SDS

SAFETY DATA SHEET PRODUCT CODE: 356PAVOCx
5 OF 3
COMPONENT Xylene: Inhalation LC50 26800ppm, Skin LD50 2000 mg/kg, Ingestion LD50 4.3 g/kg. Exposure may effect skin, eye, liver,
kidney, nervous system, respiratory system and lungs. High concentrations may lead to nervous system effects. Repeated overexposure has
produced toxic effects in developing and young laboratory animals. Aspiration into lungs when swallowed or vomited may cause chemical
pneumonitis which can be fatal. Xylene may contain ethyl benzene.. Ethyl benzene has shown limited evidence of a carcinogenic effect.
COMPONENT Ethyl Benzene: Acute Oral toxicity LD50: ca. 3500 mg/kg (rat); Acute inhalation LC50: 17.2 mg/l 4h (rat); Acute Dermal
Toxicity: 17,800 mg/kg (rabbit); Skin Irritation rabbit Draize exposure time 24h – slightly irritating. Eye Irritation rabbit Draize – severely
irritating. Sensitization dermal (human patch test) non-sensitizer.Repeated Dose toxicity 28 days inhalation NOAEL: 3.4 mg/l (rabbit).
Mutagenicity Genetic Toxicity in Vitro: Ames: Negative (salmonella typhimurium, metabolic activation with/without). Carcinogenecity: Ethyl
benzene was tested by inhalation exposure in mice and rats. Ibn mice, there was an increased incidence of lung adenomas in males and liver
adenomas in females. In male rats, there was an increased incidence of renal tubule adenomas and carcinomas. Two Studies of workers
potentially exposed to ethyl benzene in a production plant and a styrene polymerization plant, showed no excess cancer incidence and no
excess cancer mortalitry during a 15 year follow-up. Toxicity to Reproduction/Fertility: Inhalation (monkey, male) Reproductive effects have
been observed in animal studies, In a generation study, inhalation (rat/female) NOAEL (parental): 100ppm NOAEL (F2): 100ppm.
Developmental Toxicity/Teratogenicity rat, female, inhalation, gestation, daily, NOAEL (teratogenicity): 100ppm (maternal): 100ppm.
Tratogenetic effects seen only with maternal toxicity., Fetotoxicity seen only with maternal toxicity. Rabbit, female, inhalation, gestation, daily,
NOAEL (teratogenicity) < 1000 mg/m3, NOAEL (maternal) < 1000 mg/m3.
Component CAS# 110-43-0: Oral LD 50 (rat): 1600 mg/kg; Oral LD50 (mouse) 730 mg/kg; Inhalation LC50 (rat) 2000-4000 ppm, 4 hr.
Dermal LD50 (rabbit) 10206 mg/kg; Dermal LD50 (guinea pig) >16200 mg/kg; Skin irritation (Rabbit) – slight to moderate; Eye irritation (rabbit)
slight; Skin sensitization (human) none
SECTION 12: ECOLOGICAL INFORMATION
No da
ta for the product itself.
Component data:
COMONENT Homopolymer of HDI: Biodegradation: 0%, Exposure time: 28 days, not readily biodegradable. Acute and Prolonged Tocicity to
fish LC0 > 100 mg/l (zebra fish, 96 h). Acute toxicity to aquatic invertebrates: EC0 > 100 mg/l (water flea, 48 h. Toxicity to aquatic plants EC50
> 1000 mg/l (gr
een algae, 72 h. Toxicity to Microorganisms: EC50 > 1000 mg/l (activated sludge microorganisms, 3 h)
.
COMP
ONENT n-Butyl Acetate: Biodegradation: aerobic, 98%, exposure time 28 days. Biochemical oxygen demand (BOD) 1020 mg/g
.
Chemical Oxygen demand (
COD) 2,320 mg/g. Bioaccumulation: ca. 4-14 BCF. Acute and Prolonged Toxicity to Fish LC50: 18 mg/l (fat
head
Minnow, 96 h). A
cute Toxicity to Aquatic Invertabrate EC50: 72.8 mg/l (water flea, 48 h). Toxicity to aquatic plants EC50: 670 mg/l, end
point:
growth
(Crytomonad, 48 h). Toxicity to Microorganisms EC50: 959 mg/l (Pseudomonas putida, 48 h)
.
COMP
ONENT Xylene: Acute Toxicity: Fish: Toxic 1 < LCECIC50 < 10mg/l, Aquatic Invertabrates: To
xic 1 < LC/EC/IC50 <10mg/l, Algae:
Toxic 1 < LC/EC/IC50 <10 mg/l. M
obility – floats on water. If it enters the soil it will be highly mobile and may contaminate groundwater.
