User guide

DuoSpray™ Ion Source User Reference
AB SCIEX TripleTOF
®
5600/5600+ Instruments
92 of 116
System User Guide
D5033331 A
especially if the probe is too low, resulting in signal instability and a high chemical background
noise. Similarly, a high heater gas flow could produce a noisy or unstable signal.
1. Adjust GS1 and GS2 in increments of 5 to achieve the best signal or signal-to-noise
ratio.
2. Increase CUR until the signal starts to decrease.
3. Adjust ISVF in increments of 100 V to achieve the best signal or signal-to-noise ratio.
Optimize the Turbo Heater Temperature
The quantity and type of sample affects the optimal TurboIonSpray probe temperature. At higher
flow rates the optimal temperature increases.
Adjust the TEM value in increments of 50°C to achieve the best signal or signal-to-
noise ratio.
Optimize for the Compound
Adjust the DP value in increments of 10 to achieve the best signal or signal-to-noise
ratio. DP optimizes between 60 to 200.
Optimize the APCI Probe
Optimize performance by injecting a known compound and monitoring the signal of the known
ion. Adjust the parameters to maximize the signal-to-noise ratio.
Run the Method
Caution: Potential Equipment Damage: Warm the ceramic heater slowly to avoid thermal
shock to the heating element.
Note: To prevent contamination, use the highest value for CUR possible
without sacrificing sensitivity. Do not set CUR lower than 20.
Note: If the ISVF is too high, a corona discharge can occur. It is visible as
a blue glow at the tip of the TurboIonSpray probe. This will result in
decreased sensitivity and stability of the ion signal.
WARNING! Toxic Chemical Hazard: Vent the source exhaust system to an
external fume hood or an external vent to prevent hazardous vapors from being
released into the laboratory environment.
Table 7-3 Typical Values for Optimizing the APCI Probe
Parameter Typical value Operational range
Probe X-axis position 5 mm Scale 0 mm to 10 mm
Probe Y-axis position 5 mm Scale 0 mm to 13 mm
The optimal X-axis position is within 0 mm to 2 mm on either side of the orifice.
The optimal probe Y-axis position is within 3.0 mm to 7.0 mm of the orifice.