User Guide
SECTION15.REGULATORYINFORMATION
ECClassication:Not classied
Riskphrases:
R18 In use, may form ammable/explosive vapour-air mixtures
R20: Harmful by inhalation
R22: Harmful if swallowed
R36: Irritating to eyes.
R37:Irritating to respiratory system.
R38: Irritating to skin.
R53: May cause long-term adverse effects in the environment.
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapors may cause drowsiness and dizziness
Safetyphrases
S2: Keep out of reach of children
S7: Keep container tightly closed.
S9: Keep container in a well-ventilated place.
S16: Keep away from sources of ignition - No smoking.
S23: Do not breathe fumes, vapor or spray
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S61: Avoid release to the environment. Refer to special instructions/safety data sheets
US EPA:
ComprehensiveEnvironmentalResponseCompensationandLiabilityActof1980(CERCLA):Spills or releases resulting in the loss of any ingredient at
or above its RQ requires immediate notication to the National Response Center [(800) 424-8802] and to your Local Emergency Planning Committee.
RQ: 2000 pounds (1,2 dichloroethylene)
SuperfundAmendmentsandReauthorizationActof1986(SARA)Title III requires emergency planning based on threshold planning quantities and release
reporting based on reportable quantities in 40 CFR 355 (used for SARA 302, 304, 311, and 312) is not required.
SuperfundAmendmentsandReauthorizationActof1986(SARA)Title III requires submission of annual reports of release of toxic chemi-
cals that appear in 40 CFR 372 (for SARA 313). This material is not subject to reporting requirements.
ToxicSubstancesControlAct(TSCA)Status:The ingredients of this product are on the TSCA inventory.
StateRighttoKnow
California Proposition 65:
Massachusetts: Hazardous substances and extraordinarily hazardous substances must be identied.
Pennsylvania: Hazardous substances must be identied.
California SCAQMD Rule 443.1 (VOC’s): 0%
SARA 311/312: Acute: No Chronic: No Fire: No Pressure: Yes Reactivity: No
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of
the information required by the CPR. Acetone meets the Canadian WHMIS criteria for classes:
B2: Flammable and combustible material: Flammable liquid
D2B- Poisonous and Infectious material-Other Effects: Toxic
FOREIGNINVENTORYSTATUS:
Ethyl Nonauoroisobutyl Ether: Not listed
Ethyl Nonauorobutyl Ether: Not listed
Trans-1,2-Dichloroethylene
Europe: ELINCS #419 170 6 #205-860-2
Trans-1,2-dichloroethylene
Japan: MOL 2-(13)-143
Canada: Notied Listed DSL
Australia: Notied
16.OTHERINFORMATION:
NFPARatings:
NFPAClassication:Health - 2, Flammability - 1, Reactivity – 1
HMISIIIClassication:Health – 2, Flammability – 1, Physical Hazard-1
Label Hazard Warning: Store Pro-Flush™ in a cool, dry area, away from sources of ignition. Use only with adequate ventilation. Wear
suitable personal protective equipment to prevent contact with skin or eyes. Avoid breathing fumes vapors or mists. Do not take internally.
May be harmful or fatal if swallowed.
LabelFirstAid: For eye contact, rinse the eyes with running water for 15 minutes, lifting the eyelids occasionally to ush the area behind the
lid. If irritation persists, get medical attention. For skin contact, wash the affected area with soap and water, then rinse thoroughly with water.
Wash contaminated clothing before re-use. For inhalation, remove affected individual to fresh air. If the victim is not breathing, administer
articial respiration. If breathing is difcult, administer oxygen. Get medical attention. If swallowed, do not induce vomiting. Dilute by drinking
3-4 glasses of water of milk, and call the nearest poison control center or the National Poison Control Hotline 1-800-222-1222 for advice.
Product Use: Flushing Solvent for air conditioning and refrigeration equipment.
This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However no representation, warranty or guarantee is made
as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the completeness and suitability of such information for his own par-
ticular use. We do not accept liability for any loss or damage that may occur from the use of this information, nor do we offer any warranty against patent infringement.
Oral,rat:LD50 = 4100 mg/kg
Skin,rabbit:LD50 = >2 gm/kg
Ethyl Nonauoroisobutyl Ether
Ethyl Nonauorobutyl Ether
AcuteOralToxicity,LD50-Rat:>2.0 grams/KG body weight.
