Datasheet

No.14
3/7
Section 4
First Aid Measures
None
, unless internal material exposure
4.1 Description of necessary first aid measures
Skin Contact:
Wash off skin thoroughly with water. Remove contaminated clothing and
wash before re-use. In severe cases obtain medical attention.
Eye Contact:
Irrigate thoroughly with water for at least 15 minutes.Lifting upper and lower lids,
until no evidence of the chemical remains. Obtain medical attention.
Ingestion:
Wash out mouth thoroughly with water. Do not induce vomiting or give food.
Drink plenty of water. Seek medical attention immediately.
Inhalation:
If battery is leaking, contents may be irritating to respiratory passages.
Move to fresh air. If irritation persists, seek medical advice.
Further treatment:
All cases of eye contamination, persistent skin irritation and casualities who have
swallowed this substance or been affected by breathing its vapours should be seen by a
doctor.
4.2 Most important symptoms / effects, acute and delayed
The chemicals mentioned in section 3 are contained in a sealed can. Risk of exposure occurs only if the
battery is mechanically or electrically abused or if it is ingested (see safety precautions in section 7).
Swallowing of a battery can lead to chemical burns, perforation of soft tissues and death. Severe burns can
occur within 2 hours of ingestion. In case of ingestion, seek medical attention immediately.
See emergency phone number in section 1.
In case of exposure to inner components/material of the battery:
Harmful if swallowed (Manganesedioxide, electrolyte)
Harmful if inhalated (Manganesedioxide)
May cause damage to organs (brain) through prolonged or repeated exposure (inhalation) (Manganesedioxide)
4.3 Indication of immediate medical attention and special treatment needed
No further information available.
Section 5
Fire Fighting Measures
Fire and explosion hazards
Batteries may burst and release hazardous decomposition products when exposed to a fire situation.
5.1 Suitable extinguishing media
Use foam, water, carbon dioxide (CO
2
), as appopriate
5.2 Specific hazards arising from the chemical
Thermal degradation may produce hazardous fumes of zinc and manganese, hydrogen gas, caustic vapors
of potassium(sodium) hydroxide and other toxic by-products
5.3 Special protective actions for firefighters
Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing.
Fight fire from a distance or protected area.
Section 6
Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Steps to be taken in case material is released or spilled:
The preferred response is to leave the area and allow batteries to cool and the vapours to disssipate.
Avoid skin and eye contact or inhalation of vapours.
6.2 Environmental precautions
Do not allow product to reach sewage system or any water course
In the event of spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
6.3 Methods and material for containment and cleaning up
In the event of spill or accidental release, collect all released material in a plastic lined metal container and
remove spilled liquid with absorbent. Doing this, protect your skin and eyes with chemical resistant protective
(EN374) and tightly sealed protective googles (EN166). Avoid direct contact with internal components.
Material - Safety - Data Sheet (MSDS)
for
Ansmann Alkaline (Manganese Dioxide) Button Cells
single cells and multi-cell batteries