Certifications 2

No.16
2/6
3.
Composition and Informations on Ingredients
IMPORTANT NOTE: The product is a manufactured article as described in 29 CFR 1910.1200. The battery
cell is contained in a hermetically-sealed case, designed to withstand temperatures and pressures
encountered during normal use. As a result, during normal use, hazardous materials are fully contained inside
the battery cell. The battery cell should not be opened or exposed to heat because exposure to the following
ingredients contained within could be harmful under some circumstances. The following information is
provided for the user's information only.
4.
First Aid Measures
Inhalation:
If battery is leaking, contents may be irritating to respiratory passages.
Move to fresh air. If irritation persists, seek medical advice.
Skin Contact:
Wash off skin thoroughly with water. Remove contaminated clothing and
wash before re-use. In severe cases obtain medical attention.
Eye Contact:
Irrigate thoroughly with water for at least 15 minutes.Lifting upper and lower lids,
until no evidence of the chemical remains. Obtain medical attention.
Ingestion:
Wash out mouth thoroughly with water. Do not induce vomiting or give food
or drink. Seek medical attention immediately.
Further treatment:
All cases of eye contamination, persistent skin irritation and casualities who
have swallowed this substance or been affected by breathing its vapours should
be seen by a doctor.
5.
Fire Fighting Measures
Fire and explosion hazards:
Batteries may burst and release hazardous decomposition products when
exposed to a fire situation.
Extinguishing media:
Use any extinguishing media that is appropriate for the surrounding fire
Extinguishing media with limited
suitability:
-
Special fire fighting
Firefighters should wear positive pressure self-contained breathing apparatus
procedures:
and full protective clothing. Fight fire from a distance or protected area.
Material - Safety - Data Sheet (MSDS)
for
Ansmann Zinc Carbon (Mercury Free Heavy Duty) Batteries
single cells and multi-cell battery packs
< 0.0001%
ACGIH (TLV)
7440-43-9
Acetylene F+5, 6, 12200ppm 8hours TWA
7440-66-6
(MnO
2
)
7439-97-6
(NH
4
Cl)
Zinc Chloride 5 - 20% 7646-85-7
0 - 5% 74-86-2
Ammonium Chloride 5 - 20% 12125-02-9
Zinc (Zn)
Manganese Dioxide 20 - 50% 1313-13-9
carbon, black (C) 2 - 12%
Ingredient Content CAS No.
1338-86-4
0.2mg/m
3
TWA (as Mn)
3.5mg/m
3
20 - 35%
0.025mg/m
3
5mg/m
3
TWA (as ZnO)
Cadmium (Cd) < 0.002% 0.01mg/m
3
Lead (Pb) < 0.4% 7439-92-1 0.025mg/m
3
paper, water, plastic residue
Mercury (Hg)
see chapter No.13
22, 34, 50/53
R Phrases Classification
20/22 Xn
50/53 N
-
(ZnCl
2
)
Xn, C, N
22, 36 Xi, Xn10mg/m
3
TWA (fume)
20mg/m
3
STEL (fume)
1mg/m
3
TWA (fume)