SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Safety Data Sheet Regulation : In accordance with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR 1910.1200 Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with normal use. This battery is an article pursuant to 29 CFR 1910.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. SAMSUNG SDI Co., Ltd. makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities from reliance on it.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 2.3 Other hazards : Appearance, Color and Odor: Solid object with no odor. Primary Routes(s) of Exposure: These chemicals are contained in a sealed enclosure. Risk of exposure occurs only if the cell or pack is mechanically, thermally, electrically or physically abused to the point of compromising the enclosure.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 12190-79-3 235-362-0 - 1~10 cobalt lithium dioxide 7440-50-8 231-159-6 - 1~10 Copper 616-38-6 210-478-4 - 1~10 dimethyl carbonate 7429-90-5 231-072-3 - 1~10 Aluminium 9002-88-4 Not available - 1~10 Polyethylene 96-49-1 202-510-0 - 1~10 1,3-Dioxolan-2-one 21324-40-3 244-334-7 - 1~10 lithium hexafluorophosphate(1-) 141-78-6 205-500-4 - 0.1~1 ethyl acetate 1333-86-4 215-609-9 - 0.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - In case of inhalation of organic electrolyte mist, remove from exposure to fresh air. - If necessary give oxygen. Get medical attention. Following ingestion : - In case of ingestion of electrolyte don’t induce vomiting. - If patient is conscious and alert give 2~4 cupfuls of milk or water. - Never give anything by mouth to an unconscious person. - Get medical attention immediately.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Use personal protective equipment, see Section 8 Emergency procedures : - In case of cell damage, possible release of dangerous substances and a flammable gas mixture. - Eliminate all ignition sources. - Please note that materials and conditions to avoid.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Storage at room temperature (approx. 20℃) at approx. 40% of the nominal capacity - Keep in closed original container. 7.3 Specific end use(s) Recommendations : Not available Industrial sector specific solutions : Not available Section VIII – EXPOSURE CONTROLS / PERSONAL PROTECTION 8.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Copper TWA = 0.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R compounds (as Ni)) lithium carbonate 1-Methyl-2-pyrrolidinone Not applicable Not applicable 0.015 mg/m3 (soluble compounds (as Ni)) Not applicable Not available Not applicable Not applicable Not available TWA = 40 mg/m³, TWA= 10 Not applicable Not applicable ppm, STEL = 80 mg/m³, STEL = 20 ppm 8.2 Exposure controls 8.2.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Discard contaminated work clothing after one work day. Respiratory protection : - None required during normal use. - Wear NIOSH or European Standard EN 149 approved full or half face piece (with goggles) respiratory protective equipment when necessary. - In lack of oxygen(< 19.5%), wear the supplied-air respirator or self-contained oxygen breathing apparatus.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Explosive properties : Not available Oxidizing properties : Not available Molecular weight : Not available 9.2 Other information Not available Section X – STABILITY AND REACTIVITY 10.1 Reactivity - Stable at ambient temperature. 10.2 Chemical stability - There is no hazard when the measures for handling and storage are followed. - Stable under normal temperatures and pressures. 10.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Section XI – TOXICOLOGICAL INFORMATION ※ This is a product that fulfills a certain function in solid state with specific shape without discharging any chemical substance in its use and has no obligation to write (M)SDS.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Copper : In test on skin irritation with rabbits, skin irritations were not observed. (OECD TG 404, GLP) - Dimethyl carbonate : In the skin irritation test using rabbits, the test material was not irritating. (OECD Guideline 404) - Aluminum : Aluminium oxide caused slight erythema in 2/12 rabbits. The observed effects do not lead to a classification.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Copper : In maximization test on skin sensitization with guinea pig, skin sensitization was not observed. (OECD TG 406, GLP) - Dimethyl carbonate : In the skin sensitization test using guinea pig, this material was not skin sensitizing. (OECD Guideline 406, GLP) - Aluminum : In test with guinea pigs, it can be concluded that aluminium oxide has no sensitisation potential under the experimental conditions.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Fe : In mammalian cell gene mutation assay electrolytic iron, positive carbonyl iron exhibited a cytotoxic and mutagenic response (OECD TG 476) - Copper : Negative reactions were observed in both in vitro(Ames test) and in vivo(DNA damage and/or repair; unscheduled DNA synthesis, micronucleus assay).