AcuteInhalationToxicity,4-hourLC50-Rat:92,000ppm
Trans-1,2-dichloroethylene
AcuteDermal(rabbit)LD50:> 5,000mg/kg
AcuteInhalation(rat)4-hr.LC50:>24,100 ppm
Delayed(SubchronicandChronic)Effects:
Ethyl Nonauoroisobutyl Ether
Ethyl Nonauorobutyl Ether
For a mixture of ethyl nonauorobutyl ether and its isomer, a single positive response for cardiac sensitization was observed at an exposure level of
49,000
ppm. No adverse health effects are anticipated from normal handling and use.
Trans-1,2-dichloroethylene
Embryotoxicity(rats):Not a teratogen. Fetal toxicity present only at maternally toxic concentrations.
Doselevels:0, 2,000, 6,000, and 12,000 ppm
NOEL(pups):12,000 ppm (decreased bodyweight, increased skeletal variations)
NOEL(dams):6,000 ppm
90-dayInhalationStudy(rats): NOAEL – 4,000 ppm, the highest level tested
Doselevels:200, 1,000, 4,000 ppm
OtherData:
Ethyl Nonauoroisobutyl Ether
Ethyl Nonauorobutyl Ether
Eye Irritation: Minimally irritating to eyes
Skin Irritation: Non-irritating to skin
Skin Sensitization: Not a skin sensitizer
Trans-1,2-dichloroethylene
Genetic studies: Not mutagenic to E-coli or S. typhimurium when incubated in the presence of liver enzymes. Not mutagenic in Saccharomyces
cerevisiae with or without microsomal activation.
SECTION12.ECOLOGICALINFORMATION
EnvironmentalFate:No information found.
EnvironmentalToxicity:
Acetone
Ecotoxicity: Rainbow trout LC50=5540 mg/L/96H; Sunsh (tap water), death at 14250 ppm/24H; Mosquito sh (turbid water) TLm=13000
ppm/48H
EnvironmentalFate:Volatilizes, leeches, and biodegrades when released to soil.
Physical/Chemical:No information available.
t-Butyl Acetate
Ecotoxicity: Bacteria: Phytobacterium phosphoreum: EC50 = 6.38-11.1 mg/L; 5,15,30 minutes; Microtox test; 15 degrees C Based on a log
Kow of 1.38, the BCF value for tert-butyl acetate can be estimated to be 6.6 by a recommended regression-derived equation. This BCF value
suggests that bioconcentration is not signicant.
Environmental:Chemical hydrolysis of tert-butyl acetate in moist, very alkaline soils (pH approaching 10 or higher) may be important, but
hydrolysis in soils of pH 9 or lower is not expected to be important. Based on an estimated Koc value of 134, tert-butyl acetate may be subject
to signicant leaching in soil. Volatilization from dry soil surfaces may be rapid.
Physical:ATMOSPHERIC FATE: tert-Butyl acetate will exist almost entirely in the vapor-phase in the ambient atmosphere due to its
expected high vapor pressure. The half-life for the vapor-phase reaction of tert-butyl acetate with photochemically produced hydroxyl radicals
has been estimated to be about 26 days in an average atmosphere indicating that this reaction may be the dominant atmospheric degradation
mechanism. Physical removal via washout may be possible.
Other: Do not empty into drains.
Ethyl Nonauoroisobutyl Ether
Ethyl Nonauorobutyl Ether
Test Organism Test Type Result
Water ea, Daphnia magna 48 hours Effect Concentration 50% >2.55 mg/l
Fathead Minnow, Pimephales promelas 96 hours Lethal Concentration 50% >2.75 mg/l
Green algae, Selenastrum capricornutum 96 hours Effect Concentration 50% >2.32 mg/l
SECTION13.DISPOSALCONSIDERATIONS
Dispose of spill-clean up and other wastes in accordance with Federal, State, and local regulations. Whatever cannot be saved for recovery or recycling should
be managed in an appropriate and approved waste facility. All spent material must be disposed of in accordance with all applicable Federal and State RCRA
Regulations. Consult with appropriate regulatory agencies before disposing of waste material. The information offered here is for the product as shipped. Use
and/or alterations to the product such as mixing with other materials may signicantly change the characteristics of the material and alter the RCRA classica-
tion and the proper disposal method. The unused product is an RCRA hazardous waste if discarded. The RCRA ID number is: U079 (1,2 dichloroethylene)
U002 (Acetone, Ignitability)
SECTION14.TRANSPORTATIONINFORMATION
US DOT: Not regulated for ground transport in quantities below 5 liters.
International
Water,I.M.O.:DangerousGoodsDescription:UN3082, Environmentally Hazardous Substance, Liquid, NOS (Contains trans 1,2 dichloroethylene),
9, PGIII (Ltd.QTY)
Marine Pollutant: No
10 11