema/eschar score: Well defined erythema (2). Oedema score: Very slight oedema - barely perceptible (1). REACH dossier information. Repeated exposure may cause skin dryness or cracking. Serious eye damage/irritation Serious eye damage/irritation Dose: 0.1 mL, 1 second, Rabbit REACH dossier information. Based on available data the classification criteria are not met.
Revision date: 15/03/2018 Revision: 1 Carterclene Acute toxicity - inhalation Acute toxicity inhalation (LC₅₀ dust/mist mg/l) 1.3 Species Rat Notes (inhalation LC₅₀) Supplier's information. Harmful if inhaled. ATE inhalation (dusts/mists mg/l) 1.3 Skin corrosion/irritation Animal data Dose: 0.5 mL, 4 hours, Erythema/eschar score: Severe erythema (beef redness) to eschar formation preventing grading of erythema (4). REACH dossier information. Corrosive.
Revision date: 15/03/2018 Revision: 1 Carterclene ATE oral (mg/kg) 795.0 Acute toxicity - dermal Notes (dermal LD₅₀) LD₅₀ 3412.5 mg/kg, Dermal, Rabbit REACH dossier information. Based on available data the classification criteria are not met. Skin corrosion/irritation Animal data Dose: 0.5 mL, 4 hours, Rabbit REACH dossier information. Corrosive. Serious eye damage/irritation Serious eye damage/irritation Corrosive to skin. Corrosivity to eyes is assumed.
Revision date: 15/03/2018 Revision: 1 Carterclene 2-Butoxyethanol Toxicity Aquatic toxicity is unlikely to occur. Based on available data the classification criteria are not met.
Revision date: 15/03/2018 Revision: 1 Carterclene Chronic toxicity - fish early NOEC, 41 days: 1.24 mg/l, Oryzias latipes (Red killifish) life stage Chronic toxicity - aquatic invertebrates NOEC, 21 days: 0.85 mg/l, Daphnia magna Ammonia 10 - <25% Acute aquatic toxicity LE(C)₅₀ 0.1 < L(E)C50 ≤ 1 M factor (Acute) 1 Benzyl-C12-14-alkyldimethylammonium chlorides Toxicity Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Very toxic to aquatic life with long lasting effects.
Revision date: 15/03/2018 Revision: 1 Carterclene Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Persistence and degradability Readily biodegradable but failing the 10-day window. Biodegradation Water - Degradation ~5%: 3 days Water - Degradation 69%: 28 days 2-Aminoethanol Phototransformation Water - DT₅₀ : 10.742 hours Estimated value.
Revision date: 15/03/2018 Revision: 1 Carterclene Partition coefficient log Pow: 2.75 12.4. Mobility in soil Mobility The product contains volatile organic compounds (VOCs) which will evaporate easily from all surfaces. Ecological information on ingredients. Petroleum gases, liquefied Mobility The product contains volatile organic compounds (VOCs) which will evaporate easily from all surfaces. 2-Butoxyethanol Mobility The product is miscible with water and may spread in water systems.
Revision date: 15/03/2018 Revision: 1 Carterclene Results of PBT and vPvB assessment This substance is not classified as PBT or vPvB according to current EU criteria. Benzyl-C12-14-alkyldimethylammonium chlorides Results of PBT and vPvB assessment This substance is not classified as PBT or vPvB according to current EU criteria. 12.6. Other adverse effects Other adverse effects None known. SECTION 13: Disposal considerations 13.1.
Revision date: 15/03/2018 Revision: 1 Carterclene IMDG class 2.2 ICAO class/division 2.2 ADN class 2.2 Transport labels 14.4. Packing group ADR/RID packing group None IMDG packing group None ADN packing group None ICAO packing group None 14.5. Environmental hazards Environmentally hazardous substance/marine pollutant No. 14.6. Special precautions for user Always transport in closed containers that are upright and secure.
Revision date: 15/03/2018 Revision: 1 Carterclene No chemical safety assessment has been carried out. Inventories EU - EINECS/ELINCS None of the ingredients are listed or exempt. SECTION 16: Other information Abbreviations and acronyms used in the safety data sheet ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways.
Revision date: 15/03/2018 Revision: 1 Carterclene Hazard statements in full H220 Extremely flammable gas. H222 Extremely flammable aerosol. H225 Highly flammable liquid and vapour. H229 Pressurised container: may burst if heated. H280 Contains gas under pressure; may explode if heated. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage.