Oxidises rapidly by photo-c
hemical reactions in air.
COMP
ONENT Ethyl Benzene: Biodegradation, Aerobic, 50%, Exposure time 28 days. .Biochemical Oxygen demand (BOD) 5 days, 2.
8%
and 35 days, 178
0 mg/g. Bioaccumulation: Cyprinus carpio (Carp), 15 BCF. Acute and Prolonged Toxicity to Fish LC50: 12.1 mg/l (fath
ead
minnow, 96 h). A
cute Toxicity to Aquatic Invertebrates EC50: 1.8-2.9 mg/l (water flea, 48 h). Toxicity to Aquatic Plants EC50: 4.6 mg/l (g
reen
algae, 72 h).
Toxicity to microorganisms EC50: 130 mg/l (activated sludge microorganisms, 48 hr).
Com
ponent Dibutylin Dilurate CAS# 77-58-7: ACUTE ORAL TOX (LD50,RAT) 3200.00 MG/KG. ACUTE DERMAL TOX (LD50,
RABBIT)
>2000 MG/K
G (NO DEATHS). ACUTE INHAL TOX (LC50, RAT) >8.10 MG/L/1 HR. AMES TEST: NEG (ACTIVATED & NONACTIVAT
ED)
INDUST
CHEMS SUC H AS THIS MATL W/ACUTE TOX VALUES SHOWN & WHOSE VAPS/MISTS ARE NOT LIKE
LY TO BE
ENCO
UNTERED BY HUMANS WHEN USED IN ANY REASONA
BLY
FORESEEABLE MANNER WOULD NO
T REQ TOXIC LBL ACCORD TO U.S. DOMESTIC & INTERNATIONAL TRANSPORT REQS. IRRI
T
EFTS DAT:
SEV IRRITANT TO EYES OF RABBIT. MOD IRRITANT TO SKIN OF
RABBIT.
Com
ponent CAS# 110-43-0: BOD-5: 1770 mg/kg; BOD-20: 2000 mg/kg; COD: 2420 mg/kg. Acute Aquatic Effects: 96 hr LC50 (fath
ead
minnow) 131 m
g/l and 48 hr EC50 (daphnia) >90 mg/l (highest concentration tested)
SECTION 13: WASTE DISPOSAL
WASTE DISPOSAL METHOD:
DISPOSE OF THE MATERIAL IN A WASTE DISPOSAL SITE IN ACORDANE WITH LOCAL, STATE, AND FEDERAL LAW.
SECTION 14: Transport Information
DOT
: UN1993, FLAMMABLE LIQUID N.O.S. (CONTAINS XYLENE, BUTYL ACETATE), 3, PG III
IMO/IMDG: UN1993, FLAMMABLE LIQUID N.O.S. (CONTAINS XYLENE, BUTYL ACETATE), 3, PG III
SECTION 15: REGULATORY INFORMATION
No da
ta for the product itself.
Component data:
Components Hopolymer of HDI CAS# 28182-81-2, Xylene CAS# 1330-20-7, *Ethyl benzene CAS# 100-41-4, n-Butyl Acetate CAS#
123-86-4, and Hexamethylene Diisocyanate (HDI) CAS# 822-06-0 (combined)): : OSHA HAZCOM STANDARD RATING: Hazardou
s. All
components on
TSCA Massachusetts, New york, Pennsylvania Right to Know list includes the following components: Homopolymer of
HDI
CAS# 28182-
81-2 @ 60-100%; n-Butyl Acetate CAS# 123-86-4 @ 10-20%; Xylene CAS# 1330-20-7 @ 7-13%; Ethyl Benzene CAS# 100-41-
4 @1-5%. Massachusetts, New york, Pennsylvania Special hazardous Substance includes the following components: n-Butyl Acetate C
AS#
123-86
-4 @ 10-20%; Xylene CAS# 1330-20-7 @ 7-13%; Ethyl Benzene CAS# 100-41-4 @1-5%; hexamethylene diisocyanate (HDI) C
AS#
822-06
-0 @ <0.6%.California Prop 65: This product contains chemicals known to the State of California to be carcinogenic: Ethyl
Benzene
CAS# 100-41
-4 @ 1-5% US EPA CERCLA Hazardous Substances (40 CFR 302): n-butyl acetate reportable quan
tity 5000 lbs
ARM356X