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R GLP) - Carbon black : No effect on endothelins or blood pressure was observed after exposure to carbon black. There were also no effects on body temperature and activity of the animals. - Nickel; Raney nickel : In the acute oral toxicity using rat, there were no effects on clinical signs, systemic toxicity.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Lithium hexafluorophosphate(1-) : 96hr-LC50 = 51 ~ 193 mg/L Information on major hydrolysis product of the registered substance (released rapidly on contact with water/moisture); 21d-NOEC = 4 mg F-/L - Ethyl acetate : 96hr-LC50 = 230 mg/L - Carbon black : 96hr-LC0 = 1000 mg/L (OECD TG 203, GLP) - Lithium carbonate;Lithane : 96hr-LC50 = 30.3 mg/L (OECD Guideline 203, GLP), 34d-NOEC (Danio rerio) = 15.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Copper : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 0.02 ~ 20) - Dimethyl carbonate : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.2) - Aluminum : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.162) (estimated) - 1,3-Dioxolan-2-one : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Section XIV – TRANSPORTATION INFORMATION ※ If those lithium-ion batteries are packed with or contained in an equipment, then it is the responsibility of the shipper to ensure that the consignment are packed in compliance to the latest edition of the IATA Dangerous Goods Regulations section Ⅱ of either Packing Instruction 966 or 967 in order for that consignment to be declared as NOT RESTRICTED (non-hazardous/non-Dangerous).
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - 1-Methyl-2-pyrrolidinone : Regulated Foreign Regulatory Information External information : U.S.A management information (OSHA Regulation) : Not regulated U.S.A management information (CERCLA Regulation) : - Copper : 5,000 lb - ethyl acetate : 5,000 lb - Nickel : 100 lb U.S.A management information (EPCRA 302 Regulation) : Not regulated U.S.A management information (EPCRA 304 Regulation) : Not regulated U.S.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 16.4 Classification and procedure used to derive the classification for mixtures according to Regulation(EC) 1272/2008(CLP) : Not classified 16.5 Relevant H-statements : Not applicable 16.6 Training advice : - Do not handle until all safety precautions have been read and understood. 16.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q Revision no.: 01 Material Safety Data Sheet 1. Product and Company Identification Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with normal use. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the OSHA Hazard Communication Standard requirement.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q Revision no.: 01 OSHA Hazard Communication: This material is not considered hazardous by the OSHA Hazard Communication Standard 29CFR 1910.1200. Carcinogenicity (NTP): Carcinogenicity (IARC): Carcinogenicity (OSHA): Not listed Not listed Not listed Special hazards for human health and environment There is no hazard when the measures for handling and storage are followed.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q 7439-96-5 24937-78-8 36619-23-5 7440-44-0 13463-67-7 7440-21-3 25038-81-7 7439-95-4 Revision no.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q Revision no.: 01 Cold water and dry powder in large amount are applicable. Use metal fire extinction powder or dry sand if only few cells are involved. Special hazards arising from the chemical May form hydrofluoric acid if electrolyte comes into contact with water. In case of fire, the formation of the following flue gases cannot be excluded: Hydrogen fluoride (HF), Carbon monoxide and carbon dioxide.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q Manganese R20/22 (VI) oxide Nickel oxide R43,R49, R53 Carbon R36/37/3 8, R36/37 R20, R10 Revision no.: 01 Xn(Harmful) Airborne Exposure Limits: - OSHA Permissible Exposure Limit (PEL): 5 mg/m3 Ceiling for manganese compounds as Mn - ACGIH Threshold Limit Value (TLV): 0.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q Revision no.: 01 No specific precautions necessary. Protective and hygiene measures When using do not eat, drink or smoke. Wash hands before breaks and after work. Respiratory protection No specific precautions necessary. Hand protection No specific precautions necessary. Eye protection No specific precautions necessary. Skin protection No specific precautions necessary. 9.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q Revision no.: 01 Possibility of Hazardous Reactions Will not occur Additional information No decomposition if stored and applied as directed. 11. Toxicological Information Empirical data on effects on humans If appropriately handled and if in accordance with the general hygienic rules, no damages to health have become known. 12. Ecological Information Further information Ecological injuries are not known or expected under normal use.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q Revision no.: 01 No T1 T2 T3 T4 T5 T6 T7 Test item Altitude Simulation Thermal Test Vibration Shock External Short Circuit Impact/Crush Overcharge Pass Pass Pass Pass Pass Pass Pass T8 Forced Discharge Pass For pack and single cell battery only 15. Regulatory Information U.S. Regulations National Inventory TSCA All of the components are listed on the TSCA inventory.
SAMSUNG SDI Co., LTD Date: January 12, 2015 MODEL INR18650-15Q R48/23 R49 R50 R53 Revision no.: 01 Toxic: danger of serious damage to health by prolonged exposure through inhalation. May cause cancer by inhalation. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
